Zinc phthalocyanine supplier | CasNO.14320-04-8

Name
ZINC PHTHALOCYANINE
EINECS 238-262-5
CAS No. 14320-04-8
Article Data57
CAS DataBase
Density 1.614-1.62g/cm3 at 20℃
Solubility Insoluble in water.
Melting Point
Formula C₃₂H₁₆N₈Zn
Boiling Point
Molecular Weight 577.923
Flash Point
Transport Information
Appearance purple powder
Safety 22-24/25
Risk Codes
Molecular Structure
Hazard Symbols
Synonyms Zinc, [29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]-, (SP-4-1)-;Zinc, [phthalocyaninato(2-)]- (8CI);29H,31H-Phthalocyanine, zinc complex;29H,31H-Phthalocyanine, zinc deriv.;CGP 55847;Ciaftalan zinc;Phthalocyaninatozinc;Zinc phthalocyanine complex;Zinc(2+) phthalocyaninate;Zinc(II) phthalocyanine;Phthalocyanine,zinc deriv. (6CI);
PSA 99.94000
LogP 1.14850

Synthetic route

: 91-15-6
phthalonitrile

: 7440-66-6
zinc

: 14320-04-8
zinc(II) phthalocyanine

Conditions

Conditions	Yield
With sodium methylate In methanol Sonication; Zn added to a methanol soln. containing an equivalent quantity of phthalonitrile and 5 drops of 30% soln of CH3ONa in methanol; flask put into an ultrasonic cleaner and maintained at 50°C for 24-72 h; blue product separated from unreacted metal by shaking and decanting with the solvent, washed with ethanol in Soxhlet equipment and dried in air; purity of 95-97%; elem. anal.;	100%
With sodium methylate In further solvent(s) Sonication; Zn added to an 1-octanol soln. containing an equivalent quantity of phthalonitrile and 5 drops of 30% soln of CH3ONa in methanol; flask put intoan ultrasonic cleaner and maintained at 50°C for 24-72 h; blue product separated from unreacted metal by shaking and decanting with the solvent, washed with ethanol in Soxhlet equipment and dried in air; purity of 95-97%; elem. anal.;	100%
With sodium methylate In methanol Sonication; Zn added to a methanol soln. containing an equivalent quantity of phthalonitrile and 5 drops of 30% soln of CH3ONa in methanol; flask put into an ultrasonic cleaner and maintained at 40°C for 24-72 h; blue product separated from unreacted metal by shaking and decanting with the solvent, washed with ethanol in Soxhlet equipment and dried in air; purity of 95-97%; elem. anal.;	85%

: 5970-45-6
zinc(II) acetate dihydrate

: 91-15-6
phthalonitrile

: 14320-04-8
zinc(II) phthalocyanine

Conditions

Conditions	Yield
In N,N-dimethyl-formamide at 200℃; for 0.166667h; Microwaves;	95%
In N,N-dimethyl-formamide other Radiation; to mixt. Zn(OAc)2*2H2O and phthalonitrile DMF was added and heated in microwave Discover CEM reactor to 200°C for 10 min in sealed tube; Soxhlet extraction with acetone, CH2Cl2, and MeCN followed by recrystn. from pyridine;	95%
In N,N-dimethyl-formamide at 110℃; under 7500.75 Torr; for 0.00694444h; Pressure; Microwave irradiation;	92%
With butyl(2-hydroxyethyl)dimethylammonium acetate at 100℃; for 2h; Ionic liquid; Inert atmosphere;	86%

: 5970-45-6
zinc(II) acetate dihydrate

: 574-93-6
29H,31H-Phthalocyanine

: 14320-04-8
zinc(II) phthalocyanine

Conditions

Conditions	Yield
With butyl(2-hydroxyethyl)dimethylammonium acetate at 100℃; Ionic liquid; Inert atmosphere;	92%
With tributyl-amine In pentan-1-ol at 160℃; for 2h; Inert atmosphere;	26 mg

