Chloro(1,5-cyclooctadiene)rhodium(I) dimer/12092-47-6CAS NO.: 12092-47-6

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1 Gram	FOB Price:USD 4.0000 -5.0000

1 Gram

FOB Price:USD 4.0000 -5.0000

Min.Order :1 Gram
Purity: 99%
Payment Terms : L/C,D/A,D/P,T/T,,MoneyGram,Other

Keywords

Chloro(1,5-cyclooctadiene)rhodium(I) dimer manufacturer Chloro(1,5-cyclooctadiene)rhodium(I) dimer high purity Chloro(1,5-cyclooctadiene)rhodium(I) dimer

Quick Details

Appearance:colourless liquid
Application:Catalyst and Auxiliary
PackAge:Aluminium Foil Bag and Paper Drum
ProductionCapacity:10000|Gram|Day
Storage:Room temperature
Transportation:By sea or by air

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Details:

Melting point	243 °C (dec.)(lit.)
storage temp.	2-8°C
solubility	Soluble in chloroform, dichloromethane, and methanol. Sparingly soluble in most common solvents.
form	Crystals or Crystalline Powder
color	Orange to orange-brown
Sensitive	Air Sensitive & Hygroscopic
Stability:	hygroscopic
NIST Chemistry Reference	Bis(1,5-cyclooctadienerhodium chloride)(12092-47-6)
EPA Substance Registry System	Rhodium, di-.mu.-chlorobis[(1,2,5,6-.eta.)-1,5-cyclooctadiene]di- (12092-47-6)

Safety Information

Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	26-37/39
WGK Germany	3
F	3
TSCA	Yes
HS Code	28439000

MSDS Information

Provider	Language
Chloro(1,5-cyclooctadiene)rhodium(I) dimer	English
SigmaAldrich	English
ACROS	English
ALFA	English

Chloro(1,5-cyclooctadiene)rhodium(I) dimer Usage And Synthesis

Reaction

Catalyst for coupling 1,3-dienes with activate methylene compounds.
Rhodium source for various asymmetric hydrogenation systems and asymmetric hydrosilylation of ketones.
Rhodium source for asymmetric reductive aldol reaction.
Cis-hydroboration of terminal alkynes.
Rhodium source for [5 + 2] additions.
Highly enantioselective for [2+2+2] carbocyclization reactions.
Enantioselective hydroboration of cyclopropenes.