1017572-74-5

Basic information

• Product Name: (Z)-N-(1-(4-chlorophenyl)-3-(trimethylsilyl)prop-2-ynylidene)-4-methoxyaniline
• Synonyms: (Z)-N-(1-(4-chlorophenyl)-3-(trimethylsilyl)prop-2-ynylidene)-4-methoxyaniline
• CAS NO: 1017572-74-5
• Molecular Weight: 341.912
• Mol File: 1017572-74-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (Z)-N-(1-(4-chlorophenyl)-3-(trimethylsilyl)prop-2-ynylidene)-4-methoxyaniline(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-N-(1-(4-chlorophenyl)-3-(trimethylsilyl)prop-2-ynylidene)-4-methoxyaniline(1017572-74-5)
• EPA Substance Registry System: (Z)-N-(1-(4-chlorophenyl)-3-(trimethylsilyl)prop-2-ynylidene)-4-methoxyaniline(1017572-74-5)

Safety Data

• Hazardous Substances Data: 1017572-74-5(Hazardous Substances Data)

Upstream product

• 4018-82-0 4-chloro-N-(4-methoxyphenyl)benzamide 
• 1066-54-2 trimethylsilylacetylene 
• 14630-40-1 Bis(trimethylsilyl)ethyne 

Relevant articles and documents

Domino 1,4- And 1,6-Addition Reactions of Ketene Silyl Acetals to Dialkynyl Imines Promoted by Aluminum Chloride: Synthesis of Multifunctionalized β-Lactams

Domino 1,4- and 1,6-addition reactions of ketene silyl acetals to dialkynyl imines are disclosed. Aluminum chloride promoted domino 1,4- and 1,6-addition reactions of ketene silyl acetals to dialkynyl imines to give a variety of alkenyl iminocyclobutenones in moderate to good yields. The chemoselective reduction of alkenyl iminocyclobutenones and the subsequent thermal rearrangement of resulting alkenyl aminocyclobutenones in the presence of appropriate amines provided cis or trans multifunctionalized β-lactams in moderate to high yields with good to high diastereoselectivities.