: 91-15-6
phthalonitrile

: 14320-04-8
zinc(II) phthalocyanine

Conditions

Conditions	Yield
With zinc diacetate In nitrobenzene for 5h; Reflux;	83%

: 557-34-6
zinc diacetate

: 91-15-6
phthalonitrile

: 14320-04-8
zinc(II) phthalocyanine

Conditions

Conditions	Yield
With sodium methylate In tetrahydrofuran 3 equiv. NaOMe, 20 °C, stirring for 7 days, addn. of metal salt,stirring for 3 days;	82%
With 1,8-diazabicyclo[5.4.0]undec-7-ene In pentan-1-ol under N2, 1,8-diazabicyclo(5.4.0)undec-7-ene (5 mmol) added to C6H4(CN)2(5 mmol) and Zn(CH3COO)2 (1.25 mmol) soln., heated for 36 h under reflu x; D. Woehrle, G. Schnurpfel, G. Knothe, Dyes Pigm. 18, 91 (1992); MeOH added, washed (with H2O and MeOH), treated with MeOH in Soxhlet apparatus overnight, dried.; purified by sublimation in vac. at 370°C;	75%
With 1,8-diazabicyclo[5.4.0]undec-7-ene In pentan-1-ol for 12h; Inert atmosphere; Reflux;	48%
With 1,8-diazabicyclo[5,4,0]undec-7-ene In pentan-1-ol reflux; filtration, washing (water), extraxting with MeOH in a Soxhilet apparatus, zone sublimation at 1E-7 - 1E-6 mbar at 370 °C;
In ethanol at 160℃; for 6h; Solvent; Autoclave; High pressure; Green chemistry;

: 91-15-6
phthalonitrile

: 7646-85-7
zinc(II) chloride

: 14320-04-8
zinc(II) phthalocyanine

Conditions

Conditions	Yield
With 1,8-diazabicyclo{5.4.0}undec-7-ene In pentan-1-ol a mixt. of the Cu salt, phthalonitrile, and the base (molar ratio 2.5:10:10) was refluxed in n-pentanol for 6 h;; the ppt. was filtered off, washed with 3% HCl soln., water, and ethanol and purified by extrn. with CHCl3; IR, UV, XRD, and elem.anal.;;	74%
With hydroquinone Thompson, J. A.; Murata, K.; Miller, D. C.; Stanton, J. L.; Broderick, W. E.; Hoffmann, B. M.; Ibers, J. A. Inorg. Chem. 1993, 32, 3546;; Soxhlet extn. with water and then acetone for 24 h each;
With ammonia; hexaammonium heptamolybdate tetrahydrate In nitrobenzene mixt. of o-phthalodinitrile, ZnCl2, nitrobenzene, ammonium molybdate, and ammonia stirred (6 h); refluxed; stripped with ammonia; filtered; washed with methanol; pptd. from 96 % H2SO4;
With 1,8-diazabicyclo[5.4.0]undec-7-ene In pentan-1-ol at 140℃; for 2h; Inert atmosphere;	263 mg
With ammonium hydroxide In dimethyl sulfoxide at 180 - 190℃; for 5h;

: 14024-63-6
zinc(II) acetylacetonate

: 91-15-6
phthalonitrile

: 14320-04-8
zinc(II) phthalocyanine

Conditions

Conditions	Yield
With 1,8-diazabicyclo{5.4.0}undec-7-ene In pentan-1-ol a mixt. of the Cu salt, phthalonitrile, and the base (molar ratio 2.5:10:10) was refluxed in n-pentanol for 6 h;; the ppt. was filtered off, washed with 3% HCl soln., water, and ethanol and purified by extrn. with CHCl3; IR, UV, XRD, and elem.anal.;;	58%

: 63368-36-5
ortho-methylbenzyltriphenylphosphonium chloride

: 91-15-6
phthalonitrile

: 7440-66-6
zinc

: 14320-04-8
zinc(II) phthalocyanine

: 1586046-62-9
27-(2-methylphenyl)tetrabenzo[b,g,l,q][5,10,15]triazaporphyrinato zinc

Conditions

Conditions	Yield
at 200 - 300℃; for 6h; Inert atmosphere;	A 25% B 11%

...Expand

: 887928-88-3
5,6-dicyano-2-(4-(triisopropylsilylethynyl)phenyl)-1-propylbenzimidazole

: 91-15-6
phthalonitrile

: 7646-85-7
zinc(II) chloride

: 14320-04-8
zinc(II) phthalocyanine

: 887928-95-2
tribenzo[g,l,q]-(2-{4-(2-triisopropylsilylethynyl)phenyl}-1-propylbenzimidazo[5,6-b])porphyrazinatozinc(II)

