101354-06-7

Basic information

• Product Name: C₁₅H₂₂N₂O₂
• CAS NO: 101354-06-7
• Molecular Weight: 262.352
• Mol File: 101354-06-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₅H₂₂N₂O₂(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₅H₂₂N₂O₂(101354-06-7)
• EPA Substance Registry System: C₁₅H₂₂N₂O₂(101354-06-7)

Safety Data

• Hazardous Substances Data: 101354-06-7(Hazardous Substances Data)

Upstream product

• 619-73-8 4-nitrobenzyl chloride 
• 107-45-9 tert-Octylamine 
• 555-16-8 4-nitrobenzaldehdye 

Downstream Products

• 132493-83-5 3-(4-nitro-phenyl)-2-(1,1,3,3-tetramethyl-butyl)-oxaziridine 

Relevant articles and documents

Dehydrogenative synthesis of imines from alcohols and amines catalyzed by a ruthenium N-heterocyclic carbene complex

A new method for the direct synthesis of imines from alcohols and amines is described where hydrogen gas is liberated. The reaction is catalyzed by the ruthenium N-heterocyclic carbene complex [RuCl2(IiPr)(p-cymene)] in the presence of the ligand DABCO and molecular sieves. The imination can be applied to a variety of primary alcohols and amines and can be combined with a subsequent addition reaction. A deuterium labeling experiment indicates that the catalytically active species is a ruthenium dihydride. The reaction is believed to proceed by initial dehydrogenation of the alcohol to the aldehyde, which stays coordinated to ruthenium. Nucleophilic attack of the amine affords the hemiaminal, which is released from ruthenium and converted into the imine.