Diallyl sulfide supplier | CasNO.592-88-1

Name
Diallyl sulfide
EINECS 209-775-1
CAS No. 592-88-1
Article Data52
CAS DataBase
Density 0.866 g/cm³
Solubility Soluble in alcohol, chloroform, ether, and carbon tetrachloride. Insoluble in water.
Melting Point -83 °C
Formula C₆H₁₀S
Boiling Point 141.5 °C at 760 mmHg
Molecular Weight 114.211
Flash Point 46.1 °C
Transport Information UN 1993 3/PG 3
Appearance clear colorless liquid
Safety 26-36-37/39-23-16
Risk Codes 10-36/37/38
Molecular Structure
Hazard Symbols Xi
Synonyms Allylsulfide (6CI,7CI,8CI);Allyl monosulfide;Bis(2-propenyl) sulfide;Di(2-propenyl) sulfide;Diallyl monosulfide;Diallylthioether;NSC 20947;Oil garlic;Thioallyl ether;Allyl sulfide;
PSA 25.30000
LogP 2.09160

Synthetic route

: 14180-63-3
diallyl sulfoxide

: 592-88-1
diallyl sulphide

Conditions

Conditions	Yield
With trifluoromethylsulfonic anhydride; potassium iodide In acetonitrile at 20℃; for 0.0833333h;	95%
With 2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine; potassium iodide for 0.0333333h; Neat (no solvent); chemoselective reaction;	93%
With iodine; sodium hydrogensulfite In chloroform at 50℃; for 3h; Temperature;	90%
With Silphos; iodine In acetonitrile for 0.25h; Heating;	89%
With sodium iodide at 20℃; for 1h; Green chemistry;	87%

: 556-56-9
allyl iodid

: 592-88-1
diallyl sulphide

Conditions

Conditions	Yield
With hexamethyldisilathiane at 150 - 160℃; for 7h;	84%
With potassium sulfide

: 75-66-1
2-methylpropan-2-thiol

: 106-95-6
allyl bromide

A: 37850-75-2
allyl tert-butyl sulfide

B: 592-88-1
diallyl sulphide

Conditions

Conditions	Yield
With sodium methylate In methanol 0 deg C, 1 h; 25 deg C, overnight; Yields of byproduct given. Title compound not separated from byproducts;	A 66% B n/a

...Expand

: 127699-25-6
Diallyl selenide

A: 2179-57-9
diallyl disulphide

B: 592-88-1
diallyl sulphide

Conditions

Conditions	Yield
With hydrogen sulfide In dimethyl sulfoxide at 40℃; for 3h;	A 11% B 50.8%

: 1309645-82-6
bis[2-chloro-3-(trimethylsilyl)-propyl]sulfide

: 592-88-1
diallyl sulphide

Conditions

Conditions	Yield
With potassium tert-butylate In methanol at 20℃; for 7h;	47%

: 6329-40-4
Dithiocarbonic acid S-allyl ester O-benzyl ester

A: 592-88-1
diallyl sulphide

B: 538-74-9
dibenzyl sulfide

C: 6937-97-9
allyl(benzyl)sulfide

Conditions

Conditions	Yield
With 1,2-bis-(diphenylphosphino)ethane; tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran at 65℃; for 7h;	A n/a B n/a C 32%

...Expand

: 22388-07-4
2-allylmercapto-1,3-benzothiazole

: 67-66-3
chloroform

A: 95-16-9
1,3-Benzothiazole

B: 2179-57-9
diallyl disulphide

C: 592-88-1
diallyl sulphide

D: 2-(1,1-dichloro-3-butenylthio)benzothiazole

Conditions

Conditions	Yield
With sodium hydroxide; tetrabutylammomium bromide at 45 - 55℃; for 25h; Rearrangement; disproportionation; Further byproducts given;	A 24% B 24% C 15% D n/a

...Expand

: 22388-07-4
2-allylmercapto-1,3-benzothiazole

: 67-66-3
chloroform

A: 95-16-9
1,3-Benzothiazole

B: 2179-57-9
diallyl disulphide

C: 592-88-1
diallyl sulphide

D: 4271-09-4
2,2'-benzothiazolyl

Conditions

Conditions	Yield
With sodium hydroxide; tetrabutylammomium bromide at 45 - 55℃; for 25h; Rearrangement; disproportionation; Further byproducts given;	A 24% B 24% C 15% D 2%

