99728-37-7Relevant articles and documents
Fluorocarbanion Chemistry. A Versatile Synthesis of Functionalized Fluoro Ketones
Krespan, Carl G.,Smart, Bruce E.
, p. 320 - 326 (1986)
Fluorocarbanions generated by the addition of an anion to a fluoro olefin can be trapped by fluoro esters, thereby providing a versatile, one-step synthesis of functionalized fluoro ketones.The most efficient anions include CN-, N3-, C6H5O-, RO-, and RS-.The reaction has been extended in one case to prepare a sulfinate ester.