: 887928-99-6
dibenzo[g,q]-(2-{4-(2-triisopropylsilylethynyl)phenyl}-1-propylbenzimidazo[5,6-b:5',6'-l])porphyrazinatozinc(II)-C2v

Conditions

Conditions	Yield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In pentan-1-ol for 12h; Inert atmosphere; Reflux;	A 4% B 22% C 1%

...Expand

: C36H16Br2N4O2

: 557-34-6
zinc diacetate

: 91-15-6
phthalonitrile

: 14320-04-8
zinc(II) phthalocyanine

: C52H24Br2N8O2Zn

: C72H32Br4N8O4Zn

Conditions

Conditions	Yield
In N,N-dimethyl-formamide; 1,2-dichloro-benzene at 150 - 160℃; Inert atmosphere;	A n/a B 21% C n/a

...Expand

: 1104643-15-3
C6H2(O(CH2CH2O)2CH3)2(CN)2

: 5970-45-6
zinc(II) acetate dihydrate

: 91-15-6
phthalonitrile

: 14320-04-8
zinc(II) phthalocyanine

: 1104908-96-4
ZnPc[O(CH2CH2O)2Me]2

Conditions

Conditions	Yield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In pentan-1-ol phthalonitrile (2.0 mmol) was treated with unsubstituted phthalonitrile (18.0 mmol) and Zn-contg. compd. (5.0 mmol) in pentanol at 140-150°C for 24 h, then a small amt. of DBU was added; brief cooling; volatiles were removed under reduced pressure; residue was dissolved in CHCl3; soln. was filtered to remove ZnPc; filtrate was collected, evapd.to dryness in vac.; column chromy. (silica gel, CHCl3/CH3OH); recrystn. from THF/hexane; elem. anal.;	A n/a B 15%

Yield

With 1,8-diazabicyclo[5.4.0]undec-7-ene In pentan-1-ol phthalonitrile (2.0 mmol) was treated with unsubstituted phthalonitrile (18.0 mmol) and Zn-contg. compd. (5.0 mmol) in pentanol at 140-150°C for 24 h, then a small amt. of DBU was added; brief cooling; volatiles were removed under reduced pressure; residue was dissolved in CHCl3; soln. was filtered to remove ZnPc; filtrate was collected, evapd.to dryness in vac.; column chromy. (silica gel, CHCl3/CH3OH); recrystn. from THF/hexane; elem. anal.;

A n/a
B 15%

...Expand

: C6H3(CN)2O(CH2CH2O)4CHCHCH(OC(CH3)2O)OCHCHOC(CH3)2OCH2

: 5970-45-6
zinc(II) acetate dihydrate

: 91-15-6
phthalonitrile

: 14320-04-8
zinc(II) phthalocyanine

: Zn(C8H4N2)3(C8H3N2O(CH2CH2O)4CHCHCH(OC(CH3)2O)OCHCHOC(CH3)2OCH2)

Conditions

Conditions	Yield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In pentan-1-ol (N2); heating a mixt. of zinc salt with dinitriles in n-pentanol to 100°C, addn. of DBU, stirring at 140-150°C for 24 h, cooling; evapn. in vac., dissolving in CHCl3, filtration, evapn. in vac., column chromy. (silica gel, CHCl3/methanol 30:1 vol.), size exclusion chromy. (Bio-Rad Bio-Beads S-X1, THF), recrystn. (THF/hexane);	A n/a B 15%

...Expand

: 1104643-17-5
3,6-bis(2-(2-[2-(2-hydroxyethoxy)ethoxy]ethoxy)ethoxy)phthalonitrile

: 5970-45-6
zinc(II) acetate dihydrate

: 91-15-6
phthalonitrile

: 14320-04-8
zinc(II) phthalocyanine

: 1104909-03-6
ZnPc[O(CH2CH2O)4H]2

Conditions

Conditions	Yield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In pentan-1-ol phthalonitrile (0.98 mmol) was treated with unsubstituted phthalonitrile(8.82 mmol) and Zn-contg. compd. (2.46 mmol) in pentanol at 140-150.deg ree.C for 24 h, then a small amt. of DBU was added; brief cooling; volatiles were removed under reduced pressure; residue was dissolved in CHCl3; soln. was filtered to remove ZnPc; filtrate was collected, evapd.to dryness in vac.; column chromy. (silica gel, CHCl3/CH3OH); recrystn. from THF/hexane; elem. anal.;	A n/a B 14%