...Expand

: 2179-57-9
diallyl disulphide

: 74-86-2
acetylene

A: 592-88-1
diallyl sulphide

B: 105278-48-6
Vinyl propen-1-yl sulfide

C: 104324-36-9
(E)-allyl(prop-1-en-1-yl)sulfane

D: 123351-73-5, 123351-76-8
1-vinylthio-3-(1-propenylthio)-1-propene

Conditions

Conditions	Yield
With potassium hydroxide; hydroquinone In water; dimethyl sulfoxide at 40 - 45℃; under 9880 - 15200 Torr; for 4h; Further byproducts given;	A 0.7% B 17.8% C 1.4% D 19.6%

...Expand

: 6704-15-0
β,β'-dihydroxydipropyl sulfide

: 592-88-1
diallyl sulphide

Conditions

Conditions	Yield
With potassium hydroxide at 200℃;

: 2179-57-9
diallyl disulphide

: 592-88-1
diallyl sulphide

Conditions

Conditions	Yield
at 117℃; Disproportionierung im geschlossenen Gefaess;

: 10595-09-2
3,3'-thiodipropanol

: 592-88-1
diallyl sulphide

Conditions

Conditions	Yield
With potassium hydroxide at 200℃;

: 106-95-6
allyl bromide

: 592-88-1
diallyl sulphide

Conditions

Conditions	Yield
With sodium sulfide; ethanol
With potassium hydrosulfide
With polyglycol; sodium sulfide In water at 70 - 80℃; for 2h;	99 % Chromat.
With bis(tributyltin)sulfide In chloroform at 110℃; for 12h;	98 % Chromat.

: 2179-57-9
diallyl disulphide

: 603-35-0
triphenylphosphine

: 71-43-2
benzene

: 592-88-1
diallyl sulphide

...Expand

: 107-05-1
3-chloroprop-1-ene

: 592-88-1
diallyl sulphide

Conditions

Conditions	Yield
With potassium hydrosulfide
With potassium sulphide; ethanol; water at 50℃; zuletzt bei Siedetemperatur;
With sodium sulfide; tetrabutylammomium bromide In water at 70 - 80℃; for 2h;	89 % Chromat.

: 57-06-7
N-allyl isothiocyanate

: 592-88-1
diallyl sulphide

Conditions

Conditions	Yield
With potassium sulfide at 120℃;

: 2179-57-9
diallyl disulphide

A: 62488-53-3
3-vinyl-4H-<1,2>-dithiin

B: 592-88-1
diallyl sulphide

C: 2050-87-5
diallyl trisulfide

D: 2444-49-7
diallyl tetrasulfide

Conditions

Conditions	Yield
at 50℃; for 168h; Further byproducts given;	A 0.7 % Chromat. B 3 % Chromat. C 9.7 % Chromat. D 0.47 % Chromat.

...Expand

: 2179-57-9
diallyl disulphide

A: 592-88-1
diallyl sulphide

B: 2050-87-5
diallyl trisulfide

C: 2444-49-7
diallyl tetrasulfide

D: 820-30-4
5-methyl-4,7-dithiadeca-1,9-diene

Conditions

Conditions	Yield
at 80℃; for 240h; Further byproducts given;	A 20 % Chromat. B 18 % Chromat. C 5.5 % Chromat. D 0.45 % Chromat.

...Expand

: 2179-57-9
diallyl disulphide

A: 592-88-1
diallyl sulphide

B: 2050-87-5
diallyl trisulfide

C: 2444-49-7
diallyl tetrasulfide

D: 80028-57-5
2‐ethenyl‐4H‐1,3‐dithiine

Conditions

Conditions	Yield
at 50℃; for 168h; Further byproducts given;	A 3 % Chromat. B 9.7 % Chromat. C 0.47 % Chromat. D 0.3 % Chromat.

...Expand

: 2179-57-9
diallyl disulphide

A: 592-88-1
diallyl sulphide

B: 2050-87-5
diallyl trisulfide

C: 2444-49-7
diallyl tetrasulfide

D: 4-methyl-1,2,3-trithiolane

Conditions

Conditions	Yield
at 80℃; for 240h; Further byproducts given;	A 20 % Chromat. B 18 % Chromat. C 5.5 % Chromat. D 0.68 % Chromat.

