993-13-5Relevant articles and documents
Nichol et al.
, p. 1008,1010 (1967)
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Thompson
, p. 3292 (1952)
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A Peanut-Like Sb-Embedded Polyoxoniobate Cage for Hydrolytic Decomposition of Chemical Warfare Agent
Wu, Yan-Lan,Zhong, Zhuo-Hao,Wu, Ping-Xin,Sun, Yan-Qiong,Li, Xin-Xiong,Zheng, Shou-Tian
, p. 1505 - 1509 (2021)
A Sb-embedded polyoxoniobate has been originally synthesized under hydrothermal conditions. Particularly, the peanut-like [Sb2Nb24O72]18? cluster cage in 1 with C2h symmetry is composed of two 9-nuclear {SbNb9O33} motifs and one {Nb6O24} crown-shaped ring. The compound 1 present the novel structure of Sb-substituted sandwich-type polyoxoniobate with antimoniobate cluster cage. Decomposition catalytic studies indicate that compound 1 exhibits good hydrolytic activity and stability on the degradation of nerve agent simulant dimethylphosphonate (DMMP).
Mass Spectrometric Identification of Methylphosphonic Acid: The Hydrolysis Product of Isopropyl Methylphosphonofluoridate and Pinacolyl Methylphosphonofluoridate
Tripathi, Durgesh N.,Pandey, Karuna S.,Bhattacharya, Arabinda,Vaidyanathaswamy, Ramamoorthy
, p. 823 - 824 (1992)
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Magnesium Exchanged Zirconium Metal-Organic Frameworks with Improved Detoxification Properties of Nerve Agents
Gil-San-Millan, Rodrigo,López-Maya, Elena,Platero-Prats, Ana E.,Torres-Pérez, Virginia,Delgado, Pedro,Augustyniak, Adam W.,Kim, Min Kun,Lee, Hae Wan,Ryu, Sam Gon,Navarro, Jorge A. R.
supporting information, p. 11801 - 11805 (2019/08/28)
UiO-66, MOF-808 and NU-1000 metal-organic frameworks exhibit a differentiated reactivity toward [Mg(OMe)2(MeOH)2]4 related to their pore accessibility. Microporous UiO-66 remains unchanged while mesoporous MOF-808 and hierarchical micro/mesoporous NU-1000 materials yield doped systems containing exposed MgZr5O2(OH)6 clusters in the mesoporous cavities. This modification is responsible for a remarkable enhancement of the catalytic activity toward the hydrolytic degradation of P-F and P-S bonds of toxic nerve agents, at room temperature, in unbuffered aqueous solutions.