100045-90-7

Basic information

• Product Name: 1,1-bis(phenylthio)-2-butylcyclopropane
• CAS NO: 100045-90-7
• Molecular Weight: 314.516
• Mol File: 100045-90-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,1-bis(phenylthio)-2-butylcyclopropane(CAS DataBase Reference)
• NIST Chemistry Reference: 1,1-bis(phenylthio)-2-butylcyclopropane(100045-90-7)
• EPA Substance Registry System: 1,1-bis(phenylthio)-2-butylcyclopropane(100045-90-7)

Safety Data

• Hazardous Substances Data: 100045-90-7(Hazardous Substances Data)

Upstream product

• 5398-70-9 1,1-dibromo-2-butylcyclopropane 
• 108-98-5 thiophenol 

Relevant articles and documents

SRN1 Reactions of Halocyclopropanes with Benzenethiolate Ion

Ultraviolet irradiation of gem-dibromocyclopropanes 1 with benzenethiolate ion in liquid ammonia or in Me2SO solutions gave dithioacetals 2 and, in some cases, cyclopropyl phenyl sulfides 3.The reactions did not proceed in the dark and they were inhibited by m-dinitrobenzene, di-tert-butyl nitroxide, and oxygen.The bromocyclopropane 6a underwent a similar, but slower, reaction.Treatment of the bromochlorocyclopropane 7b led to replacement of only the bromine, while the dichlorocyclopropane 9b was inert under the reaction conditions.The results appear consistent with a radical chain mechanism.