Product Name

  • Name

    Allyl methacrylate

  • EINECS 202-473-0
  • CAS No. 96-05-9
  • Article Data25
  • CAS DataBase
  • Density 0.917 g/cm3
  • Solubility Soluble in most organic solvents, hardly soluble in water
  • Melting Point -65 °C
  • Formula C7H10O2
  • Boiling Point 138.588 °C at 760 mmHg
  • Molecular Weight 126.155
  • Flash Point 33.889 °C
  • Transport Information UN 2929 6.1/PG 2
  • Appearance clear liquid
  • Safety 36/37-45-61
  • Risk Codes 10-21/22-23-50
  • Molecular Structure Molecular Structure of 96-05-9 (Allyl methacrylate)
  • Hazard Symbols ToxicT,DangerousN
  • Synonyms 2-Propenoicacid, 2-methyl-, 2-propenyl ester (9CI);Methacrylic acid, allyl ester(6CI,8CI);Allyl alcohol, methacrylate (6CI);2-Methyl-2-propenoic acid 2-propenyl ester;Acryester A;NSC 18597;2-Propenoic acid,2-methyl-, 2-propen-1-yl ester;
  • PSA 26.30000
  • LogP 1.29170

Synthetic route

poly(methacrylic acid)
79-41-4

poly(methacrylic acid)

Allyl acetate
591-87-7

Allyl acetate

allyl methacrylate
96-05-9

allyl methacrylate

Conditions
ConditionsYield
With [Ir(1,5-cyclooctadiene)2]PF6 In toluene at 100℃; for 5h;92%
2,3-Epoxypropyl methacrylate
106-91-2

2,3-Epoxypropyl methacrylate

allyl methacrylate
96-05-9

allyl methacrylate

Conditions
ConditionsYield
With Silphos; iodine In N,N-dimethyl-formamide at 20℃; for 3h;90%
With zirconium(IV) chloride; sodium iodide In acetonitrile for 0.0166667h; Heating;88%
With bis(cyclopentadienyl)titanium dichloride; magnesium In tetrahydrofuran for 12h; Ambient temperature;87%
allyl 2-((tert-butyl(1-(diethoxyphosphoryl)-2,2-dimethylpropyl)amino)oxy)-2-methylpropanoate
1393670-68-2

allyl 2-((tert-butyl(1-(diethoxyphosphoryl)-2,2-dimethylpropyl)amino)oxy)-2-methylpropanoate

A

allyl methacrylate
96-05-9

allyl methacrylate

B

diethyl (1-(tert-butyl((4,4-dimethyl-5-oxotetrahydrofuran-3-yl)methoxy)amino)-2,2-dimethylpropyl)phosphonate
1393670-72-8

diethyl (1-(tert-butyl((4,4-dimethyl-5-oxotetrahydrofuran-3-yl)methoxy)amino)-2,2-dimethylpropyl)phosphonate

Conditions
ConditionsYield
In tert-butyl alcohol at 120℃; for 2h; Sealed tube;A n/a
B 50%
2,3-Epoxypropyl methacrylate
106-91-2

2,3-Epoxypropyl methacrylate

A

2-methyl-acrylic acid 3-chloro-2-iodo-propyl ester

2-methyl-acrylic acid 3-chloro-2-iodo-propyl ester

B

allyl methacrylate
96-05-9

allyl methacrylate

Conditions
ConditionsYield
Stage #1: 2,3-Epoxypropyl methacrylate With N-chloro-succinimide; triphenylphosphine In acetonitrile at 20℃;
Stage #2: With N-iodo-succinimide; triphenylphosphine In acetonitrile for 10h; Heating;
A 44%
B n/a
α-allyloxy-isobutyric acid allyl ester
874487-06-6

α-allyloxy-isobutyric acid allyl ester

allyl methacrylate
96-05-9

allyl methacrylate

Conditions
ConditionsYield
at 60℃; mit Oxalsaeure, ZnCl2 oder besser P2O5;
α-acetoxy-isobutyric acid allyl ester
408318-09-2

