ALLYL-GLYCIDYL-ETHER: 0 Products found
Name
ALLYL-GLYCIDYL-ETHER
EINECS
203-442-4
CAS No.
106-92-3
Density
0.962 g/cm3
Solubility
50 g/L (20 °C) in water
Melting Point
-100 °C
Formula
C6H10O2
Boiling Point
153.2 °C at 760 mmHg
Molecular Weight
114.16
Flash Point
57.2 °C
Transport Information
UN 2219 3/PG 3
Appearance
colourless liquid
Safety
24/25-26-36/37/39-61
Risk Codes
10-20/22-37/38-40-41-43-52/53-62-68
Molecular Structure
Hazard Symbols
Synonyms
Oxirane,[(2-propenyloxy)methyl]- (9CI);Propane, 1-(allyloxy)-2,3-epoxy- (6CI,8CI);1,2-Epoxy-3-allyloxypropane;1-(2-Propenyloxy)-2,3-epoxypropane;1-Allyloxy-2,3-epoxypropane;2-(Allyloxymethyl)oxirane;2-[[(2-Propenyl)oxy]methyl]oxirane;AGE;Allyl 2,3-epoxypropyl ether;Allyl oxiranemethyl ether;Denacol EX 111;Glycidyl2-propenyl ether;Glycidyl allyl ether;NSC 18596;NSC 631;[(2-Propenyloxy)methyl]oxirane;[(Allyloxy)methyl]oxirane;

History

Formaldehyde was first reported by the Russian chemist Aleksandr Butlerov (1828-1886), but it was conclusively identified by August Wilhelm von Hofmann.

Consensus

Reported in EPA TSCA Inventory.

Standards

OSHA PEL: TWA 5 ppm; STEL 10 ppm
ACGIH TLV: 1 ppm; Not Classifiable as a Human Carcinogen
DFG MAK: Confirmed Animal Carcinogen, Suspected Human Carcinogen
NIOSH REL: (Glycidyl Ethers) CL 45 mg/m3/15M
DOT Classification:  3; Label: Flammable Liquid, Poison

AnalyticalMethods

For occupational chemical analysis use NIOSH: Allyl Glycidyl Ether S346.

Others

The Allyl glycidyl ether, with the cas register number 106-92-3, has the systematic name of 2-[(prop-2-en-1-yloxy)methyl]oxirane. And its product categories of Industrial/Fine Chemicals; Simple 3-Membered Ring Compounds; Oxiranes.

The basic information of this chemical is below: This is a kind of colourless liquid, and it is insoluble in water and is flammable. And this is stable but incompatible with strong oxidizing agents, acids, bases. May form peroxides in storage if in contact with air. When store it, this chemical should be stored in the temp. Refrigerator (+4°C), and away from the oxidizing agent.

The characteristics of this chemical are as following: (1)ACD/LogP: 0.78; (2)ACD/LogD (pH 5.5): 0.78; (3)ACD/LogD (pH 7.4): 0.78; (4)ACD/BCF (pH 5.5): 2.3; (5)ACD/BCF (pH 7.4): 2.3; (6)ACD/KOC (pH 5.5): 63.18; (7)ACD/KOC (pH 7.4): 63.18; (8)#H bond acceptors: 2; (9)#Freely Rotating Bonds: 4; (10)Polar Surface Area: 21.76; (11)Index of Refraction: 1.443; (12)Molar Refractivity: 30.89 cm3; (13)Molar Volume: 116.3 cm3; (14)Polarizability: 12.24 ×10-24 cm3; (15)Surface Tension: 32.1 dyne/cm; (16)Density: 0.981 g/cm3; (17)Flash Point: 57.2 °C; (18)Enthalpy of Vaporization: 37.39 kJ/mol; (19)Boiling Point: 153.2 °C at 760 mmHg; (20)Vapour Pressure: 4.32 mmHg at 25°C.

Use of Allyl glycidyl ether: Allyl glycidyl ether could react with 7(9)H-purin-6-ylamine to produce 1-allyloxy-3-(6-amino-purin-9-yl)-propan-2-ol, in the following condtion: reagent: K2CO3; solvent: dimethylsulfoxide; reaction time: 5 days; field: 40%; other condition: Ambient temperature.

When you deal with this chemical, you should be very cautious. Being a kind of harmful chemical, it may cause damage to health, and if by inhalation or if swallowed, it will be very harmful. Then it may even have limited evidence of a carcinogenic effect and has possible risk of impaired fertility. Besides, it is irritating to respiratory system and skin and it may cause sensitisation by skin contact. What's more, it is harmful to aquatic organisms, and it may cause long-term adverse effects in the aquatic environment. Then it has possible risk of irreversible effects. So you should take the following instructions while using. Wear suitable protective clothing, gloves and eye/face protection, and avoid contacting with skin and eyes. If in case of contacting with eyes, rinse immediately with plenty of water and seek medical advice. Besides, avoid releasing to the environment and then refer to special instructions/safety data sheet.

In addition, you could convert the following datas into the molecular structure:
SMILES: C=CCOCC1CO1Copy

Below are the toxicity information of this chemical:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LC50 inhalation 270ppm/4H (270ppm) SENSE ORGANS AND SPECIAL SENSES: LACRIMATION: EYE

LUNGS, THORAX, OR RESPIRATION: DYSPNEA

GASTROINTESTINAL: CHANGES IN STRUCTURE OR FUNCTION OF SALIVARY GLANDS
AMA Archives of Industrial Health. Vol. 14, Pg. 250, 1956.
mouse LD50 oral 390mg/kg (390mg/kg) BRAIN AND COVERINGS: RECORDINGS FROM SPECIFIC AREAS OF CNS

BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

BEHAVIORAL: ATAXIA
AMA Archives of Industrial Health. Vol. 14, Pg. 250, 1956.
rabbit LD50 skin 2550mg/kg (2550mg/kg)   AMA Archives of Industrial Health. Vol. 14, Pg. 250, 1956.
rat LC50 inhalation 670ppm/8H (670ppm) SENSE ORGANS AND SPECIAL SENSES: CORNEAL DAMAGE: EYE

LUNGS, THORAX, OR RESPIRATION: ACUTE PULMONARY EDEMA

GASTROINTESTINAL: CHANGES IN STRUCTURE OR FUNCTION OF SALIVARY GLANDS
AMA Archives of Industrial Health. Vol. 14, Pg. 250, 1956.
rat LD50 oral 1600mg/kg (1600mg/kg) BRAIN AND COVERINGS: RECORDINGS FROM SPECIFIC AREAS OF CNS

BEHAVIORAL: CHANGES IN MOTOR ACTIVITY (SPECIFIC ASSAY)

BEHAVIORAL: ATAXIA
AMA Archives of Industrial Health. Vol. 14, Pg. 250, 1956.