100651-92-1Relevant articles and documents
Palladium-catalyzed C-H olefination of uracils and caffeines using molecular oxygen as the sole oxidant
Zhang, Xinyu,Su, Lv,Qiu, Lin,Fan, Zhenwei,Zhang, Xiaofeng,Lin, Shen,Huang, Qiufeng
, p. 3499 - 3506 (2017)
The palladium-catalyzed oxidative C-H olefination of uracils or caffeines with alkenes using an atmospheric pressure of molecular oxygen as the sole oxidant has been disclosed. This novel strategy offers an efficient and environmentally friendly method to
PALLADIUM CATALYZED COUPLING OF 5-HYDROXYURACIL TRIFLUOROMETHANESULFONATES (TRIFLATES) WITH ALKENES AND ALKYNES
Hirota, Kosaku,Kitade, Yukio,Isobe, Yoshiaki,Maki, Yoshifumi
, p. 355 - 358 (1987)
Cross coupling of 5-hydroxyuracil triflates (1) with alkenes and alkynes in the presence of a palladium catalyst and triphenylphosphine affords 5-vinyluracils (2) and 5-alkynyluracils (3), respectively, in good yields.Coupling of the triflate (1a) with organocopper reagents is also described.
Dehydrogenative alkenylation of uracils via palladium-catalyzed regioselective C-H activation
Yu, Yi-Yun,Georg, Gunda I.
supporting information, p. 3694 - 3696 (2013/05/09)
A regioselective Pd-catalyzed cross-dehydrogenative coupling between uracils and alkenes is reported. This protocol provides easy access to a variety of 5-alkenyluracil structural motifs. The Royal Society of Chemistry 2013.