α-acetoxy-isobutyric acid allyl ester

allyl methacrylate
96-05-9

allyl methacrylate

Conditions
ConditionsYield
at 475℃; Pyrolysis;
α-acetoxy-isobutyric acid allyl ester
408318-09-2

α-acetoxy-isobutyric acid allyl ester

A

allyl methacrylate
96-05-9

allyl methacrylate

B

acetic acid
64-19-7

acetic acid

Conditions
ConditionsYield
at 475℃; Kontaktzeit ca.4.7 sec.Pyrolysis;
poly(methacrylic acid)
79-41-4

poly(methacrylic acid)

allyl alcohol
107-18-6

allyl alcohol

allyl methacrylate
96-05-9

allyl methacrylate

Conditions
ConditionsYield
With sulfuric acid
With toluene-4-sulfonic acid In toluene Heating;
With dmap; dicyclohexyl-carbodiimide In dichloromethane Inert atmosphere;
2-allyloxy-2-methylpropanoic acid
17859-93-7

2-allyloxy-2-methylpropanoic acid

allyl alcohol
107-18-6

allyl alcohol

A

allyl methacrylate
96-05-9

allyl methacrylate

B

α-allyloxy-isobutyric acid allyl ester
874487-06-6

α-allyloxy-isobutyric acid allyl ester

Conditions
ConditionsYield
With sulfuric acid; tannic acid
allyl alcohol
107-18-6

allyl alcohol

methacrylic acid methyl ester
80-62-6

methacrylic acid methyl ester

allyl methacrylate
96-05-9

allyl methacrylate

Conditions
ConditionsYield
With sodium methylate; 2-hydroxyresorcinol
With oxygen; 4-methoxy-phenol; hydroquinone; zirconium(IV) acetylacetonate at 70 - 117℃; Product distribution / selectivity; Reflux;
allyl 2-hydroxyisobutyrate
19444-21-4

allyl 2-hydroxyisobutyrate

allyl methacrylate
96-05-9

allyl methacrylate

Conditions
ConditionsYield
With phosphorus pentachloride In toluene at 80℃;
Multi-step reaction with 2 steps
1: H3PO4 / 80 - 110 °C
2: 475 °C / Pyrolysis
View Scheme
α-allyloxy-isobutyric acid allyl ester
874487-06-6

α-allyloxy-isobutyric acid allyl ester

P2O5

P2O5

allyl methacrylate
96-05-9

allyl methacrylate

Conditions
ConditionsYield
at 60℃;
2-allyloxy-2-methylpropanoic acid
17859-93-7

2-allyloxy-2-methylpropanoic acid

allyl methacrylate
96-05-9

allyl methacrylate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: concentrated H2SO4; tannin
2: 60 °C / mit Oxalsaeure, ZnCl2 oder besser P2O5
View Scheme
EDMA
97-90-5

EDMA

allyl methacrylate
96-05-9

allyl methacrylate

2-methylpropenal
78-85-3

2-methylpropenal

allyl alcohol
107-18-6

allyl alcohol

allyl methacrylate
96-05-9

allyl methacrylate

Conditions
ConditionsYield
Stage #1: 2-methylpropenal With tert-butylhypochlorite In tetrachloromethane at 20 - 50℃; for 5.5 - 6.5h;
Stage #2: allyl alcohol In tetrachloromethane at 0 - 20℃; for 15.5h;
allyl dodecanoate
7003-75-0

allyl dodecanoate

methyl methacrylate
97-63-2

methyl methacrylate

A

allyl methacrylate
96-05-9

allyl methacrylate

B

ethyl laurate
106-33-2

ethyl laurate

Conditions
ConditionsYield
With 15percent (w/w) Candida antarctica lipase B immobilised onto macroporous acrylic resin at 50℃; for 1h; Enzymatic reaction;A 34.2 %Chromat.
B n/a
2-bromo-2-methylpropionic acid
2052-01-9