...Expand

: 2179-57-9
diallyl disulphide

A: 592-88-1
diallyl sulphide

B: 2050-87-5
diallyl trisulfide

C: 2444-49-7
diallyl tetrasulfide

D: 5-methyl-1,2,3,4-tetrathiane

Conditions

Conditions	Yield
at 80℃; for 240h; Further byproducts given;	A 20 % Chromat. B 18 % Chromat. C 5.5 % Chromat. D 0.42 % Chromat.

...Expand

: 2179-57-9
diallyl disulphide

A: 592-88-1
diallyl sulphide

B: 2050-87-5
diallyl trisulfide

C: 2444-49-7
diallyl tetrasulfide

D: 7-methyl-4,5,8-trithiaundeca-1,10-diene

Conditions

Conditions	Yield
at 80℃; for 240h; Further byproducts given;	A 20 % Chromat. B 18 % Chromat. C 5.5 % Chromat. D 0.86 % Chromat.

...Expand

: 2179-57-9
diallyl disulphide

A: 592-88-1
diallyl sulphide

B: 2050-87-5
diallyl trisulfide

C: 2444-49-7
diallyl tetrasulfide

D: 7-methyl-4,5,6,9,10-pentathiatrideca-1,12-diene

Conditions

Conditions	Yield
at 80℃; for 240h; Yield given. Further byproducts given;	A 20 % Chromat. B 18 % Chromat. C 5.5 % Chromat. D n/a

...Expand

: 2179-57-9
diallyl disulphide

A: 592-88-1
diallyl sulphide

B: 2050-87-5
diallyl trisulfide

C: 2444-49-7
diallyl tetrasulfide

D: 8-methyl-4,5,6,9,10-pentathiatrideca-1,12-diene

Conditions

Conditions	Yield
at 80℃; for 240h; Yield given. Further byproducts given;	A 20 % Chromat. B 18 % Chromat. C 5.5 % Chromat. D n/a

...Expand

: 2179-57-9
diallyl disulphide

A: 592-88-1
diallyl sulphide

B: 2050-87-5
diallyl trisulfide

C: 2444-49-7
diallyl tetrasulfide

D: 2-(2',3'-dithia-5'-hexenyl)-3,4-dihydro-2H-thiopyran

Conditions

Conditions	Yield
at 80℃; for 240h; Further byproducts given;	A 20 % Chromat. B 18 % Chromat. C 5.5 % Chromat. D 2.3 % Chromat.

...Expand

: 2179-57-9
diallyl disulphide

A: 592-88-1
diallyl sulphide

B: 2050-87-5
diallyl trisulfide

C: 2444-49-7
diallyl tetrasulfide

D: 2-(2'-<3',4'-dihydro-2H-thiopyranyl>)-4H-<1,3>-dithiin

Conditions

Conditions	Yield
at 80℃; for 240h; Further byproducts given;	A 20 % Chromat. B 18 % Chromat. C 5.5 % Chromat. D 0.2 % Chromat.

...Expand

: 2179-57-9
diallyl disulphide

A: 592-88-1
diallyl sulphide

B: 2050-87-5
diallyl trisulfide

C: 2444-49-7
diallyl tetrasulfide

D: 2-(2',3',4'-trithia-6'-heptenyl)-3,4-dihydro-2H-thiopyran

Conditions

Conditions	Yield
at 80℃; for 240h; Further byproducts given;	A 20 % Chromat. B 18 % Chromat. C 5.5 % Chromat. D 0.7 % Chromat.

...Expand

: 2179-57-9
diallyl disulphide

A: 592-88-1
diallyl sulphide

B: 2050-87-5
diallyl trisulfide

C: 2444-49-7
diallyl tetrasulfide

D: 3-(2',3',4'-trithia-6'-heptenyl)-3,4-dihydro-2H-thiopyran

Conditions

Conditions	Yield
at 80℃; for 240h; Further byproducts given;	A 20 % Chromat. B 18 % Chromat. C 5.5 % Chromat. D 0.25 % Chromat.