Yield

With 1,8-diazabicyclo[5.4.0]undec-7-ene In pentan-1-ol phthalonitrile (0.98 mmol) was treated with unsubstituted phthalonitrile(8.82 mmol) and Zn-contg. compd. (2.46 mmol) in pentanol at 140-150.deg ree.C for 24 h, then a small amt. of DBU was added; brief cooling; volatiles were removed under reduced pressure; residue was dissolved in CHCl3; soln. was filtered to remove ZnPc; filtrate was collected, evapd.to dryness in vac.; column chromy. (silica gel, CHCl3/CH3OH); recrystn. from THF/hexane; elem. anal.;

A n/a
B 14%

...Expand

: C6H2(O(CH2CH2O)12CH3)2(CN)2

: 5970-45-6
zinc(II) acetate dihydrate

: 91-15-6
phthalonitrile

: 14320-04-8
zinc(II) phthalocyanine

: ZnPc[O(CH2CH2O)12Me]2

Conditions

Conditions	Yield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In pentan-1-ol phthalonitrile (0.47 mmol) was treated with unsubstituted phthalonitrile(4.14 mmol) and Zn-contg. compd. (1.14 mmol) in pentanol at 140-150.deg ree.C for 24 h, then a small amt. of DBU was added; brief cooling; volatiles were removed under reduced pressure; residue was dissolved in CHCl3; soln. was filtered to remove ZnPc; filtrate was collected, evapd.to dryness in vac.; column chromy. (silica gel, CHCl3/CH3OH); recrystn. from THF/hexane;	A n/a B 13%

Yield

With 1,8-diazabicyclo[5.4.0]undec-7-ene In pentan-1-ol phthalonitrile (0.47 mmol) was treated with unsubstituted phthalonitrile(4.14 mmol) and Zn-contg. compd. (1.14 mmol) in pentanol at 140-150.deg ree.C for 24 h, then a small amt. of DBU was added; brief cooling; volatiles were removed under reduced pressure; residue was dissolved in CHCl3; soln. was filtered to remove ZnPc; filtrate was collected, evapd.to dryness in vac.; column chromy. (silica gel, CHCl3/CH3OH); recrystn. from THF/hexane;

A n/a
B 13%

...Expand

: 1104643-16-4
C6H2(O(CH2CH2O)4CH3)2(CN)2

: 5970-45-6
zinc(II) acetate dihydrate

: 91-15-6
phthalonitrile

: 14320-04-8
zinc(II) phthalocyanine

: 1104908-99-7
ZnPc[O(CH2CH2O)4Me]2

Conditions

Conditions	Yield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In pentan-1-ol phthalonitrile (1.0 mmol) was treated with unsubstituted phthalonitrile (9.0 mmol) and Zn-contg. compd. (2.5 mmol) in pentanol at 140-150°C for 24 h, then a small amt. of DBU was added; brief cooling; volatiles were removed under reduced pressure; residue was dissolved in CHCl3; soln. was filtered to remove ZnPc; filtrate was collected, evapd.to dryness in vac.; column chromy. (silica gel, CHCl3/CH3OH); recrystn. from THF/hexane;	A n/a B 12%

Yield

With 1,8-diazabicyclo[5.4.0]undec-7-ene In pentan-1-ol phthalonitrile (1.0 mmol) was treated with unsubstituted phthalonitrile (9.0 mmol) and Zn-contg. compd. (2.5 mmol) in pentanol at 140-150°C for 24 h, then a small amt. of DBU was added; brief cooling; volatiles were removed under reduced pressure; residue was dissolved in CHCl3; soln. was filtered to remove ZnPc; filtrate was collected, evapd.to dryness in vac.; column chromy. (silica gel, CHCl3/CH3OH); recrystn. from THF/hexane;

A n/a
B 12%

...Expand

: 574-93-6
29H,31H-phthalocyanine

: 557-34-6
zinc diacetate

: 14320-04-8
zinc(II) phthalocyanine

Conditions

Conditions	Yield
In acetonitrile Kinetics; byproducts: CH3COOH; at 298 K;
In not given prepd. by Barrett, P. A.; Dent, C. E.; Linstead, R. P.: J. Chem. Soc. (London) 1936, 1719;