2-bromo-2-methylpropionic acid

allyl methacrylate
96-05-9

allyl methacrylate

methacrylic acid methyl ester
80-62-6

methacrylic acid methyl ester

Poly(methyl methacrylate-b-allyl methacrylate) end-capped with isobutyric acid, block copolymerization, Mn 6800, Mw/Mn 1.21

Poly(methyl methacrylate-b-allyl methacrylate) end-capped with isobutyric acid, block copolymerization, Mn 6800, Mw/Mn 1.21

Conditions
ConditionsYield
Multistep reaction.;100%
Triethoxysilane
998-30-1

Triethoxysilane

allyl methacrylate
96-05-9

allyl methacrylate

3-methacryloyloxypropyltriethoxysilane
21142-29-0

3-methacryloyloxypropyltriethoxysilane

Conditions
ConditionsYield
With platinum-containing olefin organic polymer catalyst at 25℃; for 24h;98%
With dihydrogen hexachloroplatinate; Triethoxyvinylsilane; isopropyl alcohol In pentane at 50℃; for 1.5h; Product distribution; Mechanism; influence unsaturated Si-comp. on rate of hydrosilylation; effect of different solvents; further functionalized alkenes;66 % Chromat.
Stage #1: Triethoxysilane; allyl methacrylate With dihydrogen hexachloroplatinate; tetramethyldivinyldisiloxane; N,N'-diphenyl-1,4-phenylenediamine; triphenylphosphine In isopropyl alcohol at 95 - 135℃; for 2.25h;
Stage #2: With dmap In isopropyl alcohol
allyl methacrylate
96-05-9

allyl methacrylate

platinum
7440-06-4

platinum

γ-methacryloxypropyltrichlorosilane

γ-methacryloxypropyltrichlorosilane

Conditions
ConditionsYield
With trichlorosilane; [SG]-S-Pt In hexane98%
dimethylmonochlorosilane
1066-35-9

dimethylmonochlorosilane

allyl methacrylate
96-05-9

allyl methacrylate

3-Methacryloxypropyldimethylchlorosilane
24636-31-5

3-Methacryloxypropyldimethylchlorosilane

Conditions
ConditionsYield
Stage #1: dimethylmonochlorosilane; allyl methacrylate With 10H-phenothiazine; platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex In 5,5-dimethyl-1,3-cyclohexadiene at 80℃; under 5171.62 Torr; for 0.666667h; Flow reactor; Sealed tube; Inert atmosphere;
Stage #2: With 2,6-di-tert-butyl-4-methyl-phenol In 5,5-dimethyl-1,3-cyclohexadiene at 80℃; for 1h; Temperature; Inert atmosphere;
97.9%
With platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex In toluene at 70℃; for 3h;96%
With dihydrogen hexachloroplatinate; 10H-phenothiazine In tetrahydrofuran at 80℃; for 0.5h;72%
With N,N-dimethyl-(3,5-di-tert-butyl-4-hydroxybenzyl)ammonium chloride; Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex at 65 - 80℃; for 1h;
Dichloromethylsilane
75-54-7

Dichloromethylsilane

allyl methacrylate
96-05-9

allyl methacrylate

3-(dichloromethylsilyl)propyl methacrylate
18301-56-9

3-(dichloromethylsilyl)propyl methacrylate

Conditions
ConditionsYield
With platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex In toluene at 70℃; for 3h;97%
With dihydrogen hexachloroplatinate; 10H-phenothiazine In tetrahydrofuran at 80℃; for 0.5h;83%
With dihydrogen hexachloroplatinate; 2-Ethylhexyl alcohol; 2,6-di-tert-butyl-4-methyl-phenol; platinum In toluene at 70 - 80℃; for 4h;
allyl methacrylate
96-05-9

allyl methacrylate

C22H44F12O4Si5

C22H44F12O4Si5

C29H54F12O6Si5

C29H54F12O6Si5

Conditions
ConditionsYield
With complex of alkali-neutralized chloroplatinic acid with vinyl siloxane, containing 0.5percent of platinum In methyl cyclohexane; toluene at 70 - 100℃; for 2h;97%
allyl methacrylate
96-05-9

