1000612-69-0Relevant articles and documents
Stereoselective synthesis of (2S,3S,4R,5S)-3,4-dihydroxy-2,5- dihydroxymethyl pyrrolidine from l-sorbose
Balieu, Sebastien,Guilleret, Arnaud,Reynaud, Romain,Martinez, Agathe,Haudrechy, Arnaud
, p. 14 - 22 (2013/06/27)
One of the most frequently synthesized iminosugar derivatives is DMDP. Starting from l-sorbose, a practical method for the synthesis of derivatives of this five-membered iminocyclitol has been developed, involving straightforward steps and a convenient selective reduction of a ketoxime intermediate.
Nucleophilic additions and redox reactions of polyhydroxypyrroline N-oxides on the way to pyrrolidine alkaloids: Total synthesis of radicamine B
Merino, Pedro,Delso, Ignacio,Tejero, Tomas,Cardona, Francesca,Goti, Andrea
, p. 2651 - 2654 (2008/02/11)
Nucleophilic addition of aryl Grignard reagents to (2R,3R,4R)-3,4- bis(benzyloxy)-2-(benzyloxymethyl)-3,4-dihydro-2H-pyrrole 1-oxide afford straightforwardly trihydroxylated pyrrolidine alkaloids. Organometallic additions take place with complete anti sel