Add time:07/21/2019 Source:sciencedirect.com
Hydrogenation of Acrylonitrile (cas 107-13-1) to propionitrile catalyzed by Raney Ni was accessible with good yield and high selectivity under optimized reaction conditions. Kinetic modeling was performed by means of computer aided autoclave reaction; the apparent activation energy of this reaction was determined to be 31.3 kJ/mol. This reaction is controlled by Raney Ni surface. The reaction is apparently zero-order reaction with respect to acrylonitrile and first-order reaction regarding the concentration of dissolved hydrogen in the liquid phase, respectively.
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