Yttrium(III) chloride supplier

Name
YTTRIUM CHLORIDE
EINECS 233-801-0
CAS No. 10361-92-9
Article Data75
CAS DataBase
Density 2.67 g/mL at 25 °C(lit.)
Solubility Soluble.
Melting Point 721 °C(lit.)
Formula Cl3Y
Boiling Point °Cat760mmHg
Molecular Weight 195.265
Flash Point °C
Transport Information
Appearance powder
Safety Poison by intraperitoneal route. When heated to decomposition it emits toxic fumes of Cl⁻. See also YTTRIUM and RARE EARTHS.
Risk Codes 36/37/38
Molecular Structure
Hazard Symbols Xi
Synonyms Yttriumchloride;Yttrium chloride (Y2Cl6);Yttrium trichloride;Yttrium(III) chloride;
PSA 0.00000
LogP 2.06850

Synthetic route

: hexaaquadichloroyttrium(III) chloride

: 10361-92-9
yttrium(III) chloride

Conditions

Conditions	Yield
In neat (no solvent, solid phase) byproducts: H2O; Schlenk techniques; heating Y compd. under vacuum (1E-3 Torr);	99%

: yttrium(III) oxide

: erbium(III) oxide

: potassium chloride

: 7782-50-5
chlorine

A: 10138-41-7
erbium(III) chloride

B: 10361-92-9
yttrium(III) chloride

Conditions

Conditions	Yield
With pyrographite In gas byproducts: CO; by chlorination-chem. vapor transport react.; mixt. of Er2O3 and Y2O3 with carbon and KCl (1:1:6:1 at. ratio) placed in alumina reactor and chlorinated with dry Cl2 (20 cm**3/min) at 800 K for 2 h; gas replace by Ar:Cl2 at 800-1300 K; detn. of separation factor;	A 31.74% B 21.33%

...Expand

: 7647-01-0
hydrogenchloride

: yttrium(III) oxide

: ammonium chloride

: 10361-92-9
yttrium(III) chloride

Conditions

Conditions	Yield
In hydrogenchloride Y2O3 dissolved in 10 ml HCl (6m); addn. of solid NH4Cl (n(NH4Cl):n(Y2O3) approx. 15), addn. of 10 ml concd. HCl, heating to near dryness, cooling, ground; transferred to a quartz tube with a side arm, evacuation to ca. 10 Pa, heated to 373 K for 15-18 h, then temp. rise to 673 K (sublimation of NH4Cl), then temp. rise to 1223 K (sublimation of YCl3); elem. anal.;

...Expand

: yttrium(III) oxide

: ammonium chloride

: 10361-92-9
yttrium(III) chloride

Conditions

Conditions	Yield
Y2O3 is reacted with NH4Cl; purified by two distn. in tantalum crucibles under high vac.;
In hydrogenchloride react. of oxide and excess NH4Cl in concd. HCl at 100°C; sublimation at 360°C/0.1 mmHg;
In not given extd. with THF;

: 7647-01-0
hydrogenchloride

: yttrium(III) chloride hexahydrate

: 10361-92-9
yttrium(III) chloride

Conditions

Conditions	Yield
In neat (no solvent) heating (70°C, vac.; 100-250°C, HCl atm.);

: yttrium(III) chloride hydrate

: 10361-92-9
yttrium(III) chloride

Conditions

Conditions	Yield
With NH4Cl In neat (no solvent) heating of YCl3*99H2O in the presence of NH4Cl (Handbuch der preparativen anorganischen Chemie, Herausg. G. Brauer, Studgardt, 1975);

: 3NH4(1+)*YCl6(3-) = (NH4)3YCl6

: 10361-92-9
yttrium(III) chloride

Conditions

Conditions	Yield
In neat (no solvent, solid phase) thermolysis (vac., 400°C); sublimation (870°C, 1E-5 torr);
In neat (no solvent) Y compd. transferred to platinum crucible under dry conditions, evacuation temp. raised slowly to 350-400°C, complete decompn. after fewhs.;

: yttrium(III) oxide

: 7782-50-5
chlorine

: 7429-90-5
aluminium

A: 1333-84-2, 1344-28-1
aluminum oxide

B: 10361-92-9
yttrium(III) chloride

Conditions

Conditions	Yield
In neat (no solvent) heating (200°C, vac.; 300°C, 2 d); separated by chemical transport;

...Expand

: yttrium

: 10025-73-7
chromium(III) chloride

A: 7440-47-3
chromium

B: 10361-92-9
yttrium(III) chloride

Conditions

Conditions	Yield
In melt exchange reaction (KCl/NaCl melt, 1073 K);
In melt exchange reaction (KCl-NaCl melt, 1073 K);

