101859-19-2

Basic information

• Product Name: (1R,2S)-2-(2-methylprop-2-en-1-yl)cyclohexanol
• CAS NO: 101859-19-2
• Molecular Formula: C₁₀H₁₈O
• Molecular Weight: 154.2493
• Mol File: 101859-19-2.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 225.9°C at 760 mmHg
• Flash Point: 90.8°C
• Density: 0.913g/cm³
• Vapor Pressure: 0.0167mmHg at 25°C
• Refractive Index: 1.473
• CAS DataBase Reference: (1R,2S)-2-(2-methylprop-2-en-1-yl)cyclohexanol(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,2S)-2-(2-methylprop-2-en-1-yl)cyclohexanol(101859-19-2)
• EPA Substance Registry System: (1R,2S)-2-(2-methylprop-2-en-1-yl)cyclohexanol(101859-19-2)

Safety Data

• Hazardous Substances Data: 101859-19-2(Hazardous Substances Data)

Upstream product

• 286-20-4 cyclohexene oxide 
• 67883-62-9 2-methylallyltributyltin 
• 5674-01-1 2-methylallylmagnesium chloride 
• 286-20-4 cyclohexane-1,2-epoxide 
• 563-47-3 3-Chloro-2-methylpropene 
• 936-67-4 2-(2-methyl-2-propenyl)cyclohexanone 
• 108-94-1 cyclohexanone 

Downstream Products

• 101859-20-5 tert-Butyl-dimethyl-[(1R,2S)-2-(2-methyl-allyl)-cyclohexyloxy]-silane 
• 101859-25-0 (1S,2R)-2-((E)-2-Methyl-but-2-enyl)-cyclohexanol 
• 101859-21-6 1-((1R*,2S*)-2-((tert-butyldimethylsilyl)oxy)cyclohexyl)-2-propanone 
• 101859-24-9 tert-Butyl-dimethyl-[(1R,2S)-2-((E)-2-methyl-but-2-enyl)-cyclohexyloxy]-silane 
• 101859-23-8 (Z)-4-[(1S,2R)-2-(tert-Butyl-dimethyl-silanyloxy)-cyclohexyl]-3-methyl-but-2-en-1-ol 
• 101859-23-8 (E)-4-[(1S,2R)-2-(tert-Butyl-dimethyl-silanyloxy)-cyclohexyl]-3-methyl-but-2-en-1-ol 

Relevant articles and documents

Generation of allylic manganates from trimethylmanganate and allylic stannanes and their reactions with epoxides

A new method for forming allyldimethylmanganate has been developed. The preparation eliminated the need for prior generation of an allylmetal species such as allyllithium or allylmagnesium compounds. The reagents reacted with epoxides to give allylated products exclusively in good yields.

Ligand exchange between cyanocuprates and allylic stannanes: A novel, direct route to allylic cuprates possessing remarkable reactivity and stability

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