allyl methacrylate

trichlorosilane
10025-78-2

trichlorosilane

3-(trichlorosilyl)propyl 2-methylprop-2-enoate
7351-61-3

3-(trichlorosilyl)propyl 2-methylprop-2-enoate

Conditions
ConditionsYield
With platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex In toluene at 70℃; for 3h;96%
allyl methacrylate
96-05-9

allyl methacrylate

C20H62O9Si10
1293367-37-9

C20H62O9Si10

C34H82O13Si10

C34H82O13Si10

Conditions
ConditionsYield
platinum 1,3-divinyl-1,1,3,3-tetramethyldisiloxane In toluene; xylene at 20℃; Inert atmosphere;95.8%
allyl methacrylate
96-05-9

allyl methacrylate

methacrylic acid methyl ester
80-62-6

methacrylic acid methyl ester

poly(methyl methacrylate-allyl methacrylate) copolymer, MMA/AMA=30, Mn=38400

poly(methyl methacrylate-allyl methacrylate) copolymer, MMA/AMA=30, Mn=38400

Conditions
ConditionsYield
With 2,2'-azobis(isobutyronitrile) In toluene at 80℃; for 8h; radical copolymerization;95.6%
triethylsilane
617-86-7

triethylsilane

allyl methacrylate
96-05-9

allyl methacrylate

triethylsilyl 2,2-dimethyl-4-pentenoate

triethylsilyl 2,2-dimethyl-4-pentenoate

Conditions
ConditionsYield
With 1,3,5-trimethyl-2,4,6-tris-(3,5-di-tert-butyl-4-hydroxybenzyl)benzene; tris(pentafluorophenyl)borate In toluene at 40 - 50℃; for 3.3h;95.6%
1,1,3,3-Tetramethyldisiloxane
3277-26-7

1,1,3,3-Tetramethyldisiloxane

allyl methacrylate
96-05-9

allyl methacrylate

1,3-bis(2,2-dimethyl-4-pentenoyloxy)-1,1,3,3-tetramethyldisiloxane

1,3-bis(2,2-dimethyl-4-pentenoyloxy)-1,1,3,3-tetramethyldisiloxane

Conditions
ConditionsYield
With 1,3,5-trimethyl-2,4,6-tris-(3,5-di-tert-butyl-4-hydroxybenzyl)benzene; tris(pentafluorophenyl)borate In toluene at 1.5 - 12℃; for 12h;94.8%
trimethoxysilane
2487-90-3

trimethoxysilane

allyl methacrylate
96-05-9

allyl methacrylate

[3-(methacryloyloxy)propyl]trimethoxysilane
2530-85-0

[3-(methacryloyloxy)propyl]trimethoxysilane

Conditions
ConditionsYield
With dihydrogen hexachloroplatinate; 10H-phenothiazine at 85℃; under 1125.11 - 3000.3 Torr; for 4h; Catalytic behavior; Pressure; Autoclave; Inert atmosphere;94.3%
With 4-aminotriphenylamine; 2,6-di-tert-butyl-4-methyl-phenol; acetone; dihydrogen hexachloroplatinate(IV) hexahydrate at 75℃; under 18751.9 Torr; Inert atmosphere;
With dihydrogen hexachloroplatinate(IV) hexahydrate In acetylacetone at 105℃;
oct-1-ene
111-66-0

oct-1-ene

allyl methacrylate
96-05-9

allyl methacrylate

octakis(dimethylsiloxy)octasilsesquioxane

octakis(dimethylsiloxy)octasilsesquioxane

C76H160O28Si16

C76H160O28Si16

Conditions
ConditionsYield
Stage #1: oct-1-ene; octakis(dimethylsiloxy)octasilsesquioxane With bis(1,5-cyclooctadiene)diiridium(I) dichloride; Karstedt's catalyst In toluene at 90℃;
Stage #2: allyl methacrylate In toluene at 60℃;
94%
allyl methacrylate
96-05-9

