Add time:09/25/2019 Source:sciencedirect.com
D-ERYTHRO-SPHINGOSINE (cas 123-78-4) and D-erythro-sphinganine can be produced in protected form from serine by a synthetic approach in which the normal biological intermediate 3-ketosphinganine in protectyed form, is a key synthetic intermediate. The sequence is short and convergent, proceeds in good overall yields (≈30% for 6 steps) and with excellent stereocontrol (>91% de, >95% ee).
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