101320-93-8Relevant articles and documents
Photo-induced Carboiodination: A Simple Way to Synthesize Functionalized Dihydrobenzofurans and Indolines
Yang, Xiaobo,Liu, Wenbo,Li, Lu,Wei, Wei,Li, Chao-Jun
, p. 15252 - 15256 (2016)
Herein, we report a simple, redox-neutral and pH-neutral photo-induced carboiodination reaction under very mild conditions. This protocol employs readily available and cheap aryl bromides and sodium iodide as the starting materials to synthesize valuable functionalized dihydrobenzofurans and indolines in good to excellent yields with broad functional-group compatibility. As examples to demonstrate the utility of this protocol, gram-scale reactions and further transformations of the products were accomplished towards the synthesis of bioactive drug candidates. Most significantly, to the best of our knowledge, this reaction represents the first example of a cascade atom-radical-transfer addition involving the cleavage of aromatic C?Br bond.
2-Iodoxybenzoic acid-mediated transformation of halogenated hydrocarbon in the presence of tetraethyl ammonium bromide
Zhang, Yuan,Han, Jianlei,Xu, Yanjun,Wei, Yuping
experimental part, p. 303 - 307 (2012/09/25)
2-Iodoxybenzoic acid (IBX) has been shown to react with alkyl halides in the presence of tetraethyl ammonium bromide to give 2-iodobenzoate esters. Most of the monohalides and dihalides reacted easily with moderate to good yields. The 2-iodobenzoate ester
