Product Name

  • Name

    Vat Green 1

  • EINECS 204-896-6
  • CAS No. 128-58-5
  • Density 1.455 g/cm3
  • Solubility
  • Melting Point
  • Formula C36H20O4
  • Boiling Point 521.39°C (rough estimate)
  • Molecular Weight 516.552
  • Flash Point
  • Transport Information
  • Appearance solid
  • Safety
  • Risk Codes
  • Molecular Structure Molecular Structure of 128-58-5 (Vat Green 1)
  • Hazard Symbols
  • Synonyms CaledonJade Green XN (6CI);Ahcovat Jade Green B;Ahcovat Printing Jade Green B;Amanthrene Green JF;Belanthrene Jade Green;Benzadone Jade GreenX;Benzadone Jade Green XBN;Brilliant Green S;C.I. Pigment Green 47;Calcoloid Jade Green N;Calcoloid Jade GreenNP;Caledon Jade Green XBN;Caledon Printing Jade Green XN;CarbanthreneBrilliant Green G;Cibanone Brilliant Green FBF;Dimethoxyviolanthrone;Indanthrene BrilliantGreen BN;Indanthrene Green FFB;Mikethrene Brilliant Green B;Mikethrene Brilliant Green FFB Superfine;Navinon Green FFB;PalanthreneJade Green;Paradone JadeGreen B New;Pigment Green 47;
  • PSA 52.60000
  • LogP 8.17720

Synthetic route

2-methoxy-benz[de]anthracen-7-one
6535-67-7

2-methoxy-benz[de]anthracen-7-one

Jade Green XBN
128-58-5

Jade Green XBN

Conditions
ConditionsYield
With potassium hydroxide; ethanol at 130 - 140℃; Behandeln des Reaktionsprodukts mit Luft;
With potassium hydroxide; potassium chlorate; potassium acetate at 125℃; Reagens 4:Methanol; Reagens 5:Naphtalin; anschlissendes Erhitzen auf 200grad und Behandeln einer Suspension des Reaktionsprodukts in Wasser mit Luft;
isoviolanthrone
116-71-2

isoviolanthrone

methyl p-toluene sulfonate
80-48-8

methyl p-toluene sulfonate

Jade Green XBN
128-58-5

Jade Green XBN

Conditions
ConditionsYield
With tetralin; sodium carbonate auf Siedetemperatur;
With potassium carbonate; 1,2,3-trichlorobenzene unter Zusatz von Phenol, Naphthol-(1) oder Hydrochinon auf 180grad;
With sodium carbonate; 1,2,3-trichlorobenzene unter Zusatz von Phenol, Naphthol-(1) oder Hydrochinon auf 180grad;
isoviolanthrone
116-71-2

isoviolanthrone

dimethyl sulfate
77-78-1

dimethyl sulfate

Jade Green XBN
128-58-5

Jade Green XBN

Conditions
ConditionsYield
With potassium carbonate; 1,2,3-trichlorobenzene unter Zusatz von Phenol, Naphthol-(1) oder Hydrochinon auf 180grad;
With sodium carbonate; 1,2,3-trichlorobenzene unter Zusatz von Phenol, Naphthol-(1) oder Hydrochinon auf 180grad;
dimethyl sulfate
77-78-1

dimethyl sulfate

16.17-dihydroxy-violanthrenedione-(5.10)

16.17-dihydroxy-violanthrenedione-(5.10)

Jade Green XBN
128-58-5

Jade Green XBN

Conditions
ConditionsYield
With potassium carbonate; nitrobenzene
dimethyl sulfate
77-78-1

dimethyl sulfate

bz2.bz2'-dioxy-violanthrone

bz2.bz2'-dioxy-violanthrone

Jade Green XBN
128-58-5

Jade Green XBN

Conditions
ConditionsYield
With sodium carbonate; nitrobenzene
sulfuric acid
7664-93-9

sulfuric acid

16,17-dimethoxy-anthra[9,1,2-cde]benzo[rst]pentaphene-5,10-diol
3951-01-7

16,17-dimethoxy-anthra[9,1,2-cde]benzo[rst]pentaphene-5,10-diol

Jade Green XBN
128-58-5

Jade Green XBN

5,10-bis-(5-carboxy-valeryloxy)-16,17-dimethoxy-anthra[9,1,2-cde]benzo[rst]pentaphene

