100596-91-6Relevant articles and documents
Cyanation of Allylic Carbonates and Acetates Using Trimethylsilyl Cyanide Catalyzed by Palladium Complex
Tsuji, Yasushi,Yamada, Naoaki,Tanaka, Shinsuke
, p. 16 - 17 (2007/10/02)
Allylic carbonates and acetates are cyanated with trimethylsilyl cyanide in the presence of a catalytic amount (5 mol percent based on the allylic substrates) od Pd(PPh3)4 or Pd(CO)(PPh3)3 in THF under reflux to afford β,γ-unsaturated nitriles in high yields.