1001919-23-8

Basic information

• Product Name: (+/-)-N-tert-butoxycarbonyl-5-(tert-butyldiphenylsilyloxy)-3-piperidene
• Synonyms: (+/-)-N-tert-butoxycarbonyl-5-(tert-butyldiphenylsilyloxy)-3-piperidene
• CAS NO: 1001919-23-8
• Molecular Weight: 437.654
• Mol File: 1001919-23-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (+/-)-N-tert-butoxycarbonyl-5-(tert-butyldiphenylsilyloxy)-3-piperidene(CAS DataBase Reference)
• NIST Chemistry Reference: (+/-)-N-tert-butoxycarbonyl-5-(tert-butyldiphenylsilyloxy)-3-piperidene(1001919-23-8)
• EPA Substance Registry System: (+/-)-N-tert-butoxycarbonyl-5-(tert-butyldiphenylsilyloxy)-3-piperidene(1001919-23-8)

Safety Data

• Hazardous Substances Data: 1001919-23-8(Hazardous Substances Data)

Upstream product

• 224779-26-4 N-allyl-N-(2-hydroxy-but-3-enyl)-carbamic acid tert-butyl ester 
• 24424-99-5 di-tert-butyl dicarbonate 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 224779-27-5 tert-butyl 3-hydroxy-1,2,3,6-tetrahydropyridine-N-carboxylate 

Relevant articles and documents

A new preparation of homochiral N-protected 5-hydroxy-3-piperidenes, promising chiral building blocks, by palladiumCatalyzed deracemization of their alkyl carbonates

The palladium-catalyzed deracemization of N-protected alkyl carbonates of 5-hydroxy-3-piperidenes by use of chiral phosphine ligands is described. A Trost ligand such as (R)-BPA was found to be a suitable chiral ligand for the deracemization, providing N-