1001197-19-8

Basic information

• Product Name: [Au(p-CN-C₆H₄-CC-S)(PPh₃)]
• CAS NO: 1001197-19-8
• Molecular Weight: 617.461
• Mol File: 1001197-19-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Au(p-CN-C₆H₄-CC-S)(PPh₃)](CAS DataBase Reference)
• NIST Chemistry Reference: [Au(p-CN-C₆H₄-CC-S)(PPh₃)](1001197-19-8)
• EPA Substance Registry System: [Au(p-CN-C₆H₄-CC-S)(PPh₃)](1001197-19-8)

Safety Data

• Hazardous Substances Data: 1001197-19-8(Hazardous Substances Data)

Upstream product

• 14243-64-2 (triphenylphosphine)gold(I) chloride 
• 82894-99-3 4-(1,2,3-thiadiazol-4-yl)benzonitrile 

Relevant articles and documents

Synthesis and properties of alkynethiolate gold(i) complexes

A series of alkynethiolate gold(i) derivatives have been synthesised by the cleavage of 4-monosubstituted 1,2,3-thiadiazoles in the presence of strong bases. The syntheses of the 1,2,3-thiadiazoles with p-cyanophenyl, p-tolyl, 2-thienyl, 3-thienyl and 9,9-dimethylfluoren-2-yl fragments are also described. All the complexes have been characterised by spectroscopic techniques and the complexes [Au(p-CH3-C6H4-CC-S)PPh3], [Au(3-C4H3S-CC-S)PPh3] and PPN[Au(p-CH 3-C6H4-CC-S)(C6F5)] by X-ray analysis. The electrochemically polymerizable mononuclear bis(alkynethiolate) gold(i) complex PPN[Au(3-C4H3S-CC-S) 2] is also described, including its electropolymerization and electrochemical properties. This journal is The Royal Society of Chemistry.