Conditions | Yield |
---|---|
With sulfuric acid; dihydrogen peroxide | |
With dihydrogen peroxide | |
With dihydrogen peroxide |
Conditions | Yield |
---|---|
With oxygen |
2,5-dimethylhexane
A
2,5-dimethyl-2,5-dihydroperoxyhexane
B
5-hydroperoxy-2,5-dimethyl-hexan-2-ol
Conditions | Yield |
---|---|
With oxygen |
2,5-dimethylhexane
A
2,5-dimethyl-2,5-dihydroperoxyhexane
B
2-Hydroperoxy-2,5-dimethylhexane
Conditions | Yield |
---|---|
With oxygen at 95℃; |
2,5-dimethyl-2,5-hexanediol
sulfuric acid
dihydrogen peroxide
2,5-dimethyl-2,5-dihydroperoxyhexane
Conditions | Yield |
---|---|
at 25 - 30℃; |
Conditions | Yield |
---|---|
at 20℃; Autoxydation; |
2,5-dimethylhexane
A
2,5-dimethyl-2,5-dihydroperoxyhexane
B
2-Hydroperoxy-2,5-dimethylhexane
Conditions | Yield |
---|---|
at 120℃; | |
at 95℃; |
2,2,5,5-tetramethyltetrahydrofuran
2,5-dimethyl-2,5-dihydroperoxyhexane
Conditions | Yield |
---|---|
With sulfuric acid; dihydrogen peroxide In water |
sebacoyl chloride
2,5-dimethyl-2,5-dihydroperoxyhexane
terephthaloyl chloride
Conditions | Yield |
---|---|
With pyridine In dichloromethane at 20℃; for 1.5h; | 98% |
2,5-dimethyl-2,5-dihydroperoxyhexane
α-bromosebacoyl chloride
C90H157Br5O31
Conditions | Yield |
---|---|
With pyridine In dichloromethane at 20℃; for 1.5h; | 97% |
2,5-dimethyl-2,5-dihydroperoxyhexane
α-bromoglutaryl chloride
C52H86Br4O25
Conditions | Yield |
---|---|
With pyridine In dichloromethane at 20℃; for 1.5h; | 95% |
2,5-dimethyl-2,5-dihydroperoxyhexane
α-bromoadipoyl chloride
C56H94Br4O25
Conditions | Yield |
---|---|
With pyridine In dichloromethane at 20℃; for 1.5h; | 95% |
2,5-dimethyl-2,5-dihydroperoxyhexane
succinoyl dichloride
Phthaloyl dichloride
2-(4-{2-[4-(3-{4-[3-(4-Hydroperoxy-1,1,4-trimethyl-pentylperoxycarbonyl)-propionylperoxy]-1,1,4-trimethyl-pentylperoxycarbonyl}-propionylperoxy)-1,1,4-trimethyl-pentylperoxycarbonyl]-benzoylperoxy}-1,1,4-trimethyl-pentylperoxycarbonyl)-benzoic acid
Conditions | Yield |
---|---|
With pyridine In dichloromethane at 20℃; for 1.5h; | 95% |
2,5-dimethyl-2,5-dihydroperoxyhexane
tert-butyl alcohol
2,5-dimethyl-2,5-bis(tert-butylperoxy)hexane
Conditions | Yield |
---|---|
With spherical polyvinyl alcohol complex amino acid C In pentane at 70 - 80℃; for 8h; Reagent/catalyst; | 94.3% |
With sulfuric acid In water at 40 - 45℃; for 2h; Industry scale; | |
With sulfuric acid at 50℃; Temperature; | |
With sulfuric acid In water; tert-butyl alcohol at 15 - 40℃; for 4.33333h; |
2,5-dimethyl-2,5-dihydroperoxyhexane
α-chloroazelaoyl chloride
C68H118Cl4O25
Conditions | Yield |
---|---|
With pyridine In dichloromethane at 20℃; for 1.5h; | 93% |
Conditions | Yield |
---|---|
With pyridine In pentane at 10℃; | 71% |
2,5-dimethyl-2,5-dihydroperoxyhexane
(+-)-5,5,6exo-trimethyl-norbornan-2-one
6,6,9,9-tetramethyl-3-(5,5,6-trimethylbicyclo<2.2.1>heptyl)-1,2,4,5-tetraoxacyclononane
Conditions | Yield |
---|---|
With cation-exchange resin KRS-40t In diethyl ether at 20 - 23℃; for 8h; | 59.5% |
2,5-dimethyl-2,5-dihydroperoxyhexane
1,7-dicarba-closo-dodecarborane-1-carboxylic acid chloride
2,5-dimethyl-2,5-di(m-carboranoylperoxy)hexane
Conditions | Yield |
---|---|
In pyridine; dichloromethane addn. of a soln. of B-compound in CH2Cl2 to a mixt. of organic compound, pyridine and CH2Cl2 at -5 to 0°C, raising temp. slowly to room temp., stirring for 12-14 h; diluting mixt. with hexane, washing (tartaric acid soln., water, sodium bicarbonate), drying (sodium sulfate), column chromy. (silica gel/benzene or hexane-ether), elem. anal.; | 54% |
2,5-dimethyl-2,5-dihydroperoxyhexane
3,3,6,6-tetramethyl-1,2-dioxane
Conditions | Yield |
---|---|
With lead(IV) acetate; acetic acid |
2,5-dimethyl-2,5-dihydroperoxyhexane
3,3,6,6,9,9-hexamethyl-1,2,4,5-tetraoxacyclononane
Conditions | Yield |
