101184-08-1

Basic information

• Product Name: METHYL 4-(1H-IMIDAZOL-1-YL)BENZENECARBOXYLATE
• Synonyms: Methyl 4-(1H-iMidazol-1-yl)benzoate,99%;Methyl 4-(1H-imidazol-1-yl)benzoate 99%;Methyl 4-(1H-imidazol-1-yl);METHYL 4-(1H-IMIDAZOL-1-YL)BENZENECARBOXYLATE;METHYL 4-(1 H-IMIDAZOL-1-YL)BENZOATE;RARECHEM AL BF 0793;4-(Imidazol-1-yl)benzoicacidmethylester;Methyl 4-(imidazol-1-yl)benzoate, GC 99%
• CAS NO: 101184-08-1
• Molecular Formula: C₁₁H₁₀N₂O₂
• Molecular Weight: 202.21
• Product Categories: Heterocyclic Compounds;Building Blocks;Heterocyclic Building Blocks;Imidazoles
• Mol File: 101184-08-1.mol
• Article Data: 15

Chemical Properties

• Melting Point: 124-127 °C(lit.)
• Boiling Point: 354.7°Cat760mmHg
• Flash Point: 168.3°C
• Appearance: /
• Density: 1.18g/cm³
• Vapor Pressure: 3.28E-05mmHg at 25°C
• Refractive Index: 1.583
• Storage Temp.: Sealed in dry,Room Temperature
• PKA: 5.06±0.10(Predicted)
• CAS DataBase Reference: METHYL 4-(1H-IMIDAZOL-1-YL)BENZENECARBOXYLATE(CAS DataBase Reference)
• NIST Chemistry Reference: METHYL 4-(1H-IMIDAZOL-1-YL)BENZENECARBOXYLATE(101184-08-1)
• EPA Substance Registry System: METHYL 4-(1H-IMIDAZOL-1-YL)BENZENECARBOXYLATE(101184-08-1)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36
• WGK Germany: 3
• HazardClass: IRRITANT
• Hazardous Substances Data: 101184-08-1(Hazardous Substances Data)

Usage

Description

METHYL 4-(1H-IMIDAZOL-1-YL)BENZENECARBOXYLATE, an imidazole derivative, is a heterocyclic building block utilized in chemical synthesis. It is known for its versatile chemical properties and potential applications across various industries.
Used in Pharmaceutical Industry:
METHYL 4-(1H-IMIDAZOL-1-YL)BENZENECARBOXYLATE is used as an intermediate in the synthesis of pharmaceutical compounds for its ability to form stable and bioactive molecules.
Used in Agrochemical Industry:
In the agrochemical sector, METHYL 4-(1H-IMIDAZOL-1-YL)BENZENECARBOXYLATE is used as a precursor in the development of new agrochemicals, contributing to the creation of effective and environmentally friendly products.
Used in Material Science:
METHYL 4-(1H-IMIDAZOL-1-YL)BENZENECARBOXYLATE is employed as a component in the synthesis of advanced materials, such as polymers and composites, due to its ability to enhance properties like thermal stability and chemical resistance.
Used in Research and Development:
As a heterocyclic building block, METHYL 4-(1H-IMIDAZOL-1-YL)BENZENECARBOXYLATE is used in research and development for the exploration of new chemical reactions and the discovery of novel compounds with potential applications in various fields.

InChI:InChI=1/C11H10N2O2/c1-15-11(14)9-2-4-10(5-3-9)13-7-6-12-8-13/h2-8H,1H3

Upstream product

• 288-32-4 1H-imidazole 
• 403-33-8 methyl 4-flurobenzoate 
• 50-00-0 formaldehyd 
• 619-45-4 4-methoxycarbonyl aniline 
• 18156-74-6 1-(Trimethylsilyl)imidazole 
• 99768-12-4 4-methoxycarbonylphenylboronic acid 
• 75-91-2 tert.-butylhydroperoxide 
• 10040-98-9 1-(4-formylphenyl)-1H-imidazole 
• 67-56-1 methanol 
• 619-42-1 4-methoxycarbonylphenyl bromide 
• 619-44-3 methyl 4-iodobenzoate 

Downstream Products

• 120690-04-2 4-(1H-imidazol-1-yl)-N-<2-ethyl>benzamide 
• 125903-44-8 N-(2-aminoethyl)-4-(1H-imidazol-1-yl)benzamide 
• 125903-29-9 4-(1H-imidazol-1-yl)-N-<2-<(phenylmethyl)amino>ethyl>benzamide hydrochloride 
• 86718-08-3 1-(Hydroxymethyl)-4-(1H-imidazol-1-yl)benzene 
• 120690-14-4 N-(2-aminoethyl)-4-(1H-imidazol-1-yl)benzamide hydrochloride 
• 120690-08-6 N-<2-(diethylamino)ethyl>-4-(1H-imidazol-1-yl)benzamide dihydrochloride 
• 1394898-48-6 C₂₁H₂₄Cl₂N₂O₂Ru 
• 1434057-31-4 1-(4-(methoxycarbonyl)phenyl)-3-phenyl-1H-imidazol-3-ium tetrafluoroborate 
• 17616-04-5 4-(1H-imidazol-1-yl)benzoic acid 

Relevant articles and documents

A N-heterocyclic tetracarbene Pd(II) moiety containing a Pd(II)-Pb(II) bimetallic MOF for three-component cyclotrimerization via benzyne

A novel Pd(ii)-Pb(ii) bimetallic metal-organic framework Pd(ii)-Pb(ii)-MOF (B) which contains an N-heterocyclic tetracarbene Pd(ii) moiety was synthesized based on a chelating N-heterocyclic dicarbene Pd(ii)-NHDC ligand (A) under solvothermal conditions. It can be a highly active heterogeneous catalyst for three-component cyclotrimerization via benzyne species.

An efficient one-pot oxidative esterification of aldehydes to carboxylic esters using B(C6F5)3-TBHP

A simple and efficient protocol for oxidative esterification of diverse aldehydes with alcohols was accomplished with tert-butyl hydroperoxide and 1 mol % of tris(pentafluorophenyl)borane [B(C6F5)3] to generate the corresponding esters in good to excellent yields. The present protocol represents compatibility with wide range of functional groups as well as exceptional tolerance toward acid labile protecting groups such as TBDPS, TBDMS, acetonide, and Boc.

Nucleation of Tiny Silver Nanoparticles by Using a Tetrafacial Organic Molecular Barrel: Potential Use in Visible-Light-Triggered Photocatalysis

Coordination-driven self-assembly of discrete molecular architectures of diverse shapes and sizes has been well studied in the last three decades. Use of dynamic imine bonds for designing analogous metal-free architectures has become a growing challenge r

Chan-Lam-Type C-N Cross-Coupling Reactions under Base- and Ligand-Free CuI-Zeolite Catalysis

Various representative copper(I)-exchanged zeolites were investigated for their catalytic potential in Chan-Lam cross-coupling reactions. CuI-USY appeared as the best catalyst and proved to efficiently promote C-N cross-coupling processes under attractive, simple, and practical conditions, namely refluxing in methanol under air and without any base.