100377-10-4

Basic information

• Product Name: Phosphonic acid, (4-nitrophenyl)-, dimethyl ester
• CAS NO: 100377-10-4
• Molecular Formula: C8H10NO5P
• Molecular Weight: 231.145
• Mol File: 100377-10-4.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Phosphonic acid, (4-nitrophenyl)-, dimethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Phosphonic acid, (4-nitrophenyl)-, dimethyl ester(100377-10-4)
• EPA Substance Registry System: Phosphonic acid, (4-nitrophenyl)-, dimethyl ester(100377-10-4)

Safety Data

• Hazardous Substances Data: 100377-10-4(Hazardous Substances Data)

Upstream product

• 100-01-6 4-nitro-aniline 
• 100-16-3 4-nitrophenylhydrazone 
• 121-45-9 phosphorous acid trimethyl ester 
• 298-00-0 parathion-methyl 
• 186581-53-3 diazomethane 
• 2175-86-2 4-nitropheylphosphonic acid 

Downstream Products

• 15286-22-3 (4-amino-phenyl)-phosphonic acid dimethyl ester 

Relevant articles and documents

Cu2O/TiO2 nanoparticles as visible light photocatalysts concerning C(sp2)-P bond formation

A novel and efficient method has been developed for the construction of an aromatic-phosphorus (Ar-P) bond under visible light irradiation using Cu2O/TiO2 nanoparticles as inexpensive and available photocatalysts. This protocol is a simple system without the use of any base, ligand, oxidant, or special conditions. This is the first report for the synthesis of arylphosphonates from arylhydrazines in visible light irradiation.

Copper-catalyzed coupling reaction of arylhydrazines and trialkylphosphites

A novel CuO-catalyzed coupling reaction of arylhydrazines with trialkyl phosphites to afford arylphosphonates is described. The reaction proceeded at 80 C in air without external reductants, oxidants, and ligands.