101660-28-0 Usage
Description
[Mo3(sulfido)4(aqua)9]4+ is a coordination complex consisting of three molybdenum atoms in a 4+ oxidation state, bonded to four sulfide ions and nine water molecules. The molybdenum atoms are at the center of the complex, with the sulfide and water molecules arranged symmetrically around them in an octahedral geometry. [Mo3(sulfido)4(aqua)9](4+) is highly stable and soluble in water.
Uses
Used in Chemical Industry:
[Mo3(sulfido)4(aqua)9]4+ is used as a catalyst for various chemical reactions due to its unique structure and the presence of molybdenum atoms, which are known for their catalytic properties.
Used in Pharmaceutical Industry:
[Mo3(sulfido)4(aqua)9]4+ can be used as a starting material for the synthesis of other molybdenum-containing compounds with potential pharmaceutical applications, such as those with antibacterial or antifungal properties.
Used in Environmental Applications:
[Mo3(sulfido)4(aqua)9]4+ can be employed in the treatment of wastewater, as the molybdenum atoms may help in the removal of contaminants or the reduction of harmful substances.
Used in Analytical Chemistry:
[Mo3(sulfido)4(aqua)9]4+ can be utilized as a reference compound or a standard for the development and validation of analytical methods, particularly those involving the determination of molybdenum or sulfide ions in various samples.
Check Digit Verification of cas no
The CAS Registry Mumber 101660-28-0 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,0,1,6,6 and 0 respectively; the second part has 2 digits, 2 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 101660-28:
(8*1)+(7*0)+(6*1)+(5*6)+(4*6)+(3*0)+(2*2)+(1*8)=80
80 % 10 = 0
So 101660-28-0 is a valid CAS Registry Number.
101660-28-0Relevant articles and documents
Preparation and properties of the corner-shared double cube [Mo6PbS8(H2O)18]8+ as a derivative of [Mo3S4(H2O)9]4+
Saysell, David M.,Huang,Sykes, A. Geoffrey
, p. 2623 - 2627 (1996)
The heterometallic corner-shared double-cuboidal cluster [Mo6PbS8(H2O)18]8+, with the lead atom common to both cubes, has been prepared for the first time by the reaction of [Mo3S4(H2O)9]4+ with lead shot, which requires up to 1 h to reach completion, and by addition of a solution mix of [Mo3S4(H2O)9]4+ and PbII to an excess of BH4-, when reaction is rapid. The air-sensitive blue-green product has UV/VIS absorbance bands at 387 and 757 nm in 2.0 M HClO4. Inductively coupled plasma atomic emission spectroscopy confirmed the Mo:Pb:S ratio as 6:1:8. It was eluted from a cation-exchange column with 4 M Hpts (toluene-p-sulfonic acid), but not 2 M Hpts (or 4 M HClO4), consistent with a high charge, confirmed as 8 + from the 2:1 stoichiometries for the oxidation reactions with e.g. [Co(dipic)2]- (dipic = pyridine-2,6-dicarboxylate) or [Fe(H2O)6]3+, which yield [Mo3S4(H2O)9]4+. Kinetic studies on the oxidations with [Co(dipic)2]- and [Fe(H2O)6]3+ were also carried out as part of an overall appraisal of the reactivity of the heterometallic clusters.