...Expand

: yttrium(III) oxide

: 7719-09-7
thionyl chloride

: 10361-92-9
yttrium(III) chloride

Conditions

Conditions	Yield
at 300°C, 1-2 d, sealed tube;

: 75-44-5
phosgene

: yttrium(III) oxide

: 10361-92-9
yttrium(III) chloride

Conditions

Conditions	Yield
In neat (no solvent) passing stream of COCl2 over Y2O3 at 600 °C;;

: yttrium(III) oxide

: 7446-70-0
aluminium trichloride

: 10361-92-9
yttrium(III) chloride

Conditions

Conditions	Yield
In neat (no solvent) vac., 573 K; vapour trasportion;

: 13709-49-4
yttrium(III) fluoride

: 7782-50-5
chlorine

: 10361-92-9
yttrium(III) chloride

Conditions

Conditions	Yield
In neat (no solvent) in streaming Cl2-gas at 200-300°C;;

: 56-23-5
tetrachloromethane

: yttrium(III) oxide

: 10361-92-9
yttrium(III) chloride

Conditions

Conditions	Yield
at 500°C, 6 h;
In neat (no solvent) chlorination of Y2O3 with carbon tetrachloride at 955 K for 10 h; elem. anal.;

: 7647-01-0
hydrogenchloride

: yttrium (III) formate

: 10361-92-9
yttrium(III) chloride

Conditions

Conditions	Yield
With Cl2 In neat (no solvent) 250-300°C, 1 d; Cl2 atm., 600°C;

: 7647-01-0
hydrogenchloride

: yttrium(III) oxide

: 10361-92-9
yttrium(III) chloride

Conditions

Conditions	Yield
In water dissolving Y2O3 in HCl soln.; evapn.;
In neat (no solvent) oxide was treated with concd. HCl; evapd.; residue dissolved in H2O; evapd.;
In hydrogenchloride metal oxide dissolved in slight excess of HCl; solvent evapd.;

: yttrium hexachloro stannate (IV) * 24 water

A: yttrium(III) oxide

B: 10361-92-9
yttrium(III) chloride

C: 7646-78-8
tin(IV) chloride

Conditions

Conditions	Yield
In neat (no solvent) thermic decomposition;;

...Expand

: yttrium(III) oxide

: 7782-50-5
chlorine

: 10361-92-9
yttrium(III) chloride

Conditions

Conditions	Yield
With pyrographite In solid byproducts: CO; at 800°C for 2 h;
With aluminium trichloride; pyrographite In neat (no solvent) chlorinating of rare earth/carbon (molar ration 3/1) mixt. (Cl2 flow rate 20 ml/min, 800 K, 2 h), heating in CO/HCl flow (800-1200 K), chemical vapor transport (AlCl3, 1300 K, 6 h, CO carrier gas, 40 ml/min); atomic emission spectrometric monitoring;
With sucrose carbon In neat (no solvent) byproducts: CO, CO2, O2; mixt. of Y2O3 and sucrose carbon kept under flowing Ar for 1 h and heated at 100°C; Cl2 introduced; mixt. heated in Ar/Cl2 atm. up to 950°C at 3.8°C/min; X-ray diffraction;
With sucrose carbon In further solvent(s) Kinetics; byproducts: CO, CO2; the chlorination kinetics of Y2O3/sucrose carbon studied by thermogravimetry at 550-950°C; Cl2 used in a mixt. with Ar;

: yttrium(III) oxide

: 7440-44-0
pyrographite

: 10361-92-9
yttrium(III) chloride

Conditions

Conditions	Yield
With chlorine byproducts: CO; at 1100°C; YCl3 removed from the reaction zone with a stream of He;
With Cl2 byproducts: CO; at 1100°C; YCl3 removed from the reaction zone with a stream of He;

: yttrium chloride*99H2O

: 10361-92-9
yttrium(III) chloride

Conditions

Conditions	Yield
With ammonium chloride In neat (no solvent) heating of mixt. of YCl3-hydrate and NH4Cl in Cl2/HCl stream;

: yttrium(III) oxide

: 10361-92-9
yttrium(III) chloride

Conditions

Conditions	Yield
In neat (no solvent) 300°C, 2 d;;
In neat (no solvent) 300°C, 2 d;;

: YBa2 cuprate

A: 10361-92-9
yttrium(III) chloride

B: barium(II) chloride

C: copper dichloride

Conditions

Conditions	Yield
With HCl In hydrogenchloride byproducts: O2, H2O; dissolution in excess concd. HCl;

