1015074-86-8

Basic information

• Product Name: C₅₀H₅₈Br₂FeO₄P₂
• Synonyms: C₅₀H₅₈Br₂FeO₄P₂
• CAS NO: 1015074-86-8
• Molecular Weight: 1000.61
• Mol File: 1015074-86-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₅₀H₅₈Br₂FeO₄P₂(CAS DataBase Reference)
• NIST Chemistry Reference: C₅₀H₅₈Br₂FeO₄P₂(1015074-86-8)
• EPA Substance Registry System: C₅₀H₅₈Br₂FeO₄P₂(1015074-86-8)

Safety Data

• Hazardous Substances Data: 1015074-86-8(Hazardous Substances Data)

Upstream product

• 1015074-84-6 1,1'-diethyl-2,2'-dibromoferrocene 
• 136802-85-2 bis(3,5-dimethyl-4-methoxy-phenyl)chlorophosphine 

Downstream Products

• 1015074-94-8 C₅₆H₇₆FeO₄P₂Si₂ 
• 1015074-96-0 C₅₃H₆₇BrFeO₄P₂Si 
• 1015074-88-0 C₅₄H₆₄FeO₈P₂ 
• 1015075-10-1 C₅₂H₆₀FeO₈P₂ 

Relevant articles and documents

DIPHOSPHINES AND METAL COMPLEXES

Compounds of the formulae (I) and (II), or a mixture of these enantiomers, where R'1 is C1-C4-alkyl and n is 0, 1 or 2; R1 is C1-C8-alkyl, C2-C8-alken-1-yl, -CH2-OR or - CH2-NR5R6; the two radicals R2 are identical or different and are each hydrogen or a monovalent radical of an electrophilic organic compound, or one R2 has this meaning and the other R2 is hydrogen; sec-phos is a secondary phosphino group; R is C1-C8- alkyl and R5 and R6 are each C1-C6-alkyl or R5 and R6 together form tetramethylene, pentamethylene or 3-oxa-1,5-pentylene, are ligands for metal complexes which can be used as valuable homogeneous catalysts for asymmetric syntheses. The compounds are obtained by a novel process in which 3,3'-metallated 1,1'-di-R1-2,2'- dibromoferrocenes are firstly reacted with sec-phos halide, the bromine atoms are then replaced by lithium and the substituent R2 is subsequently introduced by reaction with an electrophilic organic compound or with water.