Alloxan 5-oxime supplier

Name
VIOLURIC ACID
EINECS 201-741-4
CAS No. 87-39-8
Article Data16
CAS DataBase
Density 2.19 g/cm³
Solubility Slightly soluble
Hazard Symbols UN NO.
Synonyms Alloxan,5-oxime (8CI); Violuric acid (6CI,7CI); 5-(Hydroxyimino)barbituric acid;5-Isonitrosobarbituric acid; NSC 56338; VLA
PSA 107.86000
LogP -1.15980

Synthetic route

: 67-52-7
BARBITURIC ACID

: 87-39-8
violuric acid

Conditions

Conditions	Yield
With hydrogenchloride; sodium hydroxide; sodium nitrite In water at 10 - 30℃; for 16h; Reagent/catalyst;	85.2%
With potassium nitrite
With sodium perchlorate; sodium nitrite at 25℃; Kinetics; Mechanism; Concentration; pH-value; Reagent/catalyst; Acidic aq. solution;

: 67-52-7
BARBITURIC ACID

: 463-04-7
n-Amyl nitrite

: 87-39-8
violuric acid

Conditions

Conditions	Yield
With hydrogenchloride

: 61066-33-9, 61066-34-0, 61066-35-1, 61127-23-9
pyrimidine-2,4,5,6(1H,3H)-tetraone

: 87-39-8
violuric acid

Conditions

Conditions	Yield
With hydroxylamine hydrochloride; water
With hydroxylamine hydrochloride; water at 60 - 70℃;

: 69-93-2
uric Acid

: 87-39-8
violuric acid

Conditions

Conditions	Yield
With hydrogenchloride; potassium chlorate man erwaermt die von ueberschuessigem Chlor befreite Loesung mit salzsaurem Hydroxylamin;

: 74646-24-5
alloxan-4-oxime

: 87-39-8
violuric acid

Conditions

Conditions	Yield
With hydrogenchloride

: 476-61-9
[5,5']bipyrimidinyl-2,4,6,2',4',6'-hexaone

: 87-39-8
violuric acid

Conditions

Conditions	Yield
With nitric acid
With potassium nitrite; acetic acid
With cis-nitrous acid

: 76-24-4
Alloxantin

: 87-39-8
violuric acid

Conditions

Conditions	Yield
With hydroxylamine hydrochloride; water

: 7647-01-0
hydrogenchloride

: 4,6-diamino-pyrimidine-2,5-dione-5-oxime

: 87-39-8
violuric acid

6-amini-5-nitroso-1H-pyrimidine-2,4-dione: 6-amini-5-nitroso-1H-pyrimidine-2,4-dione

: 87-39-8
violuric acid

Conditions

Conditions	Yield
With hydrogenchloride

diliturate iron: diliturate iron

: 87-39-8
violuric acid

Conditions

Conditions	Yield
With potassium cyanide

dilituric acid: dilituric acid

: 87-39-8
violuric acid

Conditions

Conditions	Yield
With glycerol

: 7732-18-5
water

: 76-24-4
Alloxantin

hydroxylamine hydrochloride: hydroxylamine hydrochloride

: 87-39-8
violuric acid

...Expand

: 67-52-7
BARBITURIC ACID

: 10544-73-7
dinitrogen trioxide

: 87-39-8
violuric acid

: 412341-12-9
5-nitroso-6-aminopyrimidine

: 87-39-8
violuric acid

Conditions

Conditions	Yield
With hydrogenchloride; water

: 7154-73-6
1-(2-aminoethyl)pyrrolidine

: 87-39-8
violuric acid

: 2-pyrrolidin-1-yl-ethylammonium bis(violurate)

