Conditions | Yield |
---|---|
With nitric acid byproducts: KNO3; Al(NO3)3 crystd. at 25°C; |
Conditions | Yield |
---|---|
With aluminium trichloride evapn. with excess of HNO3 soln.; | >99 |
With AlCl3 evapn. with excess of HNO3 soln.; | >99 |
aluminium
A
aluminium trinitrate
B
ammonium nitrite
C
copper
Conditions | Yield |
---|---|
In water Cu is deposited; Al(NO3)3 and NH4NO2 are in solution;; |
aluminium trinitrate
Conditions | Yield |
---|---|
With nitric acid |
aluminium trinitrate
Conditions | Yield |
---|---|
With nitric acid heating under pressure with HNO3; Fe removed with aq.HCl; |
Conditions | Yield |
---|---|
In neat (no solvent) | |
In neat (no solvent) |
Conditions | Yield |
---|---|
With calcium(II) nitrate |
aluminium trinitrate
Conditions | Yield |
---|---|
In water dissolved in deionized water; |
Conditions | Yield |
---|---|
With hydrogenchloride In water |
Conditions | Yield |
---|---|
In water | 100% |
Conditions | Yield |
---|---|
In water to aq. soln. of H3PW12O40 added Al(NO3)3; solvent evapd.; | 99% |
In water addn. of Al(NO3)3 to aq. soln. of H3PW12O40; evapn. of solvent; | 99% |
Conditions | Yield |
---|---|
In solid Kinetics; in electric furnace at 1670 K; XRD; | 95% |
In solid Kinetics; in electric furnace at 1570 K; | 90% |
In solid Kinetics; in electric furnace at 1770 K; | 83% |
Conditions | Yield |
---|---|
In water all solns. in decarbonated H2O; solns. of Zn+Al salts mixed, added to this soln. of benzoic acid+NaOH (under N2 atm.), gel-like mixt. digested at 348 K for 62 h; gel after digestion cooled, filtered, washed with H2O and EtOH, dried overnight at 333 K; elem. anal.; | 90% |
aluminium trinitrate
N,N'-bis(naphthylidene)-2-aminobenzylamine
Conditions | Yield |
---|---|
In methanol; water for 24h; Reflux; | 89% |
Conditions | Yield |
---|---|
In dichloromethane; water at 30℃; for 2h; Sealed tube; | 88% |
aluminium trinitrate
Conditions | Yield |
---|---|
With triethylamine In ethanol at 20℃; Inert atmosphere; | 79.9% |
aluminium trinitrate
4,4’,4’’-(benzene-1,3,5-triyltris(methylene))tribenzoic acid
water
N,N-dimethyl-formamide
Conditions | Yield |
---|---|
at 10 - 120℃; for 72h; Temperature; High pressure; | 76% |
aluminium trinitrate
3-(4-pyridyl)-2,4-pentanedione
Conditions | Yield |
---|---|
With sodium hydrogencarbonate In methanol; water byproducts: Al(OH)3; components dissoln. (H2O/MeOH 1:1), NaHCO3 addn., suspn. stirring for 5 min, solvent removal under reduced pressure, residue extb. (CHCl3), Al(OH)3 filtration off, soln. concn., opptn. on EtOAc/hexane (1:1, v/v) addn.; solid vac. drying; | 75% |
With sodium hydrogencarbonate In methanol; water |
N-(2-hydroxynaphthalen-1-ylmethylene)-1,2-diaminobenzene
aluminium trinitrate
salicylaldehyde
Conditions | Yield |
---|---|
In ethanol at 60℃; for 6h; | 72% |
aluminium trinitrate
Conditions | Yield |
---|---|
With triethylamine In water at 20℃; Inert atmosphere; | 71.6% |
Conditions | Yield |
---|---|
