101258-15-5

Basic information

• Product Name: Benzoic acid, 4-(phosphonomethyl)-
• CAS NO: 101258-15-5
• Molecular Formula: C8H9O5P
• Molecular Weight: 216.13
• Mol File: 101258-15-5.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Benzoic acid, 4-(phosphonomethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoic acid, 4-(phosphonomethyl)-(101258-15-5)
• EPA Substance Registry System: Benzoic acid, 4-(phosphonomethyl)-(101258-15-5)

Safety Data

• Hazardous Substances Data: 101258-15-5(Hazardous Substances Data)

Upstream product

• 2417-72-3 Methyl 4-(bromomethyl)benzoate 
• 17201-43-3 4-cyanobenzyl bromide 
• 180466-87-9 (4-Cyano-benzyl)-phosphonic acid diisopropyl ester 
• 28149-48-6 4-[(diethoxyphosphinyl)methyl]benzoic acid 
• 14295-52-4 4-(diethyoxyphosphorylmethyl)benzoic acid methyl ester 

Downstream Products

• 132047-09-7 C₈H₆Cl₃O₂P 
• 1206723-89-8 C₉H₁₁O₅P 
• 132047-18-8 4-[Hydroxy-((Z)-(S)-1-trifluoromethyl-non-2-enyloxy)-phosphorylmethyl]-benzoic acid 
• 132047-14-4 4-[Hydroxy-((E)-(R)-1-trifluoromethyl-non-2-enyloxy)-phosphorylmethyl]-benzoic acid 
• 132047-17-7 4-[Hydroxy-((Z)-(R)-1-trifluoromethyl-non-2-enyloxy)-phosphorylmethyl]-benzoic acid 
• 132047-15-5 4-[Bis-((E)-(S)-1-trifluoromethyl-non-2-enyloxy)-phosphorylmethyl]-benzoic acid (E)-(S)-1-trifluoromethyl-non-2-enyl ester 
• 132047-15-5 4-[Bis-((Z)-(S)-1-trifluoromethyl-non-2-enyloxy)-phosphorylmethyl]-benzoic acid (Z)-(S)-1-trifluoromethyl-non-2-enyl ester 
• 132047-15-5 4-[Bis-((E)-(R)-1-trifluoromethyl-non-2-enyloxy)-phosphorylmethyl]-benzoic acid (E)-(R)-1-trifluoromethyl-non-2-enyl ester 
• 132047-15-5 4-[Bis-((Z)-(R)-1-trifluoromethyl-non-2-enyloxy)-phosphorylmethyl]-benzoic acid (Z)-(R)-1-trifluoromethyl-non-2-enyl ester 
• 132047-12-2 4-[Bis-((R)-1-trifluoromethyl-nonyloxy)-phosphorylmethyl]-benzoic acid (R)-1-trifluoromethyl-nonyl ester 
• 132047-10-0 4-[Bis-((R)-1-difluoromethyl-nonyloxy)-phosphorylmethyl]-benzoic acid (R)-1-difluoromethyl-nonyl ester 

Relevant articles and documents

Reactivity of the acids of trivalent phosphorus and their derivatives. Part VI. The reaction of the >P-O- anions with benzyl bromides para-substituted in the phenyl ring

The reaction of p-substituted benzyl bromides with the >P-O- ions in THF, alcohols and toluene as the solvents is described. According to the reduction potential of the p-substituted benzyl bromides and the solvent used the formation of the P-C bond, debromination and/or dimerization occur. The principal process is believed to be X-philic substitution, the dimers are formed through a secondary process via SET from the p-substituted benzyl anions into the p-substituted benzyl bromides.

Stereoselective Synthesis of Fluorinated Materials Catalyzed by an Antibody

A monoclonal antibody, elicited by a transition-state analogue for the hydrolysis of fluorinated esters, acted as an enzymelike catalyst for the preparation of chiral fluorinated compounds. The syntheses of (R)- or (S)-1-(fluoroalkyl)alkanols and an allyl