: 32703-80-3
4-(t-butyl)phthalonitrile

: 91-15-6
phthalonitrile

: 14320-04-8
zinc(II) phthalocyanine

: 118681-06-4
Zn(II) mono-2-(t-butyl)phthalocyanine

Conditions

Conditions	Yield
In not given from phthalonitrile and 4-tert-butylphthalonitrile using the usual template react. technique (Moser and Thomas, Phthalocyanines, CRC Press, Florida (1983), Vol.II, Chap.1); refluxing with acetone after react. (2 h), filtration from insol. ZnPc (washing with acetone and 5%aq. HCl for prepn.), washing (several times, hot acetone), evapn. of filtrate to dryness, purifn. (chromy. on silica, diethylether as eluent); elem. anal.;

Yield

In not given from phthalonitrile and 4-tert-butylphthalonitrile using the usual template react. technique (Moser and Thomas, Phthalocyanines, CRC Press, Florida (1983), Vol.II, Chap.1); refluxing with acetone after react. (2 h), filtration from insol. ZnPc (washing with acetone and 5%aq. HCl for prepn.), washing (several times, hot acetone), evapn. of filtrate to dryness, purifn. (chromy. on silica, diethylether as eluent); elem. anal.;

...Expand

: 91-15-6
phthalonitrile

: zinc(II) oxide

: 14320-04-8
zinc(II) phthalocyanine

Conditions

Conditions	Yield
In further solvent(s) at 220°C in Soltrol 220;

: 10196-18-6
zinc(II) nitrate

: 91-15-6
phthalonitrile

: 14320-04-8
zinc(II) phthalocyanine

Conditions

Conditions	Yield
In methanol React. at 90°C, 9-12 kbar, for 16-24 h in presence of hydroquinone.; Extg. with MeOH and acetone, sublimed in vac.;	13-28

: zinc(II) cation

: 91-15-6
phthalonitrile

: 14320-04-8
zinc(II) phthalocyanine

Conditions

Conditions	Yield
In not given react. of phthalonitrile with Zn(2+); washing, sublimation;

: 56174-38-0
dioxocyclopentakis(1-iminoisoindolinato)uranium(VI)

: 7646-85-7
zinc(II) chloride

: 14320-04-8
zinc(II) phthalocyanine

Conditions

Conditions	Yield
In methanol soln. of ZnCl2 in acetone mixed with soln. of superphthalocyanine in 1-chloronaphthalene; reaction monitored by electronic absorption spectroscopy;;

: 22856-30-0
2,3-dicyanonaphthalene

: 557-34-6
zinc diacetate

: 91-15-6
phthalonitrile

: 14320-04-8
zinc(II) phthalocyanine

: 143434-13-3
cis zinc dibenzodinaphthotetraazaporphyrine

: 143566-49-8
trans zinc dibenzodinaphthotetraazaporphyrine

: 143566-48-7
zinc mononaphthotribenzotetraazaporphyrine

: 143566-50-1
zinc monobenzotrinaphthotetraazaporphyrine

Conditions

Conditions	Yield
In neat (no solvent) heated for 5 min at 270°C; further products; allowed to cool; dissolved in THF; filtered off; solution passed through an alumina column; dried; dissolved in THF; left for 4 days at 0°C; precipitate filtered; recrystn. (THF); filtrate was applied on a column (GPC, eluent: THF); elem.anal.;

...Expand

: zinc(II) sulfate heptahydrate

: 154724-25-1
bromo(phthalocyaninato)bismuth(III)

: 14320-04-8
zinc(II) phthalocyanine

Conditions

Conditions	Yield
In dimethyl sulfoxide dry and distd. solvents; addn. of DMSO soln. of Zn-compd. to Bi(pc)Br (molar ratio 30:1); detn. by UV-spectroscopy;

: 85-44-9
phthalic anhydride

: 557-34-6
zinc diacetate

: 57-13-6
urea

: 552-30-7
trimellitic Anhydride

: 14320-04-8
zinc(II) phthalocyanine

: 912562-84-6
zinc 2-carboxyl-29H,31H-phthalocyanine

Conditions

Conditions	Yield
With potassium hydroxide; ammonium molybdate; ammonium chloride In not given byproducts: polycarboxy substituted phtalocyanine zinc; trimellitic anhydride and phthalic anhydride (1:7) in presence of urea, zinc acetate and ammonium molybdate reacted at 170°C for 4 h; mixture then hydrolysed under alkaline condition; purified by HPLC column chromy. (silica gel/DMF:acetone (3:1));

