1017319-36-6Relevant articles and documents
Exploiting neighboring-group interactions for the self-selection of a catalytic unit
Gasparini, Giulio,Prins, Leonard J.,Scrimin, Paolo
supporting information; experimental part, p. 2475 - 2479 (2009/02/06)
(Figure Presented) A good neighbor is better than a far-away friend: A tethering strategy is used to self-select groups that assist in the cleavage of a neighboring carboxylic ester moiety (see picture, TSA=transition-state analogue). A correlation is observed between the amplification at thermodynamic equilibrium and the catalytic efficiency.