In water V-oxide addn. to aq. H3PO4 soln. with stoich. amts. of metal salts, reflux for 14 h; suspn. hot filtration, ppt. washing (cold water), drying at room temp.; | 70% |
Conditions | Yield |
---|---|
In water High Pressure; mixt. of Al nitrate and phenylphosphonic acid in H2O (molar ratio Al:P:H2O 1:1:1000) heated at 180°C in a sealed tube for 2 weeks; elem. anal.; | 70% |
aluminium trinitrate
zinc(II) nitrate
cyclo-L-phenylalanyl-L-phenylalanine
sodium hydroxide
Conditions | Yield |
---|---|
In water co-pptn. in mixed soln. of Zn(NO3)2, Al(NO3)3 and soln. of phenylalanyl-phenylalanine in 2:1:1 molar ratio at 313 K with stirring under N2 atmosphere, pH=8, adjusted by aq. NaOH; ppt. centrifuged after aging for 2 h, washed 3 times with distd. H2O dried in vac. at 313 K; | 70% |
aluminium trinitrate
potassium permanganate
phosphoric acid
Conditions | Yield |
---|---|
In water V-oxide addn. to aq. H3PO4 soln. with stoich. amts. of metal salts, reflux for 14 h; suspn. hot filtration, ppt. washing (cold water), drying at room temp.; TG, DTA; | 68% |
Conditions | Yield |
---|---|
With nitric acid byproducts: KNO3; Al(NO3)3 crystd. at 25°C; |
Conditions | Yield |
---|---|
With aluminium trichloride evapn. with excess of HNO3 soln.; | >99 |
With AlCl3 evapn. with excess of HNO3 soln.; | >99 |
aluminium
A
aluminium trinitrate
B
ammonium nitrite
C
copper
Conditions | Yield |
---|---|
In water Cu is deposited; Al(NO3)3 and NH4NO2 are in solution;; |
aluminium trinitrate
Conditions | Yield |
---|---|
With nitric acid |
aluminium trinitrate
Conditions | Yield |
---|---|
With nitric acid heating under pressure with HNO3; Fe removed with aq.HCl; |
Conditions | Yield |
---|---|
In neat (no solvent) | |
In neat (no solvent) |
Conditions | Yield |
---|---|
With calcium(II) nitrate |
aluminium trinitrate
Conditions | Yield |
---|---|
In water dissolved in deionized water; |
Conditions | Yield |
---|---|
With hydrogenchloride In water |
Conditions | Yield |
---|---|
In water | 100% |
Conditions | Yield |
---|---|
In water to aq. soln. of H3PW12O40 added Al(NO3)3; solvent evapd.; | 99% |
In water addn. of Al(NO3)3 to aq. soln. of H3PW12O40; evapn. of solvent; | 99% |
Conditions | Yield |
---|---|
In solid Kinetics; in electric furnace at 1670 K; XRD; | 95% |
In solid Kinetics; in electric furnace at 1570 K; | 90% |
In solid Kinetics; in electric furnace at 1770 K; | 83% |
Conditions | Yield |
---|---|
In water all solns. in decarbonated H2O; solns. of Zn+Al salts mixed, added to this soln. of benzoic acid+NaOH (under N2 atm.), gel-like mixt. digested at 348 K for 62 h; gel after digestion cooled, filtered, washed with H2O and EtOH, dried overnight at 333 K; elem. anal.; | 90% |
aluminium trinitrate
N,N'-bis(naphthylidene)-2-aminobenzylamine
Conditions | Yield |
---|---|
In methanol; water for 24h; Reflux; | 89% |
Conditions | Yield |
---|---|
In dichloromethane; water at 30℃; for 2h; Sealed tube; | 88% |
aluminium trinitrate
Conditions | Yield |
---|---|
