101214-73-7

Basic information

• Product Name: [(C₅H₁₁)4N]⁽¹⁺⁾*[(C₆H₅)3SnOCOCF₃(Br)]^(1-) = [(C₅H₁₁)4N][(C₆H₅)3SnOCOCF₃(Br)]
• CAS NO: 101214-73-7
• Molecular Weight: 841.523
• Mol File: 101214-73-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [(C₅H₁₁)4N]⁽¹⁺⁾*[(C₆H₅)3SnOCOCF₃(Br)]^(1-) = [(C₅H₁₁)4N][(C₆H₅)3SnOCOCF₃(Br)](CAS DataBase Reference)
• NIST Chemistry Reference: [(C₅H₁₁)4N]⁽¹⁺⁾*[(C₆H₅)3SnOCOCF₃(Br)]^(1-) = [(C₅H₁₁)4N][(C₆H₅)3SnOCOCF₃(Br)](101214-73-7)
• EPA Substance Registry System: [(C₅H₁₁)4N]⁽¹⁺⁾*[(C₆H₅)3SnOCOCF₃(Br)]^(1-) = [(C₅H₁₁)4N][(C₆H₅)3SnOCOCF₃(Br)](101214-73-7)

Safety Data

• Hazardous Substances Data: 101214-73-7(Hazardous Substances Data)

Upstream product

• 866-97-7 tetrapentylammonium bromide 

Relevant articles and documents

Synthesis, Reactivity and Spectral Studies of Some Pentacoordinate Tin(IV) Complexes Derived from Triphenyltin Trifluoroacetate

Triphenyltin methoxide/ethoxide prepared in situ reacts with trifluoroacetic acid, yielding triphenyltin trifluoroacetate in quantitative yield.The reactions of Ph3SnOCOCF3 with tetraalkylammonium salts (R4NX) give pentacoordinated Sn(IV) complex anions of the general formulae (+)(-) .Ph3SnOCOCF3 undergoes cleavage with electrophilic reagents such as ICl, IBr, HgCl2, Hg(SCN)2, yielding Ph2Sn(OCOCF3)*X (X=Cl, Br, SCN).These compounds like the parent Ph3SnOCOCF3 are polymeric in nature with five coordinated Sn(IV) atoms and bridging trifluoroacetate groups.These undergo nucleophilic substitution of (X) with other electronegative groups and form 1:1 molecular adducts with common Lewis bases.All these compounds have been characterized by elemental analyses, and IR and PMR data.