...Expand

: YBa2 cuprate

A: 10361-92-9
yttrium(III) chloride

B: barium(II) chloride

C: copper dichloride

Conditions

Conditions	Yield
With HCl In hydrogenchloride byproducts: O2, H2O; dissolution in excess concd. HCl;

...Expand

: YBa2 cuprate

A: 10361-92-9
yttrium(III) chloride

B: barium(II) chloride

C: copper dichloride

Conditions

Conditions	Yield
With HCl In hydrogenchloride byproducts: O2, H2O; dissolution in excess concd. HCl;

...Expand

: YBa2 cuprate

A: 10361-92-9
yttrium(III) chloride

B: barium(II) chloride

C: copper dichloride

Conditions

Conditions	Yield
With HCl In hydrogenchloride byproducts: O2, H2O; dissolution in excess concd. HCl;

...Expand

: yttrium(III) trifluoromethanesulfonate

A: 353-50-4
Carbonyl fluoride

B: 10361-92-9
yttrium(III) chloride

Conditions

Conditions	Yield
byproducts: SO2; above 400°C;
byproducts: SO2; above 400°C;

: yttrium(III) trifluoromethanesulfonate

: 10361-92-9
yttrium(III) chloride

Conditions

Conditions	Yield
thermal decompn. at 500-1000°C;
thermal decompn. at 500-1000°C;
thermal decompn. at 500-1000°C;

: YCl3*2(acetylacetone imine)

A: 1118-66-7
4-amino-3-penten-2-one

B: 10361-92-9
yttrium(III) chloride

Conditions

Conditions	Yield
In neat (no solvent) 335°C; thermogravimetric anal.;

: YBa2 cuprate

A: 10361-92-9
yttrium(III) chloride

B: barium(II) chloride

C: copper dichloride

Conditions

Conditions	Yield
With HCl In hydrogenchloride byproducts: O2, H2O; dissolution in excess concd. HCl;

...Expand

: 101750-31-6
Y((SiMe3)2)2Cl(tetrahydrofuran)2

A: bis(trimethylsilyl)amide yttrium(III)

B: 10361-92-9
yttrium(III) chloride

Conditions

Conditions	Yield
byproducts: THF; decompn. in absence of THF;

: 6389-79-3
methyl methylphenylphosphinate

: 10361-92-9
yttrium(III) chloride

: Y(3+)*3C7H8O2P(1-)=Y(C7H8O2P)3

Conditions

Conditions	Yield
In further solvent(s) byproducts: MeCl; slow heating in neat Ph(Me)P(O)OMe until complete pptn.; particle size and polymerization degree depending on heating rate;	100%
In not given byproducts: chloromerhane; heating with the excess of methylphenylphosphinic acid methyl ester; filtering, washing with ethanol;

: 7732-18-5
water

: 10361-92-9
yttrium(III) chloride

: 10028-70-3
disodium terephthalate

: [Y2(benzene-1,4-dicarboxylate)3(H2O)4]

Conditions

Conditions	Yield
In water stoich., YCl3 and 1,4-benzenedicarboxylate disodium salt mixed in H2O atroom temp.; filtered, dried (air), elem. anal.;	100%
In water stoich. amt. of YCl3 and Na salt of terephthalic acid mixed in H2O; filtered; ppt. dried in air; detd. by X-ray powder diffraction and inductively coupled plasma-atomic emission spectra;

...Expand

: 10138-41-7
erbium(III) chloride

: 7732-18-5
water

: 10361-92-9
yttrium(III) chloride

: 10028-70-3
disodium terephthalate

: ErY(1,4-benzenedicarboxylate)(H2O)4

Conditions

Conditions	Yield
In water stoich., ErCl3, YCl3 and 1,4-benzenedicarboxylate disodium salt mixed inH2O at room temp.; filtered, dried (air), elem. anal.;	100%

...Expand

: 10138-41-7
erbium(III) chloride

: 7732-18-5
water

: 10361-92-9
yttrium(III) chloride

: 10028-70-3
disodium terephthalate

: Er1.6Y0.4(1,4-benzenedicarboxylate)(H2O)4

Conditions

Conditions	Yield
In water stoich., ErCl3, YCl3 and 1,4-benzenedicarboxylate disodium salt mixed inH2O at room temp.; filtered, dried (air), elem. anal.;	100%

