101010-12-2Relevant articles and documents
Hetero ?-Systems, 17. - Aminosilylene (Aminosilanediyl)
Maier, Guenter,Glatthaar, Joerg,Reisenauer, Hans Peter
, p. 2403 - 2406 (2007/10/02)
Aminosilylene can be prepared by 254-nm photolysis of silyl azide isolated in an argon matrix at 12 K.Subsequent irradiation with wavelenghts > 300 nm yields silaisonitrile (3) and molecular hydrogen.This reaction may be reversed with 254-nm light. - Key Words: Hydrogen capture / Matrix isolation / Photochemistry / Aminosilylene