...Expand

: 1448688-96-7
4-(4-((trimethylsilyl)ethynyl)phenoxy)phthalonitrile

: 5970-45-6
zinc(II) acetate dihydrate

: 91-15-6
phthalonitrile

: 14320-04-8
zinc(II) phthalocyanine

2-(4-(ethynyl)phenoxy)-phthalocyaninato zinc(II): 2-(4-(ethynyl)phenoxy)-phthalocyaninato zinc(II)

Conditions

Conditions	Yield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In octanol at 130℃; for 2h;	A n/a B 23 %Spectr.
With 1,8-diazabicyclo[5.4.0]undec-7-ene at 130℃; for 15h; Overall yield = 25 %; Overall yield = 400 mg;

...Expand

: C32H17N8SZn(1-)

: 14320-04-8
zinc(II) phthalocyanine

Conditions

Conditions	Yield
With acetic acid In tetrahydrofuran; dimethyl sulfoxide Inert atmosphere;

: 3-(3,4-dicyanophenoxy)benzoic acid

: 5970-45-6
zinc(II) acetate dihydrate

: 91-15-6
phthalonitrile

: 14320-04-8
zinc(II) phthalocyanine

: 1041187-54-5
zinc(II) 3-(4-phenoxycarboxylic acid)phthalocyanine

Conditions

Conditions	Yield
With 1,8-diazabicyclo[5.4.0]undec-7-ene at 130℃; for 15h; Overall yield = 43 %; Overall yield = 1.15 g;

...Expand

: 189691-53-0
4-(4-aminophenoxy)-1,2-dicyanobenzene

: 5970-45-6
zinc(II) acetate dihydrate

: 91-15-6
phthalonitrile

: 14320-04-8
zinc(II) phthalocyanine

: 1282522-35-3
2-(4-(amino)phenoxy)phthalocyaninato zinc(II)

Conditions

Conditions	Yield
With 1,8-diazabicyclo[5.4.0]undec-7-ene at 130℃; for 15h; Overall yield = 35 %; Overall yield = 950 mg;

...Expand

: 85-44-9
phthalic anhydride

: 557-34-6
zinc diacetate

: 57-13-6
urea

: 552-30-7
trimellitic Anhydride

: 14320-04-8
zinc(II) phthalocyanine

: 912562-83-5
2-formamidophthalocyanine zinc

Conditions

Conditions	Yield
With ammonium molybdate; ammonium chloride at 170℃; for 4h;

...Expand

: 85-44-9
phthalic anhydride

: 7646-85-7
zinc(II) chloride

: 14320-04-8
zinc(II) phthalocyanine

Conditions

Conditions	Yield
With ammonium molibdate; sodium carbonate; ammonium chloride at 280℃;

: 14320-04-8
zinc(II) phthalocyanine

: 157131-39-0
1,3,5-tris{2-(pyridin-4-yl)-vinyl}benzene

: 1039768-31-4
[Ru2(η6-p-cymene)2(C6H2O4)Cl2]

: 2923-28-6
silver trifluoromethanesulfonate

: [Zn-phthalocyanine*Ru6(p-cymene)6(1,3,5-tris{2-(pyridin-4-yl)-vinyl}benzene)2(μ-2,5-dioxido-1,4-benzoquinonato)3][trifluoromethanesulfonate]6

Conditions

Conditions	Yield
In methanol for 24h; Reflux;	90%

...Expand

: 14320-04-8
zinc(II) phthalocyanine

: 1,2,4,5-tetrakis{2-(pyridin-4-yl)vinyl}benzene

: (η6-p-cymRu)2(μ4-5,8-dihydroxy-1,4-naphthoquinone)Cl2

: 2923-28-6
silver trifluoromethanesulfonate

: [Zn-phthalocyanine*Ru8(p-cymene)8(1,2,4,5-tetrakis{2-(pyridin-4-yl)vinyl}benzene)2(μ-5,8-dioxido-1,4-naphthoquinonato)4][trifluoromethanesulfonate]8

Conditions

Conditions	Yield
In methanol for 24h; Reflux;	72%

...Expand

: 14320-04-8
zinc(II) phthalocyanine

: 574-93-6
29H,31H-Phthalocyanine

Conditions

Conditions	Yield
With pyridine; pyridine hydrochloride for 17h; Inert atmosphere;	65.7%