...Expand

: 107-18-6
allyl alcohol

: 106-95-6
allyl bromide

: 592-88-1
diallyl sulphide

Conditions

Conditions	Yield
With 1,1,3,3-tetramethyl-2-thiourea; sodium hydride 1) DMF, room temp., 1 h; 2) DMF, hexane, room temp., 10 min.; Yield given. Multistep reaction;

: 2179-57-9
diallyl disulphide

: 74-86-2
acetylene

A: 65819-74-1
(E,E)-bis-(1-propenyl) sulfide

B: 592-88-1
diallyl sulphide

C: 105278-48-6
Vinyl propen-1-yl sulfide

D: 123351-74-6
1,2-bis(1-propylenylthio)ethene

E: 123351-75-7
1-vinylthio-3-allylthio-1-propene

F: 123351-73-5, 123351-76-8
1-vinylthio-3-(1-propenylthio)-1-propene

Conditions

Conditions	Yield
With potassium hydroxide; hydroquinone In dimethyl sulfoxide at 40℃; under 6840 - 13680 Torr; for 4h; Product distribution; other temperatures, times, amount of potassium hydroxide, inhibitors and the conc. of water in DMSO;

...Expand

: 592-88-1
diallyl sulphide

: 14180-63-3
diallyl sulfoxide

Conditions

Conditions	Yield
With Mn(III) Schiff-base; dihydrogen peroxide In water; acetic acid at 20℃; for 0.0666667h;	100%
With 2-hydroperoxyhexafluoro-2-propanol In dichloromethane at -78℃; for 2h;	98%
With dihydrogen peroxide; Amberlyst 15 In methanol at 20℃; for 0.5h;	98%

: 592-88-1
diallyl sulphide

: 16841-48-8
diallyl sulfone

Conditions

Conditions	Yield
With sodium tungstate (VI) dihydrate; dihydrogen peroxide In methanol; water at 40℃;	100%
With 1H-imidazole; tetra-n-butylammonium hydrogen monopersulfate In dichloromethane at 25℃; for 0.0333333h; chemoselective reaction;	100%
With tert.-butylhydroperoxide; [Mo2(O)4{[2,2'-(1,3-phenylene)bis(4,5-dihydrooxazole-4,2-diyl)]dimethanol}(acac)2] In 1,2-dichloro-ethane for 0.416667h; Reflux;	100%

: 128-09-6
N-chloro-succinimide

: 592-88-1
diallyl sulphide

: 104324-35-8
2-propenyl 3-chloro-1-propenyl sulfide

Conditions

Conditions	Yield
In tetrachloromethane at 4℃; for 10h;	100%

: 592-88-1
diallyl sulphide

A: 1708-32-3
2,5-dihydro-thiophene

B: 74-85-1
ethene

Conditions

Conditions	Yield
With tungsten In octane; chlorobenzene at 80℃; for 1h;	A 100% B n/a
With chloroaryloxide neopentylidene complex of tungsten (1)	A 90% B n/a
(2,6-Ph2C6H3O)2W(Cl)=CHC(CH3)3*OEt2 In chlorobenzene at 80℃; for 3h;	A 88% B n/a

: 592-88-1
diallyl sulphide

: 104324-35-8
2-propenyl 3-chloro-1-propenyl sulfide

Conditions

Conditions	Yield
With N-chloro-succinimide In tetrachloromethane at 0℃;	100%

: 592-88-1
diallyl sulphide

: 74427-22-8
2,2-difluoroethyl triflate

: triallylsulfonium trifluoromethanesulfonate

Conditions

Conditions	Yield
In neat (no solvent) at 60℃; for 24h; Inert atmosphere; Sealed tube;	99%

: 592-88-1
diallyl sulphide

: 95353-04-1
trifluoromethanesulfonic acid 2-fluoroethyl ester

: diallyl(2-fluoroethyl)sulfonium trifluoromethanesulfonate

Conditions

Conditions	Yield
In neat (no solvent) at 20℃; for 15h; Inert atmosphere; Sealed tube;	99%

