Add time:08/23/2019 Source:sciencedirect.com
SummaryRaney nickel catalysts, unpromoted or doped with molybdenum or chromium, were prepared from the precursor alloys of the type Ni2Al3. The structure and phase composition of the catalysts have been determined. Hydrogenation of Valeronitrile (cas 110-59-8) at 90°C and 1.6 MPa- in cyclohexane was performed to evaluate catalyst activities and the relative amounts of amines formed. Doping catalysts by chromium improved reaction rates and yields of primary amine, whereas molybdenum addition was ineffective.
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