allyl methacrylate

para-thiocresol
106-45-6

para-thiocresol

allyl 2-hydroxy-2-methyl-3-(p-tolylthio)propanoate

allyl 2-hydroxy-2-methyl-3-(p-tolylthio)propanoate

Conditions
ConditionsYield
Stage #1: allyl methacrylate; para-thiocresol In 1,2-dichloro-ethane; acetonitrile at 20℃; for 2.3h;
Stage #2: With triphenylphosphine In 1,2-dichloro-ethane; acetonitrile for 2h;
93%
With oxygen; copper diacetate; 4-methoxybenzoic acid In 1,2-dichloro-ethane at 50℃; for 3h;88%
styrene
292638-84-7

styrene

allyl methacrylate
96-05-9

allyl methacrylate

poly(styrene-allyl methacrylate) copolymer, St/AMA=68.4, Mn=40200

poly(styrene-allyl methacrylate) copolymer, St/AMA=68.4, Mn=40200

Conditions
ConditionsYield
With 2,2'-azobis(isobutyronitrile) In toluene at 80℃; for 8h; radical copolymerization;92.3%
allyl methacrylate
96-05-9

allyl methacrylate

methacrylic acid methyl ester
80-62-6

methacrylic acid methyl ester

poly(methyl methacrylate-allyl methacrylate) copolymer, MMA/AMA=15, Mn=56100

poly(methyl methacrylate-allyl methacrylate) copolymer, MMA/AMA=15, Mn=56100

Conditions
ConditionsYield
With 2,2'-azobis(isobutyronitrile) In toluene at 80℃; for 8h; radical copolymerization;92.3%
allyl methacrylate
96-05-9

allyl methacrylate

methacrylic acid methyl ester
80-62-6

methacrylic acid methyl ester

poly(methyl methacrylate-allyl methacrylate) copolymer, MMA/AMA=50, Mn=49800

poly(methyl methacrylate-allyl methacrylate) copolymer, MMA/AMA=50, Mn=49800

Conditions
ConditionsYield
With 2,2'-azobis(isobutyronitrile) In toluene at 80℃; for 8h; radical copolymerization;91.8%
allyl methacrylate
96-05-9

allyl methacrylate

diethyl 8-oxo-8H-cyclopenta-(a)-acenaphthylene-7,9-dicarboxylate
57830-24-7

diethyl 8-oxo-8H-cyclopenta-(a)-acenaphthylene-7,9-dicarboxylate

8-Methyl-8,9-dihydro-fluoranthene-7,8,10-tricarboxylic acid 8-allyl ester 7,10-diethyl ester

8-Methyl-8,9-dihydro-fluoranthene-7,8,10-tricarboxylic acid 8-allyl ester 7,10-diethyl ester

Conditions
ConditionsYield
In chloroform for 4h; Heating;91%
allyl methacrylate
96-05-9

allyl methacrylate

3-methyl-5H-furan-2-one
22122-36-7

3-methyl-5H-furan-2-one

Conditions
ConditionsYield
With C28H32Cl2N2ORu In toluene at 70℃; for 18h; Inert atmosphere;91%
styrene
292638-84-7

styrene

allyl methacrylate
96-05-9

allyl methacrylate

poly(styrene-allyl methacrylate) copolymer, St/AMA=7.3, Mn=37000

poly(styrene-allyl methacrylate) copolymer, St/AMA=7.3, Mn=37000

Conditions
ConditionsYield
With 2,2'-azobis(isobutyronitrile) In toluene at 80℃; for 8h; radical copolymerization;90.7%
allyl methacrylate
96-05-9

allyl methacrylate

dicyclopentadiene

dicyclopentadiene

2-methyl-acrylic acid 3-(3-vinyl-1,2,3,3a,4,6a-hexahydro-pentalen-1-yl)-allyl ester

2-methyl-acrylic acid 3-(3-vinyl-1,2,3,3a,4,6a-hexahydro-pentalen-1-yl)-allyl ester