With triethylamine In ethanol at 20℃; Inert atmosphere; | 79.9% |
aluminium trinitrate
4,4’,4’’-(benzene-1,3,5-triyltris(methylene))tribenzoic acid
water
N,N-dimethyl-formamide
Conditions | Yield |
---|---|
at 10 - 120℃; for 72h; Temperature; High pressure; | 76% |
aluminium trinitrate
3-(4-pyridyl)-2,4-pentanedione
Conditions | Yield |
---|---|
With sodium hydrogencarbonate In methanol; water byproducts: Al(OH)3; components dissoln. (H2O/MeOH 1:1), NaHCO3 addn., suspn. stirring for 5 min, solvent removal under reduced pressure, residue extb. (CHCl3), Al(OH)3 filtration off, soln. concn., opptn. on EtOAc/hexane (1:1, v/v) addn.; solid vac. drying; | 75% |
With sodium hydrogencarbonate In methanol; water |
N-(2-hydroxynaphthalen-1-ylmethylene)-1,2-diaminobenzene
aluminium trinitrate
salicylaldehyde
Conditions | Yield |
---|---|
In ethanol at 60℃; for 6h; | 72% |
aluminium trinitrate
Conditions | Yield |
---|---|
With triethylamine In water at 20℃; Inert atmosphere; | 71.6% |
Conditions | Yield |
---|---|
In water V-oxide addn. to aq. H3PO4 soln. with stoich. amts. of metal salts, reflux for 14 h; suspn. hot filtration, ppt. washing (cold water), drying at room temp.; | 70% |
Conditions | Yield |
---|---|
In water High Pressure; mixt. of Al nitrate and phenylphosphonic acid in H2O (molar ratio Al:P:H2O 1:1:1000) heated at 180°C in a sealed tube for 2 weeks; elem. anal.; | 70% |
aluminium trinitrate
zinc(II) nitrate
cyclo-L-phenylalanyl-L-phenylalanine
sodium hydroxide
Conditions | Yield |
---|---|
In water co-pptn. in mixed soln. of Zn(NO3)2, Al(NO3)3 and soln. of phenylalanyl-phenylalanine in 2:1:1 molar ratio at 313 K with stirring under N2 atmosphere, pH=8, adjusted by aq. NaOH; ppt. centrifuged after aging for 2 h, washed 3 times with distd. H2O dried in vac. at 313 K; | 70% |
aluminium trinitrate
potassium permanganate
phosphoric acid
Conditions | Yield |
---|---|
In water V-oxide addn. to aq. H3PO4 soln. with stoich. amts. of metal salts, reflux for 14 h; suspn. hot filtration, ppt. washing (cold water), drying at room temp.; TG, DTA; | 68% |
Conditions | Yield |
---|---|
With triethylamine In ethanol for 2h; | 64% |
aluminium trinitrate
phosphoric acid
Conditions | Yield |
---|---|
In water V-oxide addn. to aq. H3PO4 soln. with stoich. amts. of metal salts, reflux for 30 h; suspn. hot filtration, ppt. washing (cold water), drying at room temp.; | 60% |
aluminium trinitrate
zinc(II) nitrate
glutathion
sodium hydroxide
Conditions | Yield |
---|---|
In water co-pptn. in mixed soln. of Zn(NO3)2, Al(NO3)3 and soln. of N-(N-γ-glutamyl-cysteinyl)-glycine in 2:1:1 molar ratio at 313 K with stirring under N2 atmosphere, pH=8, adjusted by aq. NaOH; ppt. centrifuged after aging for 2 h, washed 3 times with distd. H2O dried in vac. at 313 K; | 60% |
aluminium trinitrate
Conditions | Yield |
---|---|
With Et3N In methanol solid metal nitrate added to dry CH3OH soln. of ligand (M:L=1:2) and Et3N, refluxed for 2 h, treated with 1 equiv. of KNO3; filtered, washed (H2O, Et2O), dried (vac.), elem. anal.; | 57% |
