101960-59-2

Basic information

• Product Name: [(Z)-Butylimino]-phenyl-acetic acid
• Synonyms: [(Z)-Butylimino]-phenyl-acetic acid
• CAS NO: 101960-59-2
• Molecular Weight: 205.257
• Mol File: 101960-59-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [(Z)-Butylimino]-phenyl-acetic acid(CAS DataBase Reference)
• NIST Chemistry Reference: [(Z)-Butylimino]-phenyl-acetic acid(101960-59-2)
• EPA Substance Registry System: [(Z)-Butylimino]-phenyl-acetic acid(101960-59-2)

Safety Data

• Hazardous Substances Data: 101960-59-2(Hazardous Substances Data)

Upstream product

• 109-73-9 N-butylamine 
• 611-73-4 Benzoylformic acid 

Downstream Products

• 55103-94-1 C₁₁H₁₄⁽²⁾HN 
• 5589-01-5 N-butylbenzothioamide 
• 1077-18-5 N-benzylidenebutan-1-amine 

Relevant articles and documents

X=Y-ZH SYSTEMS AS POTENTIAL 1,3-DIPOLES. PART 20. DECARBOXYLATION OF α-IMINO ACIDS. MECHANIZM AND APPLICATIONS TO THIOAMIDE SYNTHESIS

α-Imino acids, prepared from α-keto acids and primary amines, undergo facile decarboxylation to the corresponding imines on heating at =80 deg C in benzene or methylene chloride.Decarboxylation proceeds via a 1,2-ylide which can be trapped by sulphur to give the corresponding secondary thioamides in good yield. 1,2-Ylides from secondary amines and α-keto acids can be generated in situ and trapped with sulphur to give tertiary thioamides in excellent yield.