Conditions
ConditionsYield
Grubbs catalyst first generation In dichloromethane at 20℃; for 2h;90%
allyl methacrylate
96-05-9

allyl methacrylate

Triethoxyvinylsilane
78-08-0

Triethoxyvinylsilane

octakis(dimethylsiloxy)octasilsesquioxane

octakis(dimethylsiloxy)octasilsesquioxane

C76H168O40Si20

C76H168O40Si20

Conditions
ConditionsYield
Stage #1: Triethoxyvinylsilane; octakis(dimethylsiloxy)octasilsesquioxane With bis(1,5-cyclooctadiene)diiridium(I) dichloride; Karstedt's catalyst In toluene at 90℃;
Stage #2: allyl methacrylate In toluene at 60℃;
90%
styrene
292638-84-7

styrene

allyl methacrylate
96-05-9

allyl methacrylate

poly(styrene-allyl methacrylate) copolymer, St/AMA=45.5, Mn=38500

poly(styrene-allyl methacrylate) copolymer, St/AMA=45.5, Mn=38500

Conditions
ConditionsYield
With 2,2'-azobis(isobutyronitrile) In toluene at 80℃; for 8h; radical copolymerization;89.1%
styrene
292638-84-7

styrene

allyl methacrylate
96-05-9

allyl methacrylate

poly(styrene-allyl methacrylate) copolymer, St/AMA=15.0, Mn=30400

poly(styrene-allyl methacrylate) copolymer, St/AMA=15.0, Mn=30400

Conditions
ConditionsYield
With 2,2'-azobis(isobutyronitrile) In toluene at 80℃; for 8h; radical copolymerization;88.4%
allyl methacrylate
96-05-9

allyl methacrylate

3-(trichlorosilyl)propyl 2-methylprop-2-enoate
7351-61-3

3-(trichlorosilyl)propyl 2-methylprop-2-enoate

Conditions
ConditionsYield
With dihydrogen hexachloroplatinate; 10H-phenothiazine; trichlorosilane In tetrahydrofuran at 80℃; for 0.5h;88%
With dihydrogen hexachloroplatinate; Triethoxyvinylsilane; trichlorosilane at 50 - 80℃; for 2.5h;
allyl methacrylate
96-05-9

allyl methacrylate

Benzoylformic acid
611-73-4

Benzoylformic acid

C14H16O3

C14H16O3

Conditions
ConditionsYield
With (4s,6s)-2,4,5,6-tetra(9H-carbazol-9-yl)isophthalonitrile; potassium tert-butylate In acetonitrile at 20℃; Inert atmosphere; Sealed tube; Irradiation;88%
allyl methacrylate
96-05-9

allyl methacrylate

diethyltin dihydride
871-33-0

diethyltin dihydride

Diethyl-bis-<2-allyloxycarbonyl-propyl>-stannan
22403-05-0

Diethyl-bis-<2-allyloxycarbonyl-propyl>-stannan

Conditions
ConditionsYield
In neat (no solvent) closed tube, 90-100°C, 1h, N2;;86.8%
In not given reaction in a bomb tube at 90-100°C for 1 h;;
allyl methacrylate
96-05-9

allyl methacrylate

methacrylic acid methyl ester
80-62-6

methacrylic acid methyl ester

poly(methyl methacrylate-allyl methacrylate) copolymer, MMA/AMA=5.8, Mn=43300

poly(methyl methacrylate-allyl methacrylate) copolymer, MMA/AMA=5.8, Mn=43300

Conditions
ConditionsYield
With 2,2'-azobis(isobutyronitrile) In toluene at 80℃; for 8h; radical copolymerization;86%

Allyl methacrylate Consensus Reports

EPA Genetic Toxicology Program. Reported in EPA TSCA Inventory.

