1011530-91-8

Basic information

• Product Name: ((C₄H₈O)2LiH₃Al(N(C₆H₃(CH(CH₃)2)2)CH(Si(CH₃)3)2))2
• Synonyms: ((C₄H₈O)2LiH₃Al(N(C₆H₃(CH(CH₃)2)2)CH(Si(CH₃)3)2))2
• CAS NO: 1011530-91-8
• Molecular Weight: 1031.67
• Mol File: 1011530-91-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: ((C₄H₈O)2LiH₃Al(N(C₆H₃(CH(CH₃)2)2)CH(Si(CH₃)3)2))2(CAS DataBase Reference)
• NIST Chemistry Reference: ((C₄H₈O)2LiH₃Al(N(C₆H₃(CH(CH₃)2)2)CH(Si(CH₃)3)2))2(1011530-91-8)
• EPA Substance Registry System: ((C₄H₈O)2LiH₃Al(N(C₆H₃(CH(CH₃)2)2)CH(Si(CH₃)3)2))2(1011530-91-8)

Safety Data

• Hazardous Substances Data: 1011530-91-8(Hazardous Substances Data)

Upstream product

• 109-99-9 tetrahydrofuran 
• 16853-85-3 lithium aluminium tetrahydride 
• 136213-18-8 3-<(2,6-diisopropylphenyl)imino>-2,2,4,4-tetramethyl-2,4-disilapentane 

Downstream Products

• 1011530-92-9 (((CH₃)3Si)2CHNC₆H₃(CH(CH₃)2)2)AlH₂(OC₄H₈) 
• 1011530-93-0 (((CH₃)3Si)2CHNC₆H₃(CH(CH₃)2)2)AlI₂(OC₄H₈) 

Relevant articles and documents

Synthesis and characterization of the monomeric vicinal dianion Li 2(THF)3[ArNC(SiMe3)2] and the aluminum and lithium derivatives of the amido ligand [ArNCH(SiMe 3)2]_

Reaction of the imine ArNC(SiMe3)2 (1; Ar = 2,6-iPr2C6H3) with LiAlH4 in THF resulted in the formation of the dimeric hydroaluminate [(THF) 2LiH3AlL]2 (2; L = [ArNCH(SiMe 3)2]-). 2 reacted with CH3I to give the monomeric aluminum dihydride LAlH2(THF) (3), which can be converted to the diiodide LAlI2(THF) (4) upon treatment with 2 equiv of Me3SiI. The quasi two-coordinate lithium amide Li(OEt 2)L (8) with an intramolecular CH-Li interaction was obtained by the deprotonation of the corresponding amine LH (5) generated from hydrolysis of 2. Reduction of 1 with lithium in THF resulted in the first structurally characterized monomeric C-N vicinal dianion, Li2(THF) 3[ArNC(SiMe3)2] (6), and the monomeric lithium amide Li(THF)2L (7).