5,10-bis-(5-carboxy-valeryloxy)-16,17-dimethoxy-anthra[9,1,2-cde]benzo[rst]pentaphene

aqueous alkaline solution

aqueous alkaline solution

air

air

Jade Green XBN
128-58-5

Jade Green XBN

cyclopentyl nitrite
67764-33-4

cyclopentyl nitrite

5,10-bis-(5-carboxy-valeryloxy)-16,17-dimethoxy-anthra[9,1,2-cde]benzo[rst]pentaphene

5,10-bis-(5-carboxy-valeryloxy)-16,17-dimethoxy-anthra[9,1,2-cde]benzo[rst]pentaphene

aqueous alkaline solution

aqueous alkaline solution

mineral acid

mineral acid

Jade Green XBN
128-58-5

Jade Green XBN

maleic anhydride
108-31-6

maleic anhydride

Jade Green XBN
128-58-5

Jade Green XBN

(16.17-dimethoxy-anthra[9.1.2-cde]benzo[rst]pentaphenediyl-(5.10))-bis-hydrogen maleate

(16.17-dimethoxy-anthra[9.1.2-cde]benzo[rst]pentaphenediyl-(5.10))-bis-hydrogen maleate

Conditions
ConditionsYield
With pyridine; copper at 70℃; unter Kohlendioxyd; anschliessendes Erwaermen auf 100grad;
Jade Green XBN
128-58-5

Jade Green XBN

16,17-dimethoxy-anthra[9,1,2-cde]benzo[rst]pentaphene-5,10-diol
3951-01-7

16,17-dimethoxy-anthra[9,1,2-cde]benzo[rst]pentaphene-5,10-diol

Conditions
ConditionsYield
With sodium hydroxide; sodium dithionite at 50℃;
With sodium hydroxide; sodium dithionite; sodium hydrogensulfite at 55 - 60℃;
Jade Green XBN
128-58-5

Jade Green XBN

16,17-dimethoxy-5,10-bis-sulfooxy-anthra[9,1,2-cde]benzo[rst]pentaphene
2678-71-9

16,17-dimethoxy-5,10-bis-sulfooxy-anthra[9,1,2-cde]benzo[rst]pentaphene

Conditions
ConditionsYield
With pyridine; chlorosulphuric acid; hydrogen sulfide at 50℃;
With pyridine; sodium sulfide anschliessendes Behandeln mit Chloroschwefelsaeure, zuletzt bei 45grad;
With sodium hydroxide; sodium dithionite anschliessendes Behandeln mit Sulfo-trimethyl-ammonium-betain;
Jade Green XBN
128-58-5

Jade Green XBN

5,10-bis-(hydroxy-m-tolyloxy-phosphoryloxy)-16,17-dimethoxy-anthra[9,1,2-cde]benzo[rst]pentaphene

5,10-bis-(hydroxy-m-tolyloxy-phosphoryloxy)-16,17-dimethoxy-anthra[9,1,2-cde]benzo[rst]pentaphene

Conditions
ConditionsYield
With sodium hydroxide; sodium dithionite anschliessendes Behandeln mit Phosphorsaeure-m-tolylester-dichlorid;
Jade Green XBN
128-58-5

Jade Green XBN

chloroformic acid ethyl ester
541-41-3

chloroformic acid ethyl ester

5,10-bis-ethoxycarbonyloxy-16,17-dimethoxy-anthra[9,1,2-cde]benzo[rst]pentaphene

5,10-bis-ethoxycarbonyloxy-16,17-dimethoxy-anthra[9,1,2-cde]benzo[rst]pentaphene

Conditions
ConditionsYield
With pyridine; zinc at 80 - 130℃;
Jade Green XBN
128-58-5

Jade Green XBN

Adipic acid dichloride
111-50-2

Adipic acid dichloride

5,10-bis-(5-carboxy-valeryloxy)-16,17-dimethoxy-anthra[9,1,2-cde]benzo[rst]pentaphene

5,10-bis-(5-carboxy-valeryloxy)-16,17-dimethoxy-anthra[9,1,2-cde]benzo[rst]pentaphene

Conditions
ConditionsYield
With pyridine; copper zuletzt bei 50grad;
1-methyl-4-nitrosobenzene
623-11-0

