1012338-34-9Relevant articles and documents
Controlling cis/trans-selectivity in intramolecular Diels-Alder reactions of benzo-tethered, ester linked 1,3,9-decatrienes
Pearson, Emma L.,Willis, Anthony C.,Sherburn, Michael S.,Paddon-Row, Michael N.
experimental part, p. 513 - 522 (2008/10/09)
Predictions from DFT (B3LYP/6-31 G(d))-computed stereoisomer product distributions for intramolecular Diels-Alder (IMDA) reactions have been successfully replicated in the laboratory. Benzo-tethered hexadienyl acrylates generally undergo moderately trans-