1002567-00-1Relevant articles and documents
Dynamic Control of Chiral Space Through Local Symmetry Breaking in a Rotaxane Organocatalyst
Dommaschk, Marcel,Echavarren, Javier,Leigh, David A.,Marcos, Vanesa,Singleton, Thomas A.
supporting information, p. 14955 - 14958 (2019/11/05)
We report on a switchable rotaxane molecular shuttle that features a pseudo-meso 2,5-disubstituted pyrrolidine catalytic unit on the axle whose local symmetry is broken according to the position of a threaded benzylic amide macrocycle. The macrocycle can