...Expand

: 10138-41-7
erbium(III) chloride

: 7732-18-5
water

: 10361-92-9
yttrium(III) chloride

: 10028-70-3
disodium terephthalate

: Er0.4Y1.6(1,4-benzenedicarboxylate)(H2O)4

Conditions

Conditions	Yield
In water stoich., ErCl3, YCl3 and 1,4-benzenedicarboxylate disodium salt mixed inH2O at room temp.; filtered, dried (air), elem. anal.;	100%

...Expand

: 10138-41-7
erbium(III) chloride

: 7732-18-5
water

: 10361-92-9
yttrium(III) chloride

: 10028-70-3
disodium terephthalate

: Er0.2Y1.8(1,4-benzenedicarboxylate)(H2O)4

Conditions

Conditions	Yield
In water stoich., ErCl3, YCl3 and 1,4-benzenedicarboxylate disodium salt mixed inH2O at room temp.; filtered, dried (air), elem. anal.;	100%

...Expand

: yttrium(III) isopropoxide

: 10361-92-9
yttrium(III) chloride

: Y(3+)*2Cl(1-)*OCH(CH3)2(1-)*1.5(CH3)2CHOH=YCl2(OCH(CH3)2)*1.5(CH3)2CHOH

Conditions

Conditions	Yield
In isopropyl alcohol byproducts: isopropyl acetate; molar ratio chloride:isopropoxide=2:1, refluxing; solvent removal (reduced pressure), drying (28°C, 0.1 torr); elem. anal.;	99.9%

: 10361-92-9
yttrium(III) chloride

: 1066-33-7
ammonium bicarbonate

: yttrium carbonate * 2.79 H2O

Conditions

Conditions	Yield
In water byproducts: CO2, NH4Cl, H2O; to stirred soln. of YCl3 (5 mmol) was added NH4HCO3 (15 mmol) at 25° C; the soln. was maintained at 25°C for 1 wk; the resulting ppt. was filtered, washed with H2O and air-dried; chem. anal.;	99.24%

: yttrium(III) isopropoxide

: 10361-92-9
yttrium(III) chloride

: Y(3+)*Cl(1-)*2OCH(CH3)2(1-)*(CH3)2CHOH=YCl(OCH(CH3)2)2*(CH3)2CHOH

Conditions

Conditions	Yield
In isopropyl alcohol byproducts: isopropyl acetate; molar ratio chloride:isopropoxide=1:2, refluxing; solvent removal (reduced pressure), drying (28°C, 0.1 torr); elem. anal.;	99.2%

: 10361-92-9
yttrium(III) chloride

: yttrium

Conditions

Conditions	Yield
With lithium In neat (no solvent) reduction of YCl3 (distd. in vac. at 900-950°C), 16.56kg YCl3, 2.040 kg Li (15.5% excess);;	99%
With calcium In neat (no solvent) YCl3 free from H2O and oxide-halogenides, 10% excess Ca, under Ar, start of react. at 1350-1400.degreee.C;; heating to 1550°C for 5min after end of react., purity 99.-+.0.5%;;	90%
With sodium In neat (no solvent) distn. of Na into a vessel containing YCl3 at 800-850°C and 0.07 atm Ar-pressure, 5-7h at 800-850°C, pouring off NaCl-slag;; distn. at 850°C; contaminations in wt.-%: 0.012-0.090 O, 0.002-0.03 N, 0.01-0.03 C;;	85%

: niobium

: potassium chloride

: 10361-92-9
yttrium(III) chloride

: 10026-12-7
niobium pentachloride

: potassium yttrium hexaniobium octadecachloride

Conditions

Conditions	Yield
In neat (no solvent) Ar, stoichiometric mixture sealed in a quartz tube, heated at 1023 K for4 d, the heating and cooling ramps were 20 and 10 Kh*-1, respectively;	99%

...Expand

: benzene 1,3,5-tricarboxylic acid, ammonium salt

: 10361-92-9
yttrium(III) chloride

: Y trimesate

Conditions

Conditions	Yield
In not given hot soln.;	99%
In not given hot soln.;	99%

: dipotassium tetracyanopalladate(II)

: 10361-92-9
yttrium(III) chloride

: 10(CH3)2NCHO*2Y(3+)*3Pd(CN)4(2-)=((CH3)2NCHO)10Y2[Pd(CN)4]3

Conditions

Conditions	Yield
In N,N-dimethyl-formamide byproducts: KCl; YCl3 and Pd-complex were stirred in DMF at room temp. over 5 ds; filtered, DMF was pumped, 24 h at room temp., dried under vac. for 12-14h; elem. anal.;	99%

