tert-Butyl hydroperoxide 75-91-2 C4H10O2
tert-Butyl hydroperoxide Basic information |
Product Name: | tert-Butyl hydroperoxide |
Synonyms: | Butylhydroperoxid;1,1-Dimethylethyl hydroperoxide;1,1-dimethylethyl-hydroperoxid;1,1-dimethylethylhydroperoxide;1,1-dimethylethyl-Hydroperoxide;2-Hydroperoxy-2-methylpropane;2-Methyl-prop-2-yl-hydroperoxide;Aztec t-butyl Hydroperoxide-70, Aq |
CAS: | 75-91-2 |
MF: | C4H10O2 |
MW: | 90.12 |
EINECS: | 200-915-7 |
Product Categories: | Organics;Organic Peroxide;Synthetic Organic Chemistry |
Mol File: | 75-91-2.mol |
tert-Butyl hydroperoxide Basic information |
Product Name: | tert-Butyl hydroperoxide |
Synonyms: | Butylhydroperoxid;1,1-Dimethylethyl hydroperoxide;1,1-dimethylethyl-hydroperoxid;1,1-dimethylethylhydroperoxide;1,1-dimethylethyl-Hydroperoxide;2-Hydroperoxy-2-methylpropane;2-Methyl-prop-2-yl-hydroperoxide;Aztec t-butyl Hydroperoxide-70, Aq |
CAS: | 75-91-2 |
MF: | C4H10O2 |
MW: | 90.12 |
EINECS: | 200-915-7 |
Product Categories: | Organics;Organic Peroxide;Synthetic Organic Chemistry |
Mol File: | 75-91-2.mol |
tert-Butyl hydroperoxide Chemical Properties |
mp | -2.8 °C |
bp | 37 °C (15 mmHg) |
density | 0.937 g/mL at 20 °C |
refractive index |
n |
Fp | 85 °F |
storage temp. | 2-8°C |
Water Solubility | Miscible |
Merck | 14,1570 |
BRN | 1098280 |
Stability: | Stable, but may explode if heated under confinement. Decomposition may be accelerated by traces of metals, molecular sieve or other contaminants. Incompatible with reducing agents, combustible material, acids. |
CAS DataBase Reference | 75-91-2(CAS DataBase Reference) |
NIST Chemistry Reference | Tert-butyl hydroperoxide(75-91-2) |
EPA Substance Registry System | Hydroperoxide, 1,1-dimethylethyl(75-91-2) |
Safety Information |
Hazard Codes | O,C,N,T |
Risk Statements | 7-10-20/21/22-34-65-52/53-43-67-53-68-51/53-23-21/22 |
Safety Statements | 14-3/7-61-45-36/37/39-24-17-16-14A-26-62-47-43 |
RIDADR | UN 3109 5.2 |
WGK Germany | 3 |
RTECS | EQ4900000 |
F | 3-21 |
HazardClass | 5.2 |
PackingGroup | II |
Hazardous Substances Data | 75-91-2(Hazardous Substances Data) |
MSDS Information |
Provider | Language |
---|---|
TBHP | English |
SigmaAldrich | English |
ACROS | English |
ALFA | English |
tert-Butyl hydroperoxide Usage And Synthesis |
Chemical Properties | colourless liquid (as an aqueous solution) with a sweet smell |
General Description | Watery odorless colorless liquid. Floats and mixes slowly with water. |
Air & Water Reactions | Water soluble. |
Reactivity Profile | Most alkyl monohydroperoxides are liquid. The explosivity of the lower members (e.g., methyl hydroperoxide, or possibly, traces of the dialkyl peroxides) decreasing with increasing chain length and branching [Bretherick 2nd ed. 1979 p. 10]. Though relatively stable, explosions have been caused by distillation to dryness [Milas, JACS 1946, 68, 205] or attempted distillation at atmospheric pressure [Castrantas 1965 p. 15]. |
tert-Butyl hydroperoxide Preparation Products And Raw materials |
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