: 592-88-1
diallyl sulphide

: 95353-04-1
trifluoromethanesulfonic acid 2-fluoroethyl ester

: C9H14F4O3S2

Conditions

Conditions	Yield
at 60℃; for 15h; Inert atmosphere;	99%

: 592-88-1
diallyl sulphide

: 17412-15-6
pyridazine-4,5-dicarbonitrile

: 9,10-dicyano-5-thiatricyclo[5.3.1.03,8]undec-9-ene

Conditions

Conditions	Yield
In chloroform at 110℃; Diels-Alder reaction;	97%

: ammonium hexafluorophosphate

: 592-88-1
diallyl sulphide

: [(C5H5)Ru(2S,3S-bis(diphenylphosphanyl)butane)]I

: [(η(5)-C5H5)Ru((Ph2PCH(Me))2)(S(CH2CH=CH2)2)]PF6

Conditions

Conditions	Yield
In methanol N2-atmosphere; evapn., extg. (CH2Cl2), filtering, pptn. on ether addn. (0°C), filtering, washing (ether), drying (vac.);	97%

...Expand

: 592-88-1
diallyl sulphide

: 95353-04-1
trifluoromethanesulfonic acid 2-fluoroethyl ester

: C10H15F3O3S2

Conditions

Conditions	Yield
at 60℃; for 15h; Inert atmosphere;	96%

: ammonium hexafluorophosphate

: (C5H5)Ru(2S,3S-bis(diphenylphosphanyl)butane)Cl

: 592-88-1
diallyl sulphide

: [(η(5)-C5H5)Ru((Ph2PCH(Me))2)(S(CH2CH=CH2)2)]PF6

Conditions

Conditions	Yield
In methanol N2-atmosphere; refluxing (18 h); evapn., extg. (CH2Cl2), filtering, pptn. on ether addn. (0°C), filtering, washing (ether), drying (vac.); elem. anal.;	94%

...Expand

: 67969-82-8
tetrafluoroboric acid diethyl ether

: (η(5)-C5Me5)Re(NO)(PPh3)(CH3)

: 592-88-1
diallyl sulphide

: [(C5(CH3)5)Re(NO)(P(C6H5)3)(S(CH2CHCH2)2)](1+)*BF4(1-)=[(C5(CH3)5)Re(NO)(P(C6H5)3)(S(CH2CHCH2)2)]BF4

Conditions

Conditions	Yield
In chlorobenzene cooling (-45°C), stirring; dissolving (acetone), filtration (celite), rinsing (acetone), concentration, evaporation, stirring (ether), filtration, drying (vac.); elem. anal.;	93%

...Expand

: 592-88-1
diallyl sulphide

: 1418151-09-3
3,5-bis(chloromethyl)-1,4-thiaselenane

Conditions

Conditions	Yield
With selenium(II) chloride In acetonitrile at 0℃; for 2h; Solvent; regioselective reaction;	93%

: 592-88-1
diallyl sulphide

: 581794-03-8
2-(3-oxo-3-phenyl-prop-1-ynyl)-cyclohex-1-enecarbaldehyde

: C22H24O2S

Conditions

Conditions	Yield
dirhodium tetraacetate In 1,2-dichloro-ethane at 80℃; for 72h;	92%

: 592-88-1
diallyl sulphide

: 95353-04-1
trifluoromethanesulfonic acid 2-fluoroethyl ester

: triallylsulfonium trifluoromethanesulfonate

Conditions

Conditions	Yield
In neat (no solvent) at 60℃; for 15h; Inert atmosphere; Sealed tube;	92%

: 592-88-1
diallyl sulphide

: 62757-24-8
3,5-bis(bromomethyl)-1,4-thiaselenane

Conditions

Conditions	Yield
With selenium dibromide In acetonitrile at 0℃; for 2h; Solvent; regioselective reaction;	91%

: 592-88-1
diallyl sulphide

A: 14180-63-3
diallyl sulfoxide

B: 16841-48-8
diallyl sulfone

Conditions

Conditions	Yield
With tert.-butylhydroperoxide; [Mo2(O)4{[2,2'-(1,3-phenylene)bis(4,5-dihydrooxazole-4,2-diyl)]dimethanol}(acac)2] In 1,2-dichloro-ethane for 0.0833333h; Reflux;	A 90% B 10%
With dihydrogen peroxide; methyltrioxorhenium(VII) In ethanol for 2h; Ambient temperature;	A 81% B 2%
With 1H-imidazole; (TMPP)MnOAc; tetrabutylammonium periodite In dichloromethane at 20℃; for 4h; Reagent/catalyst;	A 17.3% B 26.6%

