100847-56-1Relevant articles and documents
REGIOSELECTIVE BOND CLEAVAGE AND COORDINATION EFFECTS IN THE REDUCTION OF SOME ACETALS WITH LITHIUM IN AMMONIA
Abell, A. D.,Massy-Westropp, R. A.
, p. 2451 - 2464 (2007/10/02)
Some benzylic-type acetals possessing the 2,8-dioxabicyclo(3.2.1)octane ring system are cleaved in a regioselective manner when treated with lithium in ammonia.The results from various reductions implicate coordination of lithium as a significant factor involved in reduction mechanisms.