1000612-67-8

Basic information

• Product Name: (2S,3R,4R,5R)-3,4-bis(benzyloxy)-5-(benzyloxymethyl)-1-hydroxy-5-phenylpyrrolidine
• Synonyms: (2S,3R,4R,5R)-3,4-bis(benzyloxy)-5-(benzyloxymethyl)-1-hydroxy-5-phenylpyrrolidine
• CAS NO: 1000612-67-8
• Molecular Weight: 495.618
• Mol File: 1000612-67-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (2S,3R,4R,5R)-3,4-bis(benzyloxy)-5-(benzyloxymethyl)-1-hydroxy-5-phenylpyrrolidine(CAS DataBase Reference)
• NIST Chemistry Reference: (2S,3R,4R,5R)-3,4-bis(benzyloxy)-5-(benzyloxymethyl)-1-hydroxy-5-phenylpyrrolidine(1000612-67-8)
• EPA Substance Registry System: (2S,3R,4R,5R)-3,4-bis(benzyloxy)-5-(benzyloxymethyl)-1-hydroxy-5-phenylpyrrolidine(1000612-67-8)

Safety Data

• Hazardous Substances Data: 1000612-67-8(Hazardous Substances Data)

Upstream product

• 1000612-64-5 (2R,3R,4R,5R)-3,4-bis(benzyloxy)-5-(benzyloxymethyl)-2-phenyl-3,4-dihydro-2H-pyrrole 1-oxide 
• 1000612-60-1 (2R,3R,4R,5R)-3,4-bis(benzyloxy)-2-(benzyloxymethyl)-1-hydroxy-5-phenylpyrrolidine 

Relevant articles and documents

Stereoselective synthesis of (2S,3S,4R,5S)-3,4-dihydroxy-2,5- dihydroxymethyl pyrrolidine from l-sorbose

One of the most frequently synthesized iminosugar derivatives is DMDP. Starting from l-sorbose, a practical method for the synthesis of derivatives of this five-membered iminocyclitol has been developed, involving straightforward steps and a convenient selective reduction of a ketoxime intermediate.

Nucleophilic additions and redox reactions of polyhydroxypyrroline N-oxides on the way to pyrrolidine alkaloids: Total synthesis of radicamine B

Nucleophilic addition of aryl Grignard reagents to (2R,3R,4R)-3,4- bis(benzyloxy)-2-(benzyloxymethyl)-3,4-dihydro-2H-pyrrole 1-oxide afford straightforwardly trihydroxylated pyrrolidine alkaloids. Organometallic additions take place with complete anti sel