---|---|
With hydrogenchloride; acetone | |
With copper(II) sulfate; acetone |
2,5-dimethyl-2,5-dihydroperoxyhexane
benzoyl chloride
2,5-dimethyl-2,5-di(benzoylperoxy)-hexane
Conditions | Yield |
---|---|
With pyridine |
succinic acid anhydride
2,5-dimethyl-2,5-dihydroperoxyhexane
3-[4-(3-Carboxy-propionylperoxy)-1,1,4-trimethyl-pentylperoxycarbonyl]-propionic acid
Conditions | Yield |
---|---|
With sodium acetate In tetrahydrofuran |
butanoic acid anhydride
2,5-dimethyl-2,5-dihydroperoxyhexane
2,5-Dimethyl-2,5-hexandiyl-diperbutyrat
Conditions | Yield |
---|---|
With pyridine |
glutaric anhydride,
2,5-dimethyl-2,5-dihydroperoxyhexane
4-[4-(4-Carboxy-butyrylperoxy)-1,1,4-trimethyl-pentylperoxycarbonyl]-butyric acid
Conditions | Yield |
---|---|
With sodium acetate In tetrahydrofuran |
phthalic anhydride
2,5-dimethyl-2,5-dihydroperoxyhexane
2,5-Dimethylhexan-2,5-bis(acid-peroxy-phthalat)
Conditions | Yield |
---|---|
With sodium acetate In tetrahydrofuran |
chloro-trimethyl-silane
2,5-dimethyl-2,5-dihydroperoxyhexane
C14H34O4Si2
Conditions | Yield |
---|---|
With ammonia In diethyl ether |
2,5-dimethyl-2,5-dihydroperoxyhexane
n-heptanoic anhydride
2,5-Dimethyl-2,5-hexandiyl-diperoenthat
Conditions | Yield |
---|---|
With pyridine |
2,5-dimethyl-2,5-dihydroperoxyhexane
pentanoic anhydride
2,5-Dimethyl-2,5-hexadiyl-dipervalerat
Conditions | Yield |
---|---|
With pyridine |
2,5-dimethyl-2,5-dihydroperoxyhexane
4-methylpentanoic anhydride
Conditions | Yield |
---|---|
With pyridine |
2,5-dimethyl-2,5-dihydroperoxyhexane
capric anhydride
2,5-Dimethyl-2,5-hexandiyl-dipercaprat
Conditions | Yield |
---|---|
With pyridine |
2,5-dimethyl-2,5-dihydroperoxyhexane
Triphenylsilyl chloride
C44H46O4Si2
Conditions | Yield |
---|---|
With ammonia In diethyl ether |
2,5-dimethyl-2,5-dihydroperoxyhexane
5-hydroperoxy-2,5-dimethyl-hexan-2-ol
Conditions | Yield |
---|---|
With (thermolysis) In benzene at 143.9 - 164℃; Kinetics; |
2,5-dimethyl-2,5-dihydroperoxyhexane
acetic anhydride
2,5-Dimethylhexan-2,5-bis(peroxyacetat)
Conditions | Yield |
---|---|
With pyridine |
The Hydroperoxide,1,1'-(1,1,4,4-tetramethyl-1,4-butanediyl)bis-, with the CAS registry number 3025-88-5, is also known as 2,5-Dimethylhexane 2,5-dihydroperoxide. Its EINECS registry number is 221-184-0. This chemical's molecular formula is C8H18O4 and molecular weight is 178.23. Its systematic name is called 2,5-dimethylhexane-2,5-diyl dihydroperoxide.
Physical properties of Hydroperoxide,1,1'-(1,1,4,4-tetramethyl-1,4-butanediyl)bis-: (1)ACD/LogP: 2.32; (2)ACD/LogD (pH 5.5): 2.32; (3)ACD/LogD (pH 7.4): 2.32; (4)ACD/BCF (pH 5.5): 33.89; (5)ACD/BCF (pH 7.4): 33.89; (6)ACD/KOC (pH 5.5): 433.34; (7)ACD/KOC (pH 7.4): 433.34; (8)#H bond acceptors: 4; (9)#H bond donors: 2; (10)#Freely Rotating Bonds: 7; (11)Index of Refraction: 1.453; (12)Molar Refractivity: 45.6 cm3; (13)Molar Volume: 168.4 cm3; (14)Surface Tension: 36.3 dyne/cm; (15)Density: 1.058 g/cm3; (16)Flash Point: 145.5 °C; (17)Enthalpy of Vaporization: 64.73 kJ/mol; (18)Boiling Point: 317 °C at 760 mmHg; (19)Vapour Pressure: 3.33E-05 mmHg at 25°C.
Uses of Hydroperoxide,1,1'-(1,1,4,4-tetramethyl-1,4-butanediyl)bis-: it can be used to produce 6,6,9,9-tetramethyl-3-(5,5,6-trimethylbicyclo[2.2.1]heptyl)-1,2,4,5-tetraoxacyclononane with (+-)-5,5,6exo-trimethyl-norbornan-2-one at temperature of 20 - 23 °C. This reaction will need reagent cation-exchange resin KRS-40t and solvent diethyl ether with reaction time of 8 hours. The yield is about 59.5%.
You can still convert the following datas into molecular structure:
(1)SMILES: OOC(CCC(OO)(C)C)(C)C
(2)InChI: InChI=1/C8H18O4/c1-7(2,11-9)5-6-8(3,4)12-10/h9-10H,5-6H2,1-4H3
(3)InChIKey: JGBAASVQPMTVHO-UHFFFAOYAO
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