100204-33-9

Basic information

• Product Name: 3,5-di-tert-butyl-4-hydroxyphenyl S-(hydroxymethyl) sulfide
• CAS NO: 100204-33-9
• Molecular Weight: 268.42
• Mol File: 100204-33-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3,5-di-tert-butyl-4-hydroxyphenyl S-(hydroxymethyl) sulfide(CAS DataBase Reference)
• NIST Chemistry Reference: 3,5-di-tert-butyl-4-hydroxyphenyl S-(hydroxymethyl) sulfide(100204-33-9)
• EPA Substance Registry System: 3,5-di-tert-butyl-4-hydroxyphenyl S-(hydroxymethyl) sulfide(100204-33-9)

Safety Data

• Hazardous Substances Data: 100204-33-9(Hazardous Substances Data)

Upstream product

• 50-00-0 formaldehyd 
• 950-59-4 4-hydroxy-3,5-di-tert-butylthiophenol 
• 6386-58-9 4,4'-dithiobis(2,6-di-tert-butylphenol) 

Relevant articles and documents

S-(HYDROXYMETHYL) 4-HYDROXYPHENYL SULFIDES: SYNTHESIS AND SELECTED CHEMISTRY OF SOME STABLE HEMIMERCAPTALS

The base-catalyzed reaction of 3,5-di-tert-butyl-4-hydroxybenzenethiol (1a), 3-tert-butyl-4-hydroxy-5-methylbenzenethiol (1b), and 4-hydroxybenzenethiol (1c) with formaldehyde gave the corresponding hemimercaptal derivatives 2a-c, respectively.The stable hemimercaptals 2a-c were characterized by IR, 1H NMR, 13C NMR, MS and elemental analysis.The ester of 2a with 3-(3,5-di-tert-butyl-4-hydroxyphenyl)propanoic acid (3a) was prepared using triphenylphosphine and diethyl azodicarboxylate (Mitsunobu conditions).