101062-05-9Relevant articles and documents
181. Nuchleophilic Additions to N-Glycosylnitrones Asymmetric Synthesis of α-Aminophosphonic Acids
Huber, Rolf,Knierzinger, Andreas,Obrecht, Jean-Pierre,Vasella, Andrea
, p. 1730 - 1747 (1985)
The hypothesis which explains the diastereoselectivity of the 1,3-dipolar cycloaddition of the N-glycosylnitrones 1-3 leading to the 5,5-disubstituted isoxazolidines 4-6 on the basis of a kinetic anomeric effect predicts that nucleophiles should add to N-