Conditions

Conditions	Yield
In methanol; water	90%

: 87-39-8
violuric acid

: 768-94-5
1-Adamantanamine

: C10H17N*C4H3N3O4

Conditions

Conditions	Yield
In ethanol	73%

: 87-39-8
violuric acid

: 75-64-9
tert-butylamine

: C4H11N*C4H3N3O4

Conditions

Conditions	Yield
In ethanol Reflux;	72%

: 87-39-8
violuric acid

: 3171-45-7
4,5-dimethyl-1,2-phenylenediamine

: C8H12N2*C4H3N3O4

Conditions

Conditions	Yield
In ethanol	71%

: 87-39-8
violuric acid

: 613-13-8
2-aminoanthracene

: 196872-60-3
4H-2,4,5,14-Tetraaza-pentaphene-1,3-dione

Conditions

Conditions	Yield
In acetic acid for 3h; Heating;	70%

: 87-39-8
violuric acid

: 1052111-61-1
ammonium pyrimidine-2,4-5,6(1H,3H)-tetrone 5-oximate

Conditions

Conditions	Yield
With ammonium carbonate In water	70%

: 87-39-8
violuric acid

: 121-44-8
triethylamine

: C6H15N*2C4H3N3O4

Conditions

Conditions	Yield
In ethanol; water	70%

: 87-39-8
violuric acid

: 765-30-0
Cyclopropylamine

: cyclopropylammonium violurate

Conditions

Conditions	Yield
In ethanol	66%

: 87-39-8
violuric acid

: 109-89-7
diethylamine

: C4H11N*C4H3N3O4

Conditions

Conditions	Yield
In ethanol Reflux;	61%

: 87-39-8
violuric acid

: 108-18-9
diisopropylamine

: C6H15N*C4H3N3O4

Conditions

Conditions	Yield
In ethanol	61%

: 87-39-8
violuric acid

: 121-44-8
triethylamine

: triethylammonium violurate

Conditions

Conditions	Yield
In ethanol	61%

: 14099-01-5
rhenium(I) pentacarbonyl chloride

: 87-39-8
violuric acid

: 7732-18-5
water

: fac-(5-hydroxyamino-pyrimidine-2,4,6(1H,3H,5H)-trione)aquatricarbonylrhenium(I) hemihydrate

Conditions

Conditions	Yield
In methanol stoich., ligand and Re complex reacted in CH3OH at 50-60°C under stirring for 3 h; pptd.(hexane), filtered, washed (EtOH, Et2O), dried (air), recrystd.(acetone/H2O 1:1), elem. anal.;	60%

...Expand

: 87-39-8
violuric acid

: 1020084-54-1
N1-isobutyl-4-methylbenzene-1,3-diamine

: 1020084-55-2
C15H17N5O2

Conditions

Conditions	Yield
With acetic acid for 0.75h; Heating;	58%

: 87-39-8
violuric acid

: N-butylanthracen-2-amine

: 5-butylanthra[1,2-g]pteridine-1,3(2H,5H)-dione

Conditions

Conditions	Yield
With acetic acid Reflux;	58%

: 87-39-8
violuric acid

: 91-59-8
naphthalen-2-ylamine

: 4707-30-6
8H-naphtho[1,2-g]pteridine-9,11-dione

Conditions

Conditions	Yield
at 155℃; for 0.75h;	57%

: 123-75-1
pyrrolidine

: 87-39-8
violuric acid

: C4H9N*C4H3N3O4

Conditions

Conditions	Yield
In ethanol	55%

: 87-39-8
violuric acid

: 110-18-9
N,N,N,N,-tetramethylethylenediamine

: C6H16N2*C4H3N3O4

Conditions

Conditions	Yield
In ethanol	53%

: 87-39-8
violuric acid

: N-butylpyren-4-amine

: 9-butylpyreno[4,5-g]pteridine-11,13(9H,12H)-dione

Conditions

Conditions	Yield
With acetic acid Reflux;	47%

: 87-39-8
violuric acid

: 6270-18-4
2-(but-1-ylamino)naphthalene

: 5-butylanthra[1,2-g]pteridine-1,3(2H,5H)-dione

Conditions

Conditions	Yield
With acetic acid Reflux;	46%

: 87-39-8
violuric acid

: 1262317-11-2
tert-butyl (2-((3-(cyclopentyloxy)-4-methylphenyl)amino)ethyl)carbamate

: 1262317-12-3
tert-butyl (2-(8-(cyclopentyloxy)-7-methyl-2,4-dioxo-3,4-dihydrobenzo[g]pteridin-10(2H)-yl)ethyl)carbamate

