Conditions | Yield |
---|---|
With potassium hydroxide; ethanol at 130 - 140℃; Behandeln des Reaktionsprodukts mit Luft; | |
With potassium hydroxide; potassium chlorate; potassium acetate at 125℃; Reagens 4:Methanol; Reagens 5:Naphtalin; anschlissendes Erhitzen auf 200grad und Behandeln einer Suspension des Reaktionsprodukts in Wasser mit Luft; |
Conditions | Yield |
---|---|
With tetralin; sodium carbonate auf Siedetemperatur; | |
With potassium carbonate; 1,2,3-trichlorobenzene unter Zusatz von Phenol, Naphthol-(1) oder Hydrochinon auf 180grad; | |
With sodium carbonate; 1,2,3-trichlorobenzene unter Zusatz von Phenol, Naphthol-(1) oder Hydrochinon auf 180grad; |
Conditions | Yield |
---|---|
With potassium carbonate; 1,2,3-trichlorobenzene unter Zusatz von Phenol, Naphthol-(1) oder Hydrochinon auf 180grad; | |
With sodium carbonate; 1,2,3-trichlorobenzene unter Zusatz von Phenol, Naphthol-(1) oder Hydrochinon auf 180grad; |
Conditions | Yield |
---|---|
With potassium carbonate; nitrobenzene |
Conditions | Yield |
---|---|
With sodium carbonate; nitrobenzene |
cyclopentyl nitrite
Jade Green XBN
Conditions | Yield |
---|---|
With pyridine; copper at 70℃; unter Kohlendioxyd; anschliessendes Erwaermen auf 100grad; |
Conditions | Yield |
---|---|
With sodium hydroxide; sodium dithionite at 50℃; | |
With sodium hydroxide; sodium dithionite; sodium hydrogensulfite at 55 - 60℃; |
Jade Green XBN
16,17-dimethoxy-5,10-bis-sulfooxy-anthra[9,1,2-cde]benzo[rst]pentaphene
Conditions | Yield |
---|---|
With pyridine; chlorosulphuric acid; hydrogen sulfide at 50℃; | |
With pyridine; sodium sulfide anschliessendes Behandeln mit Chloroschwefelsaeure, zuletzt bei 45grad; | |
With sodium hydroxide; sodium dithionite anschliessendes Behandeln mit Sulfo-trimethyl-ammonium-betain; |
Jade Green XBN
Conditions | Yield |
---|---|
With sodium hydroxide; sodium dithionite anschliessendes Behandeln mit Phosphorsaeure-m-tolylester-dichlorid; |
Conditions | Yield |
---|---|
With pyridine; zinc at 80 - 130℃; |
Conditions | Yield |
---|---|
With pyridine; copper zuletzt bei 50grad; |
1-methyl-4-nitrosobenzene
Jade Green XBN
16,17-dimethoxy-anthra[9,1,2-cde]benzo[rst]pentaphene-5,10-diol
Conditions | Yield |
---|---|
at 60℃; |
Jade Green XBN
16,17-bis(hexyloxy)-anthra[9,1,2-cde-]benzo[rst]pentaphene-5,10-dione
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1.1: dichloromethane / 1 h / 20 °C 1.2: 16 h / 20 °C / Reflux; Cooling with ice 2.1: potassium carbonate; 18-crown-6 ether / N,N-dimethyl-formamide / 12 h / 80 °C View Scheme |
Conditions | Yield |
---|---|
Stage #1: Jade Green XBN In dichloromethane at 20℃; for 1h; Stage #2: With boron tribromide In dichloromethane at 20℃; for 16h; Reflux; Cooling with ice; |
Jade Green XBN
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1.1: dichloromethane / 1 h / 20 °C 1.2: 16 h / 20 °C / Reflux; Cooling with ice 2.1: potassium carbonate; 18-crown-6 ether / N,N-dimethyl-formamide / 5 h / 80 °C View Scheme |
Jade Green XBN
16,17-bis(octyloxy)-anthra[9,1,2-cde-]benzo[rst]pentaphene-5,10-dione
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1.1: dichloromethane / 1 h / 20 °C 1.2: 16 h / 20 °C / Reflux; Cooling with ice 2.1: potassium carbonate; 18-crown-6 ether / 1-methyl-pyrrolidin-2-one / 8 h / 100 °C View Scheme |
CAS: 128-58-5
EINECS: 204-896-6
Product Categories: Organics
Following is the Molecular Structure of Jade green base (CAS NO.128-58-5):
SMILES: O=C2c9c1c8c(c(OC)cc1c3ccccc23)c6c(OC)cc5c4ccccc4C(=O)c7c5c6c(cc7)c8cc9
InChI: InChI=1/C36H20O4/c1-39-27-15-25-17-7-3-5-9-21(17)35(37)23-13-11-19-20-12-14-24-30-26(18-8-4-6-10-22(18)36(24)38)16-28(40-2)34(32(20)30)33(27)31(19)29(23)25/h3-16H,1-2H3
InChIKey: JXUKQCUPTNLTCS-UHFFFAOYAK
Std.InChI: InChI=1S/C36H20O4/c1-39-27-15-25-17-7-3-5-9-21(17)35(37)23-13-11-19-20-12-14-24-30-26(18-8-4-6-10-22(18)36(24)38)16-28(40-2)34(32(20)30)33(27)31(19)29(23)25/h3-16H,1-2H3
Std.InChIKey: JXUKQCUPTNLTCS-UHFFFAOYSA-N
Molecular Formula: C36H20O4
Molecular Weight: 516.54
Molar Volume: 354.8 cm3
Density: 1.455g/cm3
Molar Refractivity: 159.01cm3
Index of Refraction: 1.853
Surface Tension: 74.3dyne/cm
Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
---|---|---|---|---|---|
rat | LD50 | intraperitoneal | 2600mg/kg (2600mg/kg) | BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) BEHAVIORAL: ATAXIA LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES | Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 52(10), Pg. 88, 1987. |
Reported in EPA TSCA Inventory.
Jade green base (CAS NO.128-58-5) is an eye irritant.When heated to decomposition it emits acrid smoke and fumes.
Jade green base (CAS NO.128-58-5),which also can be called for Brilliant Green S ; Mayvat Jade Green ; Caledon Jade Green ; Dimethoxyviolanthrone ; Helanthrene Green B ; Zelen kypova 1 ; Amanthrene Green JF ; Mikethrene Green FFB ; Ostanthren Green FFB . Jade green base (CAS NO.128-58-5) is a solid, it's stable and incompatible with strong oxidizing agents. It's insoluble in water, Alcohol , Chloroform , Toluene ,slightly soluble in Acetone , O-chlorophenol and Nitrobenzene , Pyridine (heat).
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