: 109-99-9
tetrahydrofuran

: 507-52-8
2-(trifluoromethyl)-2-propanol

: 10361-92-9
yttrium(III) chloride

: 2Na(1+)*Y(3+)*5OC(CH3)2CF3(1-)*C4H8O=Na2Y(OC(CH3)2CF3)5(C4H8O)

Conditions

Conditions	Yield
With NaH In tetrahydrofuran byproducts: NaCl; inert atmosphere; treatment of 6 equiv. of ligand with slight excess ofNaH, filtration, addn. to suspn. of YCl3, refluxing for 24 h; solvent removal (vac.), dissoln. in MePh, filtration (Celite), concn., crystn. (-30°C); elem. anal.;	99%

...Expand

: 52687-02-2
sodium 2-(N,N-dimethylaminomethyl)phenolate

: 10361-92-9
yttrium(III) chloride

: [ClY(μ-OC6H4(CH2NMe2)-2)3Y(OC6H4(CH2NMe2)-2)3Na]

Conditions

Conditions	Yield
In tetrahydrofuran byproducts: NaCl; N2-atmosphere; dropwise addn. of 3 equiv. ligand to metal chloride (roomtemp.), stirring overnight; solvent removal (vac.), extn. into CH2Cl2, solvent removal (vac.), washing (pentane); elem. anal.;	99%

Yttrium(III) chloride Chemical Properties

IUPAC Name: Trichloroyttrium
The MF of Yttrium(III) chloride (CAS NO.10361-92-9) is Cl₃Y.

The MW of Yttrium(III) chloride (CAS NO.10361-92-9) is 195.26.
Synonyms of Yttrium(III) chloride (CAS NO.10361-92-9): Yttrium chloride ; Yttrium chloride (YCl3) ; Yttrium chloride solution ; Yttrium trichloride
Product Categories: Inorganics;Catalysis and Inorganic Chemistry;Chemical Synthesis;Crystal Grade Inorganics;Metal and Ceramic Science;Salts;Yttrium Salts
Density: 2.67 g/mL at 25 °C
Melting Point: 721 °C
Storage temp: 2-8 °C
Sensitive: Hygroscopic
EINECS: 1036-192-9
Merck: 14,10107
Form: powder

Yttrium(III) chloride Uses

Yttrium(III) chloride (CAS NO.10361-92-9) is used as analytical reagent.It is also used as a catalyst and in superconductors and has been linked to pulmonary edema and liver damage.

Yttrium(III) chloride Production

Yttrium(III) chloride can be formed by reacting yttrium(III) oxide with hydrochloric acid, among other methods.

Yttrium(III) chloride Toxicity Data With Reference

1.	ipr-rat LD50:45 mg/kg	AMIHAB AMA Archives of Industrial Health. 16 (1957),475.
2.	ipr-mus LD50:88 mg/kg	AMIHAB AMA Archives of Industrial Health. 16 (1957),475.
3.	ipr-gpg LD50:85 mg/kg	AEHLAU Archives of Environmental Health. 5 (1962),437.

Yttrium(III) chloride Consensus Reports

Reported in EPA TSCA Inventory.

Yttrium(III) chloride Safety Profile

Poison by intraperitoneal route. When heated to decomposition it emits toxic fumes of Cl⁻. See also YTTRIUM and RARE EARTHS.Safety information of Yttrium(III) chloride (CAS NO.10361-92-9):
Hazard Codes Irritant Xi
Risk Statements
36/37/38 Irritating to eyes, respiratory system and skin
Safety Statements
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
37/39 Wear suitable gloves and eye/face protection
WGK Germany 3
RTECS ZG3150000

Yttrium(III) chloride Standards and Recommendations

ACGIH TLV: TWA 1 mg(Y)/m³

Yttrium(III) chloride Specification

Yttrium(III) chloride is an ionic compound of yttrium and chlorine. It is a salt that is solid at room temperature, highly soluble in water, and deliquescent. YCl₃ in the solid state has a crystal structure with cubic close packed chloride ions and yttrium ions filling one third of the octahedral holes and the resulting YCl₆ octahedra sharing three edges with adjacent octahedra give a layer structure. This structure is shared by a range of compounds notably AlCl₃

Product Name

YTTRIUM CHLORIDE

Synthetic route

Yttrium(III) chloride Chemical Properties

Yttrium(III) chloride Uses

Yttrium(III) chloride Production

Yttrium(III) chloride Toxicity Data With Reference

Yttrium(III) chloride Consensus Reports

Yttrium(III) chloride Safety Profile

Yttrium(III) chloride Standards and Recommendations

Yttrium(III) chloride Specification

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