Conditions

Conditions	Yield
In ethanol at 145℃; for 1.5h; Microwave irradiation;	38%

: 51-17-2
benzoimidazole

: 67-56-1
methanol

: 87-39-8
violuric acid

: cadmium(II) nitrate tetrhydrate

: C30H20Cd2N16O16*2CH4O

Conditions

Conditions	Yield
In water for 3h;	37%

...Expand

: 110-86-1
pyridine

: ferrous(II) sulfate heptahydrate

: 87-39-8
violuric acid

: [Fe(violuric acid)3]·pyridine·4H2O

Conditions

Conditions	Yield
In methanol for 4h;	34%

...Expand

: 87-39-8
violuric acid

: 1416815-95-6
C24H43N

: 1416815-96-7
10-hexadecyl-7,8-dimethyl-10H-benzo[g]pteridine-2,4-dione

Conditions

Conditions	Yield
With acetic acid for 48h; Reflux; Inert atmosphere; Darkness;	30%

: 87-39-8
violuric acid

: 134-32-7
1-amino-naphthalene

: 196872-59-0
11H-naphtho[2,1-g]pteridine-8,10-dione

Conditions

Conditions	Yield
In acetic acid for 24h; Heating;	11%

: 503-87-7
2-thiohydantoin

: 87-39-8
violuric acid

: 5-(5-oxo-2-thioxo-imidazolidin-4-ylidenamino)-barbituric acid

Conditions

Conditions	Yield
With acetic anhydride

: 1004-38-2
2,4,6-triaminopyrimidine

: 87-39-8
violuric acid

: 7147-37-7
6,8-diamino-1H-pyrimido[5,4-g]pteridine-2,4-dione

Conditions

Conditions	Yield
With sodium carbonate; acetic acid

: 873-83-6
4-Amino-2,6-dihydroxypyrimidine

: 87-39-8
violuric acid

: 5807-13-6
1,3,6,8-tetrahydro-2,4,5,7-pyrimido<5,4-g>pteridinetetrone

Conditions

Conditions	Yield
With hydrogenchloride; acetic acid

Alloxan 5-oxime Chemical Properties

Molecular Formula: C₄H₃N₃O₄
Molar mass: 157.08 g/mol
EINECS: 201-741-4
Density: 2.19 g/cm³
Flash Point: 252.6 °C
Index of Refraction: 1.813
Boiling Point: 494.1 °C at 760 mmHg
Vapour Pressure: 7.79E-12 mmHg at 25°C
Melting point: 240-250 °C (dec.)
Appearance: Light yellow crystalline powder
Structure of Alloxan 5-oxime (87-39-8):

XLogP3-AA: -0.2
H-Bond Donor: 3
H-Bond Acceptor: 5
Systematic Name Alloxan 5-oxime (87-39-8): 5-Hydroxyiminohexahydropyrimidine-2,4,6-trione
SMILES: O=C1C(=N\O)\C(=O)NC(=O)N1
InChI: InChI=1/C4H3N3O4/c8-2-1(7-11)3(9)6-4(10)5-2/h11H,(H2,5,6,8,9,10)
InChIKey: JMUJZTASUDOAGC-UHFFFAOYAY
Std. InChI: InChI=1S/C4H3N3O4/c8-2-1(7-11)3(9)6-4(10)5-2/h11H,(H2,5,6,8,9,10)
Std. InChIKey: JMUJZTASUDOAGC-UHFFFAOYSA-N

Alloxan 5-oxime Toxicity Data With Reference

ivn-mus LD50:100 mg/kg

CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) NX#05202 .

Alloxan 5-oxime Consensus Reports

Reported in EPA TSCA Inventory.

Alloxan 5-oxime Safety Profile

Poison by intravenous route. When heated to decomposition it emits toxic fumes of NO_x.

Hazard Codes: Xi
Risk Statements:
36: Irritating to the eyes
37: Irritating to the respiratory system
38: Irritating to the skin
Safety Statements:
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36: Wear suitable protective clothing

Alloxan 5-oxime Specification

Alloxan 5-oxime (87-39-8) also can be called Violuric acid ; 5-(Hydroxyimino)pyrimidine-2,4,6(1H,3H,5H)-trione ; 2,4,5,6(1H,3H)-pyrimidinetetrone, 5-oxime ; Pyrimidin-2,4,5,6(1H,3H)-tetron-5-oxim and 5-(Hydroxyimino)-2,4,6(1H,3H,5H)-pyrimidinetrione .

Product Name

VIOLURIC ACID

Synthetic route

Alloxan 5-oxime Chemical Properties

Alloxan 5-oxime Toxicity Data With Reference

Alloxan 5-oxime Consensus Reports

Alloxan 5-oxime Safety Profile

Alloxan 5-oxime Specification

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