100791-45-5

Basic information

• Product Name: (2S,3S,4R)-3-Hydroxy-4,5-isopropylidenedioxy-2-phenylpentanoic acid
• Synonyms: (2S,3S,4R)-3-Hydroxy-4,5-isopropylidenedioxy-2-phenylpentanoic acid
• CAS NO: 100791-45-5
• Molecular Weight: 266.294
• Mol File: 100791-45-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2S,3S,4R)-3-Hydroxy-4,5-isopropylidenedioxy-2-phenylpentanoic acid(CAS DataBase Reference)
• NIST Chemistry Reference: (2S,3S,4R)-3-Hydroxy-4,5-isopropylidenedioxy-2-phenylpentanoic acid(100791-45-5)
• EPA Substance Registry System: (2S,3S,4R)-3-Hydroxy-4,5-isopropylidenedioxy-2-phenylpentanoic acid(100791-45-5)

Safety Data

• Hazardous Substances Data: 100791-45-5(Hazardous Substances Data)

Upstream product

• 103-82-2 phenylacetic acid 
• 15186-48-8 2,3-isopropylidene-glyceraldehyde 

Downstream Products

• 100791-47-7 (3S,4R)-4-<(4R)-2,2-Dimethyl-1,3-dioxolan-4-yl>-3-phenyl-2-oxetanone 
• 100791-48-8 (3S,4S)-4-<(4R)-2,2-Dimethyl-1,3-dioxolan-4-yl>-3-phenyl-2-oxetanone 
• 100791-46-6 (3R,4S)-4-<(4R)-2,2-Dimethyl-1,3-dioxolan-4-yl>-3-phenyl-2-oxetanone 

Relevant articles and documents

Addition of Crotylchromium(II) and Dilithium Propionate to (R)-2,3-O-isopropylideneglyceraldehyde: Steric Course and Synthetic Application in a Formal Synthesis of (+)- and (-)-δ-Multistriatin

The chromium(II) salt 4a of crotyl bromide adds to (R)-2,3-O-isopropylideneglyceraldehyde (1) with high enantiofacial and low diastereofacial (i.e.Cram) selectivity, whereas dilithium propionate (9) shows the opposite behaviour.The adducts 5, 7, and 10 can be used in a formal synthesis of both enantiomers of the insect pheromone δ-multistriatin (30).