1014716-67-6Relevant articles and documents
Silyl-protected dioxaborinanes: Application in the Suzuki cross-coupling reaction
Goggins, Sean,Rosevere, Eleanor,Bellini, Clement,Allen, Joseph C.,Marsh, Barrie J.,Mahon, Mary F.,Frost, Christopher G.
supporting information, p. 47 - 52 (2014/01/06)
The synthesis of a range of novel silyl-protected dioxaborinanes as a column- and bench-stable boron reagent were found to be advantageous to achieving good yields in palladium-catalysed cross-coupling reactions under standard conditions. This journal is The Royal Society of Chemistry.
Cyclic triolborates: Air- and water-stable ate complexes of organoboronic acids
Yamamoto, Yasunori,Takizawa, Miho,Yu, Xiao-Qiang,Miyaura, Norio
, p. 928 - 931 (2008/09/20)
(Chemical Equation Presented) A borate in the hand is a convenient reagent for palladium- and copper-catalyzed C-C and C-N bond-forming reactions, especially when, like the title bench-stable complexes, it demonstrates high transmetalation efficiency. Cyclic triolborates can be synthesized readily from organoboronic acids (see scheme), can be handled and stored without special precautions, and are relatively soluble in organic solvents.