100065-14-3Relevant articles and documents
Conformational Analysis of 2-Substituted Alkylphosphoryl Compounds. 4. Substituent Effect on the Nature of the Hydrogen Bonding in (2-Hydroxyalkyl)phosphoryl Systems
Genov, Daniel G.,Kresinski, Roman A.,Tebby, John C.
, p. 2574 - 2585 (1998)
The extent to which solid state conformational and hydrogen bonding preferences of five (2-hydroxyalkyl)phosphoryl compounds 2a-e [R12P(O)CH2CH(OH)R2; 2a, R1 = MeO, R2 = Ph; 2b, R1/su
Copper-catalyzed direct hydroxyphosphorylation of electron-deficient alkenes with H-phosphine oxides and dioxygen
Yi, Dong,Fu, Qiang,Chen, Su-Yuan,Gao, Ming,Yang, Lu,Zhang, Zhi-Jie,Liang, Wu,Zhang, Qiang,Ji, Jian-Xin,Wei, Wei
, p. 2058 - 2061 (2017)
A copper-catalyzed direct hydroxyphosphorylation of electron-deficient alkenes with H-phosphine oxides and dioxygen is reported. The present reaction, proceeds under mild reaction conditions with good functional group tolerance, affording the facile and efficient synthesis of various β-hydroxyphosphine oxides in a scaled-up manner with moderate to good yields.
Cobalt(II)-Catalyzed Bisfunctionalization of Alkenes with Diarylphosphine Oxide and Peroxide
Shen, Jian,Xiao, Bo,Hou, Yang,Wang, Xue,Li, Gui-Zhi,Chen, Jin-Chun,Wang, Wei-Li,Cheng, Jian-Bo,Yang, Bin,Yang, Shang-Dong
supporting information, p. 5198 - 5209 (2019/11/13)
The low-cost cobalt(II) catalyst has been used for the first time to achieve P(O)-radical-mediated bisfunctionalization of alkenes with diarylphosphine oxide and peroxides. This simple process is performed under mild conditions to afford a wide variety of phosphonation-peroxidation products in a one-pot manner. Computational studies are carried out to provide a theoretical support for the P(O)-radical-involved bisfunctionalization of alkenes. (Figure presented.).