1-methyl-4-nitrosobenzene

Jade Green XBN
128-58-5

Jade Green XBN

sodium hydrogensulfite

sodium hydrogensulfite

Na2S2O4

Na2S2O4

16,17-dimethoxy-anthra[9,1,2-cde]benzo[rst]pentaphene-5,10-diol
3951-01-7

16,17-dimethoxy-anthra[9,1,2-cde]benzo[rst]pentaphene-5,10-diol

Conditions
ConditionsYield
at 60℃;
Jade Green XBN
128-58-5

Jade Green XBN

16,17-bis(hexyloxy)-anthra[9,1,2-cde-]benzo[rst]pentaphene-5,10-dione
25637-03-0

16,17-bis(hexyloxy)-anthra[9,1,2-cde-]benzo[rst]pentaphene-5,10-dione

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: dichloromethane / 1 h / 20 °C
1.2: 16 h / 20 °C / Reflux; Cooling with ice
2.1: potassium carbonate; 18-crown-6 ether / N,N-dimethyl-formamide / 12 h / 80 °C
View Scheme
Jade Green XBN
128-58-5

Jade Green XBN

16,17-dihydroxyviolanthrene-5,10-dione
128-59-6

16,17-dihydroxyviolanthrene-5,10-dione

Conditions
ConditionsYield
Stage #1: Jade Green XBN In dichloromethane at 20℃; for 1h;
Stage #2: With boron tribromide In dichloromethane at 20℃; for 16h; Reflux; Cooling with ice;
Jade Green XBN
128-58-5

Jade Green XBN

16,17-didecyloxyviolanthrone

16,17-didecyloxyviolanthrone

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: dichloromethane / 1 h / 20 °C
1.2: 16 h / 20 °C / Reflux; Cooling with ice
2.1: potassium carbonate; 18-crown-6 ether / N,N-dimethyl-formamide / 5 h / 80 °C
View Scheme
Jade Green XBN
128-58-5

Jade Green XBN

16,17-bis(octyloxy)-anthra[9,1,2-cde-]benzo[rst]pentaphene-5,10-dione
85652-50-2

16,17-bis(octyloxy)-anthra[9,1,2-cde-]benzo[rst]pentaphene-5,10-dione

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: dichloromethane / 1 h / 20 °C
1.2: 16 h / 20 °C / Reflux; Cooling with ice
2.1: potassium carbonate; 18-crown-6 ether / 1-methyl-pyrrolidin-2-one / 8 h / 100 °C
View Scheme

Vat Green 1 Chemical Properties

CAS: 128-58-5
EINECS: 204-896-6
Product Categories: Organics
Following is the Molecular Structure of Jade green base (CAS NO.128-58-5):

SMILES: O=C2c9c1c8c(c(OC)cc1c3ccccc23)c6c(OC)cc5c4ccccc4C(=O)c7c5c6c(cc7)c8cc9
InChI: InChI=1/C36H20O4/c1-39-27-15-25-17-7-3-5-9-21(17)35(37)23-13-11-19-20-12-14-24-30-26(18-8-4-6-10-22(18)36(24)38)16-28(40-2)34(32(20)30)33(27)31(19)29(23)25/h3-16H,1-2H3
InChIKey: JXUKQCUPTNLTCS-UHFFFAOYAK
Std.InChI: InChI=1S/C36H20O4/c1-39-27-15-25-17-7-3-5-9-21(17)35(37)23-13-11-19-20-12-14-24-30-26(18-8-4-6-10-22(18)36(24)38)16-28(40-2)34(32(20)30)33(27)31(19)29(23)25/h3-16H,1-2H3
Std.InChIKey: JXUKQCUPTNLTCS-UHFFFAOYSA-N
Molecular Formula: C36H20O4
Molecular Weight: 516.54
Molar Volume: 354.8 cm3
Density: 1.455g/cm3
Molar Refractivity: 159.01cm3
Index of Refraction: 1.853
Surface Tension: 74.3dyne/cm

Vat Green 1 Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
rat LD50 intraperitoneal 2600mg/kg (2600mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

BEHAVIORAL: ATAXIA

LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES
Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 52(10), Pg. 88, 1987.

Vat Green 1 Consensus Reports

Reported in EPA TSCA Inventory.

Vat Green 1 Safety Profile

 Jade green base (CAS NO.128-58-5) is an eye irritant.When heated to decomposition it emits acrid smoke and fumes.

Vat Green 1 Specification

 Jade green base (CAS NO.128-58-5),which also can be called for Brilliant Green S ; Mayvat Jade Green ; Caledon Jade Green ; Dimethoxyviolanthrone ; Helanthrene Green B ; Zelen kypova 1 ; Amanthrene Green JF ; Mikethrene Green FFB ; Ostanthren Green FFB . Jade green base (CAS NO.128-58-5) is a solid, it's stable and incompatible with strong oxidizing agents. It's insoluble in water, Alcohol , Chloroform , Toluene ,slightly soluble in Acetone , O-chlorophenol  and Nitrobenzene , Pyridine (heat).

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