Allyl methacrylate Specification

Allyl methacrylate is an organic compound with the formula C7H10O2, and its systematic name is the same with the product name. With the CAS registry number 96-05-9, it is also named as 2-Propenoic acid,2-methyl-, 2-propen-1-yl ester. It belongs to the product categories of Acrylic Monomers; C6 to C7 Monomers; Carbonyl Compounds; Esters; Methacrylate; Ester series. Its EINECS number is 202-473-0. In addition, the molecular weight is 126.15. Its classification code is Skin / Eye Irritant. This chemical should be sealed and stored in a cool and ventilated place. Moreover, it should be protected from oxides, heat and fire. This chemical is widely used as comonomer and grafting monomer in producing organic glass, and it is also used as cross-linking agent in tooth repairing. 

Physical properties of Allyl methacrylate are: (1)ACD/LogP: 1.567; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 1.57; (4)ACD/LogD (pH 7.4): 1.57; (5)ACD/BCF (pH 5.5): 9.14; (6)ACD/BCF (pH 7.4): 9.14; (7)ACD/KOC (pH 5.5): 169.59; (8)ACD/KOC (pH 7.4): 169.59; (9)#H bond acceptors: 2; (10)#H bond donors: 0; (11)#Freely Rotating Bonds: 4; (12)Polar Surface Area: 26.3 Å2; (13)Index of Refraction: 1.43; (14)Molar Refractivity: 35.547 cm3; (15)Molar Volume: 137.553 cm3; (16)Polarizability: 14.092×10-24cm3; (17)Surface Tension: 25.65 dyne/cm; (18)Density: 0.917 g/cm3; (19)Flash Point: 33.889 °C; (20)Enthalpy of Vaporization: 37.588 kJ/mol; (21)Boiling Point: 138.588 °C at 760 mmHg; (22)Vapour Pressure: 6.68 mmHg at 25°C.

Preparation of Allyl methacrylate: this chemical can be prepared by 2-methyl-acrylic acid oxiranylmethyl ester at the ambient temperature. This reaction will need reagents Mg, Cp2TiCl2 and solvent tetrahydrofuran with the reaction time of 12 hours. The yield is about 87%.

Allyl methacrylate can be prepared by 2-methyl-acrylic acid oxiranylmethyl ester at the ambient temperature

Uses of Allyl methacrylate: it can be used to produce 3-(chlorodimethylsilyl)propyl methacrylate at the temperature of 80 °C. It will need reagents 0.05 N H2PtCl6, phenothiazine and solvent tetrahydrofuran with the reaction time of 30 min. The yield is about 72%.

Allyl methacrylate can be used to produce 3-(chlorodimethylsilyl)propyl methacrylate at the temperature of 80 °C

When you are using this chemical, please be cautious about it as the following:
It is flammable and harmful in contact with skin and if swallowed. It is toxic by inhalation and very toxic to aquatic organisms. When using it, you need to wear suitable protective clothing and gloves. In case of accident or if you feel unwell, you must seek medical advice immediately (show the label where possible). You should avoid releasing it to the environment, and you need to refer to special instructions/safety data sheet.

You can still convert the following datas into molecular structure:
(1)SMILES: O=C(OC\C=C)\C(=C)C
(2)Std. InChI: InChI=1S/C7H10O2/c1-4-5-9-7(8)6(2)3/h4H,1-2,5H2,3H3
(3)Std. InChIKey: FBCQUCJYYPMKRO-UHFFFAOYSA-N

The toxicity data is as follows:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LC50 inhalation 5500mg/m3 (5500mg/m3)   Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 34(8), Pg. 59, 1990.
mouse LD50 oral 57mg/kg (57mg/kg)   Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 34(8), Pg. 59, 1990.
mouse LD50 parenteral 57mg/kg (57mg/kg)   National Technical Information Service. Vol. OTS0559078,
rabbit LD50 skin 500uL/kg (.5mL/kg)   American Industrial Hygiene Association Journal. Vol. 30, Pg. 470, 1969.
rat LC50 inhalation 1800mg/m3 (1800mg/m3)   Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 34(8), Pg. 59, 1990.
rat LD50 oral 70mg/kg (70mg/kg)   Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 34(8), Pg. 59, 1990.
rat LD50 parenteral 70mg/kg (70mg/kg)   National Technical Information Service. Vol. OTS0559078,

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