1021879-56-0

Basic information

• Product Name: (E)-1-methyldiphenylsilyloxy-1,2-diphenylethene
• Synonyms: (E)-1-methyldiphenylsilyloxy-1,2-diphenylethene
• CAS NO: 1021879-56-0
• Molecular Weight: 392.572
• Mol File: 1021879-56-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (E)-1-methyldiphenylsilyloxy-1,2-diphenylethene(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-1-methyldiphenylsilyloxy-1,2-diphenylethene(1021879-56-0)
• EPA Substance Registry System: (E)-1-methyldiphenylsilyloxy-1,2-diphenylethene(1021879-56-0)

Safety Data

• Hazardous Substances Data: 1021879-56-0(Hazardous Substances Data)

Upstream product

• 26205-39-0 1,2-diphenyl-2-(trimethylsilyloxy)ethanone 
• 451-40-1 phenyl benzyl ketone 
• 144-79-6 chloromethyldiphenylsilane 

Relevant articles and documents

Preparation of silyl enol ethers from acyloin derivatives using silyllithium reagents

A new method for the regioselective preparation of silyl enol ethers from acyloin derivatives using silyllithium reagents has been developed. Both dimethylphenyl- and methyldiphenylsilyllithium were found to be effective, the latter providing greater stereocontrol. The reaction is believed to proceed via Brook rearrangement assisted by expulsion of the adjacent leaving group. A number of acyclic acyloin derivatives were reacted to form the corresponding silyl enol ethers in good to excellent yield.