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  • Separation of Vanillin and Syringaldehyde (cas 134-96-3) from Oxygen Delignification Spent Liquor by Macroporous Resin Adsorption
  • Add time:10/01/2019         Source:infona.pl

    This paper reports on an approach for separating vanillin and Syringaldehyde (cas 134-96-3) (VSA) from oxygen delignification spent liquor using non‐polar macroporous resin. The effects of temperature and pH on the adsorption isotherms were studied. The adsorption capacity and adsorption equilibrium constant were obtained using the Langmuir adsorption model at pH<4.5, where the ionization of the VSA to ionic forms was negligible. The standard enthalpy change was calculated using the van't Hoff equation and clearly showed that the adsorption is an exothermic process. The effect of pH on the adsorption isotherm is well‐described by a modified Langmuir model and shows that the adsorption equilibrium constant decreases significantly with the increasing pH. The VSA adsorbed on macroporous resin was eluted by ethyl ether. The separated VSA contained 37.51% vanillin, 31.88% syringaldehyde. The recoveries of VSA were 96.2 and 94.7%, respectively.

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    Prev:Solvent effect on kinetics of the chloride ion cleavage from anion radicals of 4-Chlorobenzophenone (cas 134-85-0)
    Next: Successful recovery and concentration of vanillin and Syringaldehyde (cas 134-96-3) onto a polymeric adsorbent with ethanol/water solution)

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