102101-76-8

Basic information

• Product Name: 2,5,8,11,18,21,24,27-Octaoxa-tricyclo[26.4.0.0^12,17]dotriaconta-1⁽³²⁾,12⁽¹⁷⁾,13,15,28,30-hexaene; compound with picric acid
• CAS NO: 102101-76-8
• Molecular Weight: 906.725
• Mol File: 102101-76-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2,5,8,11,18,21,24,27-Octaoxa-tricyclo[26.4.0.0^12,17]dotriaconta-1⁽³²⁾,12⁽¹⁷⁾,13,15,28,30-hexaene; compound with picric acid(CAS DataBase Reference)
• NIST Chemistry Reference: 2,5,8,11,18,21,24,27-Octaoxa-tricyclo[26.4.0.0^12,17]dotriaconta-1⁽³²⁾,12⁽¹⁷⁾,13,15,28,30-hexaene; compound with picric acid(102101-76-8)
• EPA Substance Registry System: 2,5,8,11,18,21,24,27-Octaoxa-tricyclo[26.4.0.0^12,17]dotriaconta-1⁽³²⁾,12⁽¹⁷⁾,13,15,28,30-hexaene; compound with picric acid(102101-76-8)

Safety Data

• Hazardous Substances Data: 102101-76-8(Hazardous Substances Data)

Upstream product

• 14174-09-5 dibenzo-24-crown ether 
• 88-89-1 2,4,6-Trinitrophenol 

Relevant articles and documents

Isolation and X-Ray Crystal Structure of a 2:1 Complex between Picric Acid and Dibenzo-24-crown-8; an Example of a Sandwich Structure

Despite the lack of strong intermolecular interactions in solution, picric acid (PicH) forms crystalline 2:1 complexes with both dibenzo-18-crown-6 (DB18C6) and dibenzo-24-crown-8 (DB24C8).An X-ray crystallographic study of 2PicH*DB24C8 reveals a continous layer structure comprising alternate PicH and DB24C8 molecules with stacking of the ?-electron-deficient aromatic rings in the PicH molecules and the ?-electron-rich aromatic rings in DB24C8 molecules.