: 592-88-1
diallyl sulphide

: 581794-05-0
(2-formyl-cyclohex-1-enyl)-propynoic acid methyl ester

A: 2-allylsulfanyl-2-(4,5,6,7-tetrahydro-isobenzofuran-1-yl)-pent-4-enoic acid methyl ester

: C17H22O3S

Conditions

Conditions	Yield
dirhodium tetraacetate In dichloromethane for 120h; Heating;	A n/a B 90%

...Expand

: 592-88-1
diallyl sulphide

: 88284-48-4
2-(trimethylsilyl)phenyl trifluoromethanesulfonate

: 21213-18-3
hexa-1,5-dien-3-yl(phenyl)sulfane

Conditions

Conditions	Yield
With cesium fluoride In acetonitrile at 70℃; for 18h; Solvent; Reagent/catalyst; Schlenk technique; Inert atmosphere;	90%

: 22065-57-2
ethyl 2-phenyldiazoacetate

: 592-88-1
diallyl sulphide

: 1150634-50-6
ethyl 2-phenyl-2-(allylthio)-4-pentenoate

Conditions

Conditions	Yield
With Rh2[(N-(4-dodecylphenyl)sulfonyl)-(S)-prolinate]4	89%
With silver trifluoromethanesulfonate In dichloromethane at 35℃; for 21h; Doyle-Kirmse reaction; Inert atmosphere; chemoselective reaction;	84%

: 906466-25-9
diethyl (1-diazo-2,2,2-trifluoroethyl)phosphonate

: 592-88-1
diallyl sulphide

: 1309440-85-4
diethyl [1-(allylthio)-1-(trifluoromethyl)but-3-en-1-yl]phosphonate

Conditions

Conditions	Yield
With bis(1,1,1-trifluoroacetylacetonato)copper(II) In toluene at 100℃; Inert atmosphere;	89%

: 592-88-1
diallyl sulphide

: 138308-51-7
diazoethane

A: 2-Allyl-3-((allylthio)-phenylmethylene)-2-methylindan-1-one

B: 3-(1-(Allylthio)-1-phenylbut-3-enyl)-2-methylinden-1-one

Conditions

Conditions	Yield
rhodium(II) acetate at 25℃; for 0.333333h;	A 11% B 87%

...Expand

: 92695-35-7
(η5-cyclopentadienyl)Re(NO)(P(C6H5)3)(CF3SO3)

: 592-88-1
diallyl sulphide

: [(η(5)-C5H5)Re(NO)(P(C6H5)3)(diallyl sulfide)](CF3SO3)

Conditions

Conditions	Yield
In chlorobenzene 48 h; volatiles removal (vac.), dissolving (acetone), filtration, washing (ether and pentane), drying; elem. anal.;	86%
In not given elem. anal., (1)H-, (13)C-, (31)P-NMR;	79-86

: 592-88-1
diallyl sulphide

: 63348-81-2
monochloroborane dimethyl sulfide complex

: 105332-17-0
5-chloro-1-thia-5-boracyclooctane

Conditions

Conditions	Yield
In pentane to a mixt. of diallyl sulfide in pentane (dry ice-acetone bath) is added dropwise a chloroborane-dimethyl sulfide complex to the vigorously-stirred soln. over a period of 2 h (-20°C), mixt. is warmed to room temp. and stirred (2 h); solvent is removed, residue is heated to 150°C and then distd. under reduced pressure, elem. anal.;	84.8%

: 592-88-1
diallyl sulphide

: 60190-78-5
methyl 2-diazo-2-(dimethoxyphosphoryl)acetate

: 2-allylsulfanyl-2-(dimethoxy-phosphoryl)-pent-4-enoic acid methyl ester

Conditions

Conditions	Yield
dirhodium tetraacetate In dichloromethane Heating;	84%

: 592-88-1
diallyl sulphide

: 829-85-6
diphenylphosphane

: (4-methyl-tetrahydro-thiophen-3-ylmethyl)-diphenyl-phosphane

Conditions

Conditions	Yield
With cetyltrimethylammonim bromide; 4,4'-dicyano-4,4'-azo-di-valeric acid In water at 80℃; for 4h;	84%