: 616-47-7
1-methyl-1H-imidazole

: 14320-04-8
zinc(II) phthalocyanine

: N-methylimidazole(phthalocyaninato)zinc

Conditions

Conditions	Yield
In ethanolamine at 150℃; for 24h; Sealed tube;	53%

: 288-32-4
1H-imidazole

: 14320-04-8
zinc(II) phthalocyanine

: 106231-96-3
1H-imidazole(phthalocyaninato)zinc

Conditions

Conditions	Yield
at 100 - 250℃; for 3h; Sealed tube;	50%

: 14320-04-8
zinc(II) phthalocyanine

: 134914-65-1
2-(1H-imidazol-1-yl)pyrimidine

: N-(2-pyrimidinyl)imidazole(phthalocyaninato)zinc

Conditions

Conditions	Yield
at 150℃; for 24h; Sealed tube;	41%

: 109-99-9
tetrahydrofuran

: 14320-04-8
zinc(II) phthalocyanine

: adamantylideneadamantanebromonium tetrakis-(perfluorophenyl)borate

: zinc phthalocyaninato(1-)tetrahydrofuran tetrakis(perfluorophenyl)borate

Conditions

Conditions	Yield
at 20℃; for 0.25h; Inert atmosphere;	38%

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: 14320-04-8
zinc(II) phthalocyanine

: 70460-15-0
[CpFe(dppe)(CN)]

: 75-09-2
dichloromethane

: [(C5H5)((C6H5)2PCH2CH2P(C6H5)2)Fe(CN)Zn(NCC6H4CN)4]*1.5CH2Cl2

Conditions

Conditions	Yield
In toluene soln. of ZnPc and Fe compd. in toluene refluxed for 5 h; filtered; evapd.; dissolved in CH2Cl2; filtered; layered with petroleumether (bp 60-70°C); soln. was kept for few d; sepd.; elem.anal.;	33%

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: 110-71-4
1,2-dimethoxyethane

: 14320-04-8
zinc(II) phthalocyanine

: adamantylideneadamantanebromonium tetrakis-(perfluorophenyl)borate

: C36H26N8O2Zn*C24BF20(1-)*H(1+)*C4H10O2

Conditions

Conditions	Yield
for 96h; Inert atmosphere;	27%

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: 14320-04-8
zinc(II) phthalocyanine

A: 574-93-6
29H,31H-phthalocyanine

B: zinc(II) sulfate hydrate

Conditions

Conditions	Yield
With sulfuric acid In water Kinetics; 91-97 % H2SO4;

Zinc phthalocyanine Specification

The Zinc phthalocyanine with cas registry number of 14320-04-8, belongs to the following product categories: (1)Organometallics; (2)Classes of Metal Compounds; (3)Functional Materials; (4)Phthalocyanines; (5)Phthalonitriles & Naphthalonitriles; (6)Transition Metal Compounds; (7)Zn (Zinc) Compounds. And its systematic name is (29H,31H-Phthalocyaninato(2-)-N29,N30,N31,N32)zinc. Zinc Phthalocyanine is generally immediately available in most volumes.

Physical properties about Zinc phthalocyanine are: (1)#H bond acceptors: 8; (2)#H bond donors: 0; (3)#Freely Rotating Bonds: 0; (4)Polar Surface Area: 82.33 Å² . Zinc phthalocyanine is purple powder.

When you are using this chemical, please be cautious about it as the following: Please do not breathe dust, and avoid contact with skin and eyes.

You can still convert the following datas into molecular structure:
(1)InChI=1S/C32H16N8.Zn/c1-2-10-18-17(9-1)25-33-26(18)38-28-21-13-5-6-14-22(21)30(35-28)40-32-24-16-8-7-15-23(24)31(36-32)39-29-20-12-4-3-11-19(20)27(34-29)37-25;/h1-16H;/q-2;+2;
(2)InChIKey=PODBBOVVOGJETB-UHFFFAOYSA-N;
(3)Smilesn1c2nc(c3c2cccc3)nc2[n-]c(c3c2cccc3)nc2nc(c3c2cccc3)nc2[n-]c1c1c2cccc1.[Zn+2];

Product Name

ZINC PHTHALOCYANINE

Synthetic route

Zinc phthalocyanine Specification

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