1023294-87-2

Basic information

• Product Name: 1-(2,4-dimethoxyphenyl)but-3-en-1-ol
• Synonyms: 1-(2,4-dimethoxyphenyl)but-3-en-1-ol
• CAS NO: 1023294-87-2
• Molecular Weight: 208.257
• Mol File: 1023294-87-2.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 1-(2,4-dimethoxyphenyl)but-3-en-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(2,4-dimethoxyphenyl)but-3-en-1-ol(1023294-87-2)
• EPA Substance Registry System: 1-(2,4-dimethoxyphenyl)but-3-en-1-ol(1023294-87-2)

Safety Data

• Hazardous Substances Data: 1023294-87-2(Hazardous Substances Data)

Upstream product

• 2622-05-1 allylmagnesium bromide 
• 613-45-6 2,4-Dimethoxybenzaldehyde 
• 24850-33-7 allyltributylstanane 
• 106-95-6 allyl bromide 
• 1730-25-2 allylmagnesium bromide 

Downstream Products

• 15852-68-3 1-(2,4-dimethoxyphenyl)but-3-en-1-one 
• 2653-46-5 allyl 4-methylbenzoate 

Relevant articles and documents

Palladium-Catalyzed Allylic Amination of Homoallylic Alcohols with Amines via Carbon-Carbon Bond Cleavage

An efficient approach for palladium(II) acetate catalyzed allylic amination of homoallylic alcohols with various amines via sequential retro-allylation and amination was developed, which afforded the corresponding allylic amines in up to 98% yield.

Pd-containing organopolyoxometalates derived from Dawson polyoxometalate [P2W15V3O62]9-: Lewis acidity and dual site catalysis

Grafting of a palladium complex to the Dawson vanadotungstate polyanion [P2W15V3O62]9- via an organic ligand generates a large family of pincer-type hybrid polyoxometalates. The palladium-POM derivatives have dual catalytic properties. Unlike their parent inorganic polyanions, they catalyze allylations while retaining their oxidant character, which leads to single-pot dual site catalysis. This opens a new route for multicatalytic reactions.

Pd-catalyzed carboetherification ofβ,γ-unsaturated oximes: A novel approach to δ2-lsoxazolines

A novel route to the synthesis of δ2-isoxazoline derivatives is described. Reaction of β,γ-unsaturated oximes with aryl bromides via palladium-catalyzed carboetherification affords 3,5-disubstituted δ2-isoxazollnes in good yields. The use of Xantphos as ligand Is crucial for the transformation. The carboetherification products can be further converted to β-hydroxy ketones in the presence of Fe powder and NH4CI.