: 460-12-8
Butadiyne

: 592-88-1
diallyl sulphide

: 253687-41-1
[RuCl(dppe)2]OTf

: RuCl((C6H5)2PCH2CH2P(C6H5)2)2(C10H12S)(1+)*CF3SO3(1-)=[RuCl((C6H5)2PCH2CH2P(C6H5)2)2(C10H12S)](CF3SO3)

Conditions

Conditions	Yield
In chloroform-d1 Ar atmosphere, addn. of butadiyne to soln. of Ru complex, 30 min, addn. of S(C3H5)2, 30 min; removement of solvent (vacuum), concn. of mother liquor, recrystn. (CH2Cl2/Et2O); elem. anal.;	84%

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Diallyl sulfide Chemical Properties

Molecular Structure of Allyl sulfide (CAS NO.592-88-1):

IUPAC Name: 3-Prop-2-enylsulfanylprop-1-ene
Molecular Formula: C₆H₁₀S
Molecular Weight: 114.20
EINECS: 209-775-1
FEMA: 2042
storage temp.: 2-8 °C
Melting Point: -83 °C
Index of Refraction: 1.478
Molar Refractivity: 37.29 cm³
Molar Volume: 131.7 cm³
Surface Tension: 26.7 dyne/cm
Density: 0.866 g/cm³
Flash Point: 46.1 °C
Enthalpy of Vaporization: 36.31 kJ/mol
Boiling Point: 141.5 °C at 760 mmHg
Vapour Pressure: 7.3 mmHg at 25 °C
Water Solubility: 621 mg/L at 25 °C
Product Categories: sulfide Flavor
Appearance: clear colorless liquid
Canonical SMILES: C=CCSCC=C
InChI: InChI=1S/C6H10S/c1-3-5-7-6-4-2/h3-4H,1-2,5-6H2
InChIKey: UBJVUCKUDDKUJF-UHFFFAOYSA-N
Classification Code: Anticarcinogenic agents; Antineoplastic agents; Antioxidants; Mutation data; Protective Agents

Diallyl sulfide Uses

Allyl sulfide (CAS NO.592-88-1) is mianly used in the production of flavors.

Diallyl sulfide Toxicity Data With Reference

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
rabbit	LD50	skin	> 5gm/kg (5000mg/kg)		Food and Chemical Toxicology. Vol. 26, Pg. 299, 1988.
rabbit	LDLo	intravenous	330mg/kg (330mg/kg)	BEHAVIORAL: MUSCLE CONTRACTION OR SPASTICITY) LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES	Biochemical Journal. Vol. 4, Pg. 107, 1909.
rat	LD50	oral	2980mg/kg (2980mg/kg)		Food and Chemical Toxicology. Vol. 26, Pg. 299, 1988.

Diallyl sulfide Consensus Reports

Reported in EPA TSCA Inventory.

Diallyl sulfide Safety Profile

Poison by intravenous route. Moderately toxic by ingestion. An irritant to skin, eyes, and mucous membranes. When heated to decomposition it emits toxic SO_x. Explosive reaction with N-bromosuccinimide.
Safety Information of Allyl sulfide (CAS NO.592-88-1):
Hazard Codes: Xi
Risk Statements: 10-36/37/38
R10:Flammable.
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements: 26-36-37/39-23-16
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36:Wear suitable protective clothing.
S37/39:Wear suitable gloves and eye/face protection.
S16:Keep away from sources of ignition.
S23:Do not breathe vapour.
RIDADR: UN 1993 3/PG 3
WGK Germany: 2
RTECS: BC4900000
HazardClass: 3
PackingGroup: III

Diallyl sulfide Specification

Allyl sulfide (CAS NO.592-88-1), its Synonyms are 2-Propenyl sulphide ; 3,3-Thiobis(1-propene) ; Allyl monosulfide ; Diallyl monosulfide ; Diallyl sulfide ; Diallyl thioether ; Oil garlic ; Thioallyl ether ; 1-Propene, 3,3'-thiobis- .

Product Name

Diallyl sulfide

Synthetic route

Diallyl sulfide Chemical Properties

Diallyl sulfide Uses

Diallyl sulfide Toxicity Data With Reference

Diallyl sulfide Consensus Reports

Diallyl sulfide Safety Profile

Diallyl sulfide Specification

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