Allyl-methacrylate: 0 Products found
Name
Allyl-methacrylate
EINECS
202-473-0
CAS No.
96-05-9
Density
0.917 g/cm3
Solubility
Soluble in most organic solvents, hardly soluble in water
Melting Point
-65 °C
Formula
C7H10O2
Boiling Point
138.588 °C at 760 mmHg
Molecular Weight
126.15
Flash Point
33.889 °C
Transport Information
UN 2929 6.1/PG 2
Appearance
clear liquid
Safety
36/37-45-61
Risk Codes
10-21/22-23-50
Molecular Structure
Hazard Symbols
Synonyms
2-Propenoicacid, 2-methyl-, 2-propenyl ester (9CI);Methacrylic acid, allyl ester(6CI,8CI);Allyl alcohol, methacrylate (6CI);2-Methyl-2-propenoic acid 2-propenyl ester;Acryester A;NSC 18597;2-Propenoic acid,2-methyl-, 2-propen-1-yl ester;

History

Formaldehyde was first reported by the Russian chemist Aleksandr Butlerov (1828-1886), but it was conclusively identified by August Wilhelm von Hofmann.

Consensus

EPA Genetic Toxicology Program. Reported in EPA TSCA Inventory.

Others

Allyl methacrylate is an organic compound with the formula C7H10O2, and its systematic name is the same with the product name. With the CAS registry number 96-05-9, it is also named as 2-Propenoic acid,2-methyl-, 2-propen-1-yl ester. It belongs to the product categories of Acrylic Monomers; C6 to C7 Monomers; Carbonyl Compounds; Esters; Methacrylate; Ester series. Its EINECS number is 202-473-0. In addition, the molecular weight is 126.15. Its classification code is Skin / Eye Irritant. This chemical should be sealed and stored in a cool and ventilated place. Moreover, it should be protected from oxides, heat and fire. This chemical is widely used as comonomer and grafting monomer in producing organic glass, and it is also used as cross-linking agent in tooth repairing. 

Physical properties of Allyl methacrylate are: (1)ACD/LogP: 1.567; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 1.57; (4)ACD/LogD (pH 7.4): 1.57; (5)ACD/BCF (pH 5.5): 9.14; (6)ACD/BCF (pH 7.4): 9.14; (7)ACD/KOC (pH 5.5): 169.59; (8)ACD/KOC (pH 7.4): 169.59; (9)#H bond acceptors: 2; (10)#H bond donors: 0; (11)#Freely Rotating Bonds: 4; (12)Polar Surface Area: 26.3 Å2; (13)Index of Refraction: 1.43; (14)Molar Refractivity: 35.547 cm3; (15)Molar Volume: 137.553 cm3; (16)Polarizability: 14.092×10-24cm3; (17)Surface Tension: 25.65 dyne/cm; (18)Density: 0.917 g/cm3; (19)Flash Point: 33.889 °C; (20)Enthalpy of Vaporization: 37.588 kJ/mol; (21)Boiling Point: 138.588 °C at 760 mmHg; (22)Vapour Pressure: 6.68 mmHg at 25°C.

Preparation of Allyl methacrylate: this chemical can be prepared by 2-methyl-acrylic acid oxiranylmethyl ester at the ambient temperature. This reaction will need reagents Mg, Cp2TiCl2 and solvent tetrahydrofuran with the reaction time of 12 hours. The yield is about 87%.

Allyl methacrylate can be prepared by 2-methyl-acrylic acid oxiranylmethyl ester at the ambient temperature

Uses of Allyl methacrylate: it can be used to produce 3-(chlorodimethylsilyl)propyl methacrylate at the temperature of 80 °C. It will need reagents 0.05 N H2PtCl6, phenothiazine and solvent tetrahydrofuran with the reaction time of 30 min. The yield is about 72%.

Allyl methacrylate can be used to produce 3-(chlorodimethylsilyl)propyl methacrylate at the temperature of 80 °C

When you are using this chemical, please be cautious about it as the following:
It is flammable and harmful in contact with skin and if swallowed. It is toxic by inhalation and very toxic to aquatic organisms. When using it, you need to wear suitable protective clothing and gloves. In case of accident or if you feel unwell, you must seek medical advice immediately (show the label where possible). You should avoid releasing it to the environment, and you need to refer to special instructions/safety data sheet.

You can still convert the following datas into molecular structure:
(1)SMILES: O=C(OC\C=C)\C(=C)C
(2)Std. InChI: InChI=1S/C7H10O2/c1-4-5-9-7(8)6(2)3/h4H,1-2,5H2,3H3
(3)Std. InChIKey: FBCQUCJYYPMKRO-UHFFFAOYSA-N

The toxicity data is as follows:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LC50 inhalation 5500mg/m3 (5500mg/m3)   Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 34(8), Pg. 59, 1990.
mouse LD50 oral 57mg/kg (57mg/kg)   Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 34(8), Pg. 59, 1990.
mouse LD50 parenteral 57mg/kg (57mg/kg)   National Technical Information Service. Vol. OTS0559078,
rabbit LD50 skin 500uL/kg (.5mL/kg)   American Industrial Hygiene Association Journal. Vol. 30, Pg. 470, 1969.
rat LC50 inhalation 1800mg/m3 (1800mg/m3)   Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 34(8), Pg. 59, 1990.
rat LD50 oral 70mg/kg (70mg/kg)   Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 34(8), Pg. 59, 1990.
rat LD50 parenteral 70mg/kg (70mg/kg)   National Technical Information Service. Vol. OTS0559078,