1012798-18-3

Basic information

• Product Name: 6-((tert-butoxycarbonyl)amino)hexyl benzoate
• Synonyms: 6-((tert-butoxycarbonyl)amino)hexyl benzoate
• CAS NO: 1012798-18-3
• Molecular Weight: 321.417
• Mol File: 1012798-18-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 6-((tert-butoxycarbonyl)amino)hexyl benzoate(CAS DataBase Reference)
• NIST Chemistry Reference: 6-((tert-butoxycarbonyl)amino)hexyl benzoate(1012798-18-3)
• EPA Substance Registry System: 6-((tert-butoxycarbonyl)amino)hexyl benzoate(1012798-18-3)

Safety Data

• Hazardous Substances Data: 1012798-18-3(Hazardous Substances Data)

Upstream product

• 98-88-4 benzoyl chloride 
• 4048-33-3 6-amino-1-hexanol 
• 24424-99-5 di-tert-butyl dicarbonate 
• 1579-72-2 2,2,2-trifluoroethyl benzoate 
• 1012797-89-5 6-aminohexyl benzoate 
• 93-58-3 benzoic acid methyl ester 

Relevant articles and documents

μ-Oxo-Dinuclear-Iron(III)-Catalyzed O-Selective Acylation of Aliphatic and Aromatic Amino Alcohols and Transesterification of Tertiary Alcohols

A highly chemoselective and reactive μ-oxo-dinuclear iron(III) salen catalyst for transesterification was developed. The developed iron complex catalyzed acylation of aliphatic amino alcohols with nearly perfect O-selectivity, even when using activated esters, for which chemoselectivity is more difficult to control. In addition, O-selective transesterification of aromatic amino alcohols was achieved for the first time. The high activity of the iron complex enabled the use of sterically congested tertiary alcohols, including unprecedented tert-butanol.

Enzyme-like chemoselective acylation of alcohols in the presence of amines catalyzed by a tetranuclear zinc cluster

Acylation of alcohols and amines is one of the most fundamental reactions. Due to the greater nucleophilicity of the amino group compared to the hydroxyl group, complete N-acylation occurs. Only an enzymatic reaction can promote a highly selective O-acyla