Conditions | Yield |
---|---|
In water aq. soln. Al(NO3)3 and citric acid (2:1) was stirred overnight with mildheating, react. mixt. was taken to dryness, residue was dissolved in wa ter, pH was adjusted to 3.5 with aq. ammonia and stirred at room emp. for 2 h; EtOH was addedand kept in refrigerator for 2 weeks; elem. anal.; | 50% |
aluminium trinitrate
Conditions | Yield |
---|---|
With Et3N In methanol solid metal nitrate added to dry CH3OH soln. of ligand (M:L=1:2) and Et3N, refluxed for 2 h, treated with 1 equiv. of KNO3; filtered, washed (H2O, Et2O), dried (vac.), elem. anal.; | 50% |
aluminium trinitrate
Conditions | Yield |
---|---|
In ethanol; water | 47% |
In water at 40℃; for 6h; | 47% |
aluminium trinitrate
sodium molybdate dihydrate
water
trans-1,2-bis(4-pyridyl)ethylene
Conditions | Yield |
---|---|
With nitric acid at 160℃; for 96h; pH=2.4; Autoclave; High pressure; | 46% |
Conditions | Yield |
---|---|
In water at 85℃; for 4h; | 45% |
aluminium trinitrate
sodium molybdate dihydrate
1,3-di(4-pyridyl)propane
water
Conditions | Yield |
---|---|
With nitric acid at 160℃; for 96h; pH=2.4; Autoclave; High pressure; | 43% |
aluminium trinitrate
sodium tungstate (VI) dihydrate
1,3-di(4-pyridyl)propane
ethylenediamine
Conditions | Yield |
---|---|
With HNO3 In water High Pressure; Al(NO3)3, NaWO4*2H2O, CuCl2*2H2O, bpp (1:10:3:3 molar ratio) in H2O, stirred at room temp., pH 5.5 (en and HNO3), mixt. sealed, heated at 165°C for 5 d; crystd., septd., elem. anal.; | 39% |
aluminium trinitrate
Conditions | Yield |
---|---|
With Et3N In methanol solid metal nitrate added to dry CH3OH soln. of ligand (M:L=1:2) and Et3N, refluxed for 2 h, treated with 1 equiv. of KNO3; filtered, washed (H2O, Et2O), dried (vac.), elem. anal.; | 37% |
ALUMINUM(III) NITRATE, NONAHYDRATE (1:3:9)'s MF: AlH18N3O18
ALUMINUM(III) NITRATE, NONAHYDRATE (1:3:9)'s MW: 375.13
EINECS: 236-751-8
mp: 73 °C(lit.)
density: 1.25
bp: 100°C/760mmHg
Sensitive: Hygroscopic
Water Solubility: 64 g/100 mL (25 °C)
Synonyms: NITRIC ACID ALUMINUM SALT;aluminum(111)nitrate(1:3)nonahydrate;Aluminum(III)nitrate,nonahydrate(1:3:9);aluminumnitrate(non-specificname);Aluminumtrinitratenonahydrate;nitricacid,aluminum(3+)saltnonahydrate;nitricacid,aluminumsalt,nonahydrate;Nitricacid,aluminumsalt,nonahydrate(8CI,9CI)
1. | orl-rat TDLo:1620 mg/kg (female 6-14D post):TER | TJADAB Teratology, A Journal of Abnormal Development. 38 (1988),253. | ||
2. | orl-rat LD50:3671 mg/kg | HYSAAV Hygiene and Sanitation: English Translation of Gigiena Sanitariya. 31 (7-9),(1966),204. | ||
3. | ipr-rat LD50:901 mg/kg | PHTXA6 Pharmacology and Toxicology. Translation of FATOAO. 60 (1987),280. | ||
4. | orl-mus LD50:3980 mg/kg | PHTXA6 Pharmacology and Toxicology. Translation of FATOAO. 60 (1987),280. | ||
5. | ipr-mus LD50:1587 mg/kg | PHTXA6 Pharmacology and Toxicology. Translation of FATOAO. 60 (1987),280. |
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